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Cupric nitrate trihydrate

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  • Cupric nitrate
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  • $20.00 / 25kg
  • 2023-07-25
  • CAS:10031-43-3
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  • Purity: 99%
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Cupric nitrate trihydrate Basic information
Description Chemical Properties Reference
Product Name:Cupric nitrate trihydrate
Synonyms:COPPER(+2)NITRATE TRIHYDRATE;Copper(Ⅱ)nitrate;Copper dinitrate trihydrate;Copper(ii) nitrate, trihydrate (1:2:3);Copper(II)nitrate,trihydrate(1:2:3);COPPER(II) NITRATE 3H2O;Copper(II) nitrate trihydrate, for analysis;Copper(II)nitratetrihydrate(99.999%-Cu)PURATREM
CAS:10031-43-3
MF:CuH3NO4
MW:144.57
EINECS:600-060-3
Product Categories:metal nitrate salts
Mol File:10031-43-3.mol
Cupric nitrate trihydrate Structure
Cupric nitrate trihydrate Chemical Properties
Melting point 114 °C
Boiling point 170°C
density 2,32 g/cm3
storage temp. Store at +5°C to +30°C.
solubility 2670g/l
form Fine Powder
Specific Gravity2.32
color Cream to brown
PH3-4 (50g/l, H2O, 20℃)
Water Solubility soluble
Stability:Stable. Strong oxidant - may ignite combustible material. Moisture sensitive. Incompatible with anhydrides, ammonia, amides, cyanides.
CAS DataBase Reference10031-43-3(CAS DataBase Reference)
NIST Chemistry ReferenceCopper dinitrate(10031-43-3)
Safety Information
Hazard Codes O,C,Xn,N
Risk Statements 8-22-34-36/38-50/53-41-38
Safety Statements 17-26-36/37/39-45-37/39-61-60-39
RIDADR UN 3085 5.1/PG 2
WGK Germany 2
RTECS GL7875000
3
HazardClass 5.1
PackingGroup II
HS Code 28342930
ToxicityLD50 orally in Rabbit: 940 mg/kg
MSDS Information
ProviderLanguage
Cupric nitrate English
SigmaAldrich English
ACROS English
ALFA English
Cupric nitrate trihydrate Usage And Synthesis
DescriptionCupric nitrate is the cupric salt of nitrate. Cupric nitrate has various applications: a major application is its conversion to copper oxide, a powerful catalyst organic chemistry. It can also be used in textiles and polishing agents of other metals. It can also be used to demonstrate chemical voltaic cell reactions in schools. During organic synthesis, it can be combined with acetic anhydride to be used as an effective reagent for nitration of aromatic compounds. Its hydrate form can catalyze oxidative coupling of 2, 6-dimethylphenol to produce a polymer which is an important engineering material. Its tri-hydrate form can catalyze the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates. Its pentahydrate form may be used in the preparation of novel coordination polymers. It also has applications in medicine, as an insecticide, in chemical analysis, in making light sensitive papers.
Chemical PropertiesCopper(II) nitrate trihydrate, Cu(NO3)2·3H2O, [10031-43-3], MW 241.59, MP 114.5°C, d 2.32, is a deep blue deliquescent material that crystallizes as rhombic platelets.Copper(II) nitrate trihydrate is very soluble in water, 77.4 g/100 g solution, and in methanol and ethanol. The anhydrous salt has been prepared by reaction of copper metal with N2O4 in ethylacetate, but it is not available commercially.
Referencehttps://en.wikipedia.org/wiki/Copper(II)_nitrate
https://www.sigmaaldrich.com/catalog/product/aldrich/229636?lang=en&region=US
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https://cameochemicals.noaa.gov/chemical/3023
Chemical PropertiesHygroscopic blue crystal with an order of nitric a
UsesAnalytical Reagent
UsesCopper(II) nitrate trihydrate may be used in the preparation of the following mononuclear copper(II) complexes (phen = 1,10-phenanthroline, dpq = dipyrido[3,2-d:2′,3′-f]quinoxaline and dppz = dipyrido[3,2-a:2′,3′-c]phenazine):
[Cu(dpq)(NO3)2]
[Cu(dpq)(NO3)(H2O)2](NO3)
[Cu(dpq)(NO3)2(H2O)2]·2H2O
[Cu(dppz)(NO3)2(H2O)]·H2O
General DescriptionCopper(II) nitrate trihydrate is a hydrated copper salt. It participates as catalyst in the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates.
Purification MethodsCrystallise it from weak aqueous HNO3 (0.5mL/g) by cooling from room temperature. The anhydrous salt can be prepared by dissolving copper metal in a 1:1 mixture of liquid NO2 and ethyl acetate and purified by sublimation [Evans et al. J Chem Soc, Faraday Trans 1 75 1023 1979]. The hexahydrate dehydrates to the trihydrate at 26o, and the anhydrous salt sublimes between 150 and 225o, but melts at 255-256o and is deliquescent.
Cupric nitrate trihydrate Preparation Products And Raw materials
Raw materialsNitric acid-->Copper(II) sulfate-->Copper-->Sodium nitrate-->Cupric oxide
Preparation ProductsFurfuryl alcohol-->2-Methylfuran
Tag:Cupric nitrate trihydrate(10031-43-3) Related Product Information
Ferric nitrate nonahydrate Cobaltous nitrate hexahydrate Indium nitrate hydrate CHROMIUM(III) NITRATE NONAHYDRATE Econazole nitrate Miconazole Nitrate Thiamine nitrate Cupric oxide NITRATE Copper Copper dinitrate Copper nitrate basic CUPRIC NITRATE HYDRATE NITRONIUM TETRAFLUOROBORATE Lanthanum(III) nitrate hexahydrate Neodymium(III) nitrate hydrate DYSPROSIUM NITRATE Platinum nitrate Copper Nitrate Trihydrate