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DIALIFOS

DIALIFOS Basic information
Product Name:DIALIFOS
Synonyms:dialifor;Dialiphor;O,O-Diaethyl-S-2-chlor-1-(phthalimido)-aethyl-dithiophosphat;O,O-Diethyl S-(2-chloro-1-phthalimidoethyl)phosphorodithioate;o,o-diethylphosphorodithioates-esterwithn-(2-chloro-1-mercaptoethyl)phthal;o,o-diethyls-(2-chloro-1-phthalimidoethyl)phosphorodithioate;Phosphorodithioic acid, O,O-diethyl ester, S-ester with N-(2-chloro-1-mercaptoethyl)phthalimide;Phosphorodithioic acid, S-(2-chloro-1-phthalimidoethyl) O,O-diethyl ester
CAS:10311-84-9
MF:C14H17ClNO4PS2
MW:393.85
EINECS:233-689-3
Product Categories:DIA - DICPesticides;OrganophorousPesticides;AcaricidesPesticides&Metabolites;Alpha sort;D;DAlphabetic;Insecticides;Pesticides;Pesticides&Metabolites;Phthalimides
Mol File:10311-84-9.mol
DIALIFOS Structure
DIALIFOS Chemical Properties
Melting point 68℃
Boiling point 465.9±55.0 °C(Predicted)
density 1.435±0.06 g/cm3(Predicted)
Fp 100 °C
storage temp. 0-6°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form solid
pka-2.72±0.20(Predicted)
Water Solubility 0.18mg/L(temperature not stated)
Merck 13,2989
EPA Substance Registry SystemDialifor (10311-84-9)
Safety Information
Hazard Codes T+,N
Risk Statements 24-28-50/53
Safety Statements 28-36/37-45-60-61
RIDADR 2783
RTECS TD5165000
HazardClass 6.1(a)
PackingGroup I
Hazardous Substances Data10311-84-9(Hazardous Substances Data)
ToxicityLD50 in adult male, female rats (mg/kg): 24, 6 orally (Gaines, Linder)
MSDS Information
DIALIFOS Usage And Synthesis
DescriptionDialifor is a crystalline solid. The commercialproduct may also be available as a colorless oil. Molecularweight = 393.86; Freezing/Melting point (solid) = 68℃.Hazard Identification (based on NFPA-704 M RatingSystem): Health 3, Flammability 0, Reactivity 0. Insolublein water.Dialifor is a crystalline solid. The commercialproduct may also be available as a colorless oil. Molecularweight = 393.86; Freezing/Melting point (solid) = 68℃.Hazard Identification (based on NFPA-704 M RatingSystem): Health 3, Flammability 0, Reactivity 0. Insolublein water.
Chemical PropertiesDialifor is a crystalline solid. The commercial product may also be available as a colorless oil.
UsesInsecticide; acaricide.
UsesNonsystemic insecticide and acaricide to control chewing and sucking insects and spider mites on a wide variety of fruits and vegetables.
DefinitionChEBI: Dialifor is a member of isoindoles.
General DescriptionWhite crystalline solid, also reported as a colorless oil, colorless. Used as an insecticide and acaricide (kills beetles, ticks, mites, etc.).
Reactivity ProfileReleases nitrogen oxides, sulfur oxides, and phosphorus oxides when heated. Readily hydrolyzed by concentrated alkali. Avoid alkali. [EPA, 1998]. Organophosphates, such as DIALIFOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health HazardHighly toxic by all routes of exposure;exhibits acute, delayed, and chronic effect;cholinesterase inhibitor; symptoms of poi-soning are similar to those of parathion,including weakness and twitching of mus-cle, headache, giddiness, dizziness, excessivesalivation, lacrimation, tightness in chest,blurred vision, slurred speech, mental confu-sion, and drowsiness; gastrointestinal effectsinclude nausea, vomiting, stomach cramps,and diarrhea; heavy exposure can lead to dif-ficulty in breathing, convulsions, and coma;median lethal doses reported in the literatureshow inconsistent and varying values.
LD50 oral (rat): 5–53 mg/kg
LD50 oral (mouse): 39–65 mg/kg
LD50 oral (rabbit): 35 mg/kg
LD50 skin (rabbit): 145 mg/kg.
Health HazardDIALIFOS can cause serious symptoms and in extreme cases death by respiratory arrest.
Fire HazardReleases nitrogen oxides, sulfur oxides, and phosphorus oxides when heated. Readily hydrolyzed by concentrated alkali. Avoid alkali.
Safety ProfilePoison by ingestion and skin contact. An experimental teratogen. Other experimental reproductive effects. When heated to decomposition it emits toxic fumes of SOx, POx, and NOx.
Potential ExposureA potential danger to those involved in the manufacture, formulation and application of this insecticide.
First aidIf this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Speed in removing material from skin is ofextreme importance. Shampoo hair promptly if contaminated.Seek medical attention immediately. If this chemical hasbeen inhaled, remove from exposure, begin rescue breathing(using universal precautions, including resuscitation mask) ifbreathing has stopped and CPR if heart action has stopped.Transfer promptly to a medical facility. When this chemicalhas been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Effects may be delayed; medicalobservation is recommended.
Environmental FateChemical/Physical. Though no products were identified, the hydrolysis half-lives at 20°C were 15 days and 14 hours at pH 6.1 and pH 7.4, respectively (Freed et al., 1979, 1979a).
storageColor Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with dialiforyou should be trained on its proper handling and storage.Store in tightly closed containers in a cool, well-ventilatedarea away from strong bases.
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesStrong bases. Contact with oxidizers may cause the release of phosphorous oxides. Contact with strong reducing agents, such as hydrides, may cause the formation of flammable and toxic phosphine gas.
Waste DisposalAlkaline hydrolysis or incineration. In accordance with 40CFR165, follow recom- mendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following pack- age label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
Tag:DIALIFOS(10311-84-9) Related Product Information
Succinimide Phosmet O,O-Diethyl S-methyl dithiophosphate Ammonium O,O-dimethyl dithiophosphate Dimethylphosphorodithioate N-(2-CHLOROETHYL)ACETAMIDE N-(2-CHLOROETHYL)BENZAMIDE O,O,S-TRIMETHYLDITHIOPHOSPHATE Diethylphosphorodithioate O,O-Diethyl Dithiophosphate AMMoniuM Salt N-BENZYL-N-(2-CHLOROETHYL)AMINE N-(2-CHLOROETHYL)PHTHALIMIDE DIALIFOS