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ChemicalBook >> CAS DataBase List >> Benzyl chloride

Benzyl chloride

Benzyl chloride price.
  • $13.5 - $971
  • Product name: Benzyl chloride
  • CAS: 100-44-7
  • MF: C7H7Cl
  • MW: 126.58
  • EINECS:202-853-6
  • MDL Number:MFCD00000889
  • Synonyms:AKOS BBS-00003953;Benzyl chloride, 99.5+%, stabilized, extra pure;Benzyl chloride, 99%, stabilized, pure;Benzyl chloride, 90%, pure;Benzyl chloride, stabilized, extra pure;Benzyl chloride,99.5+%,extra pure,stabilized;Benzyl chloride,99%,pure,stabilized;Benzyl Chloride (stabilized with epsilon-Caprolactam)
28 prices
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Brand
  • Alfa Aesar
  • Chem-Impex
  • ChemSupplyAustralia
  • GFS CHEMICALS
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Sigma-Aldrich
  • TCI Chemical
Package
  • 100mg
  • 500mg
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  • 250G
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  • 500g
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  • 10000g
  • 10KG
  • 50kg
  • ManufacturerAlfa Aesar
  • Product numberA12481
  • Product descriptionBenzyl chloride, 99%, stab.
  • Packaging500g
  • Price$28.1
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12481
  • Product descriptionBenzyl chloride, 99%, stab.
  • Packaging2500g
  • Price$106
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12481
  • Product descriptionBenzyl chloride, 99%, stab.
  • Packaging10000g
  • Price$324
  • Updated2023-06-20
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging250G
  • Price$13.5
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzyl chloride ≥ 98% (GC)
  • Packaging250ML
  • Price$20.7
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging1KG
  • Price$34.94
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging2.5KG
  • Price$81.54
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging5KG
  • Price$151.42
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number02278
  • Product descriptionBenzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC)
  • Packaging10KG
  • Price$279.55
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300426
  • Product descriptionBenzyl chloride, 99%
  • Packaging100g
  • Price$22
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300426
  • Product descriptionBenzyl chloride, 99%
  • Packaging1000g
  • Price$35.2
  • Updated2021-12-16
  • Buy
  • ManufacturerGFS CHEMICALS
  • Product number15672
  • Product descriptionBENZYLCHLORIDE,99%
  • Packaging500mL
  • Price$33.12
  • Updated2021-12-16
  • Buy
  • ManufacturerGFS CHEMICALS
  • Product number15673
  • Product descriptionBENZYLCHLORIDE,99%
  • Packaging2L
  • Price$79.13
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134355
  • Product description(Chloromethyl)benzene 95%+
  • Packaging100mg
  • Price$53
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134355
  • Product description(Chloromethyl)benzene 95%+
  • Packaging500mg
  • Price$87
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number134355
  • Product description(Chloromethyl)benzene 95%+
  • Packaging2.500g
  • Price$215
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar A12481 Benzyl chloride, 99%, stab. 500g $28.1 2024-03-01 Buy
Alfa Aesar A12481 Benzyl chloride, 99%, stab. 2500g $106 2024-03-01 Buy
Alfa Aesar A12481 Benzyl chloride, 99%, stab. 10000g $324 2023-06-20 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 250G $13.5 2021-12-16 Buy
Chem-Impex 02278 Benzyl chloride ≥ 98% (GC) 250ML $20.7 2021-12-16 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 1KG $34.94 2021-12-16 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 2.5KG $81.54 2021-12-16 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 5KG $151.42 2021-12-16 Buy
Chem-Impex 02278 Benzylchloride,≥98.0%(GC),ACSreagentHazmat ≥98.0%(GC) 10KG $279.55 2021-12-16 Buy
ChemSupplyAustralia 300426 Benzyl chloride, 99% 100g $22 2021-12-16 Buy
ChemSupplyAustralia 300426 Benzyl chloride, 99% 1000g $35.2 2021-12-16 Buy
GFS CHEMICALS 15672 BENZYLCHLORIDE,99% 500mL $33.12 2021-12-16 Buy
GFS CHEMICALS 15673 BENZYLCHLORIDE,99% 2L $79.13 2021-12-16 Buy
Matrix Scientific 134355 (Chloromethyl)benzene 95%+ 100mg $53 2021-12-16 Buy
Matrix Scientific 134355 (Chloromethyl)benzene 95%+ 500mg $87 2021-12-16 Buy
Matrix Scientific 134355 (Chloromethyl)benzene 95%+ 2.500g $215 2021-12-16 Buy

Properties

Melting point :-39 °C
Boiling point :179 °C
Density :1.1 g/mL at 25 °C(lit.)
vapor density :4.36 (vs air)
vapor pressure :10.3 mm Hg ( 60 °C)
refractive index :n20/D 1.538(lit.)
Flash point :165 °F
storage temp. :Store below +30°C.
solubility :soluble0.46g/L at 30°C (Decomposes in contact with water)
form :Liquid
color :Clear colorless to slightly yellow
Odor :Pungent, irritating.
explosive limit :1.1-14%(V)
Water Solubility :0.3 g/L (20 ºC)
Merck :14,1129
BRN :471308
Henry's Law Constant :(x 10-4 atm?m3/mol): 3.57 at 20.00 °C (inert gas stripping, Hovorka and Dohnal, 1997)
Exposure limits :TLV-TWA 1 ppm (~5mg/m3) (ACGIH, MSHA, and OSHA); IDLH 10 ppm (NIOSH); carcinogenicity: Animal Limited Evidence, Human Inadequate Evidence (IARC).
Dielectric constant :7.0(13℃)
Stability :Unstable - inhibitors such as propylene oxide or trimethylamine are usually added to prevent polymerization. Combustible. Incompatible with strong oxidizing agents, water, acids, most common metals, dimethyl sulfoxide. Above flash point vapour-air mixtures are explosive within the limits noted above. Contact with water produces toxic fumes.
InChIKey :KCXMKQUNVWSEMD-UHFFFAOYSA-N
LogP :2.3 at 20℃ and pH7
CAS DataBase Reference :100-44-7(CAS DataBase Reference)
IARC :2A (Vol. 29, Sup 7, 71) 1999
NIST Chemistry Reference :Benzyl chloride(100-44-7)
EPA Substance Registry System :Benzyl chloride (100-44-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger GHS hazard pictograms P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Benzyl Chloride is used as an intermediate for manufacturing of benzyl alcohol, benzoic acid and benzyl cyanide. It is also used to prepare benzyl esters, which are used as plasticizer, flavorants and perfumes. It acts as an intermediate in the preparation of phenylacetic acid. In organic synthesis, it is used as an alkylating agent and utilized for the introduction of the benzyl protecting group for alcohols. Further, it is involved in the preparation of quaternary ammonium salts by reaction with tertiary amines. In addition to this, it is used to prepare Grignard reagent by reacting with metallic magnesium.

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