ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Polyamines >(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Suppliers list
Company Name: Henan Fengda Chemical Co., Ltd
Tel: +86-371-86557731 +86-13613820652
Email: info@fdachem.com
Products Intro: Product Name:(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine
CAS:144222-34-4
Purity:99 Package:1kg;50USD|1000kg;1USD
Company Name: airuikechemical co., ltd.
Tel: +undefined86-15315557071
Email: sales02@airuikechemical.com
Products Intro: Product Name:(r,r)-tsdpen
CAS:144222-34-4
Purity:99.9% Package:1Kg;0.00;USD|5Kg;0.00;USD|25Kg;0.00;USD
Company Name: Capot Chemical Co.,Ltd.
Tel: 571-85586718 +8613336195806
Email: sales@capotchem.com
Products Intro: Product Name:(1R,2R)-(-)-N-p-tosyl-1,2-diphenylethylene diamine
CAS:144222-34-4
Purity:98%(Min,GC) Package:1G;1KG;100KG
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
Email: info@dakenam.com
Products Intro: Product Name:(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
CAS:144222-34-4
Purity:99% Package:100g ;1KG ;5KG 25KG
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512
Email: info@tianfuchem.com
Products Intro: Product Name:TIANFU-CHEM (R,R)-TsDPEN
CAS:144222-34-4
Purity:99% Package:25KG;5KG;1KG

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine manufacturers

  • (r,r)-tsdpen
  • (r,r)-tsdpen pictures
  • $0.00 / 1Kg
  • 2024-04-08
  • CAS:144222-34-4
  • Min. Order: 1Kg
  • Purity: 99.9%
  • Supply Ability: 200tons
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Basic information
Product Name:(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
Synonyms:(R,R)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE;(R,R)-N-(2-AMINO-1,2-DIPHENYLETHYL)-P-TOLUENESULFONAMIDE;(R,R)-TSDPEN;(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine;(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine98%;(R,R)-Ts-DPEN, (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98%;Benzenesulfonamide,N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-methyl-;(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine≥ 99% (Assay, Chiral purity)
CAS:144222-34-4
MF:C21H22N2O2S
MW:366.48
EINECS:
Product Categories:Chiral Nitrogen;DPEN Series;organic amine;chiral;API intermediates;Chiral Compound;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;HydrogenationChiral Building Blocks;Organic Building Blocks;Polyamines;Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:144222-34-4.mol
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Structure
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Chemical Properties
Melting point 128-131 °C(lit.)
Boiling point 537.3±60.0 °C(Predicted)
alpha -61.5 º (c=1, CH2Cl2)
density 1.1440 (rough estimate)
refractive index -30 ° (C=0.4, CHCl3)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform, Methanol
pka10.76±0.50(Predicted)
form Crystals or Crystalline Powder
color White to slightly yellow
optical activity[α]20/D 35°, c = 1 in chloroform
Water Solubility insoluble
InChIKeyUOPFIWYXBIHPIP-NHCUHLMSSA-N
CAS DataBase Reference144222-34-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29215900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Usage And Synthesis
Chemical Propertieswhite to slightly yellow crystals or crystalline
UsesChiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination
Uses(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine is used as a catalyst in stereoselective preparation of aromatic ketone derivatives as well as other chiral organic compounds.
General DescriptionThis product has been enhanced for catalytic efficiency.
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Preparation Products And Raw materials
Tag:(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine(144222-34-4) Related Product Information
(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (R)-(+)-a,a-Diphenyl-2-pyrrolidinemethanol 1,2-Diphenylethylenediamine Toluenesulfonamide Ethylenediamine (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethylenediamine(Chloro)(p-cymene)ruthenium(II) ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine (1R,2R)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE RUCL[(R,R)-TSDPEN](MESITYLENE) CHLORO[(1R,2R)-TSDPEN](P-CYMENE)RUTHENIUM(II) RU[(R,R)-TSDPEN](P-CYMENE) RUCL[(S,S)-TSDPEN](MESITYLENE) RUCL[(R,R)-TSDPEN](HEXAMETHYLBENZENE) CHLORO[(1S,2S)-TSDPEN](P-CYMENE)RUTHENIUM(II) RU[(S,S)-TSDPEN](P-CYMENE)