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| | 1,1'-FERROCENEDICARBOXYLIC ACID Basic information |
| | 1,1'-FERROCENEDICARBOXYLIC ACID Chemical Properties |
| Melting point | ≥300 °C(lit.) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated) | | form | crystal | | color | orange | | Water Solubility | Insoluble | | Exposure limits | ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | | Stability: | Stable. Incompatible with strong oxidizing agents. | | CAS DataBase Reference | 1293-87-4 | | NIST Chemistry Reference | 1,1'-Ferrocenedicarboxylic acid(1293-87-4) |
| | 1,1'-FERROCENEDICARBOXYLIC ACID Usage And Synthesis |
| Chemical Properties | dark brown powder | | Uses | Reactant for preparation of:
- Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
- Potential antitumor agents
- Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
- Prganometallic aromatic polyesters
- Manganese-lanthanide-ferrocene clusters
| | Purification Methods | It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.] |
| | 1,1'-FERROCENEDICARBOXYLIC ACID Preparation Products And Raw materials |
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