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Triethylamine

Triethylamine Suppliers list
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Email: info@tianfuchem.com
Products Intro: CAS:121-44-8
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Anhui Royal Chemical Co., Ltd.
Tel: +86-025-86736275
Email: dana.jiang@royal-chem.com
Products Intro: Product Name:Triethylamine
CAS:121-44-8
Purity:99.00% Package:25kg/drum;200kg/drum
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: 86-0551-65418684 18949823763
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Products Intro: Product Name:Triethylamine
CAS:121-44-8
Purity:99.9% Package:1KG;5USD
Company Name: Thermo Fisher Scientific  Gold
Tel:800-810-5118
Email:cnchemical@thermofisher.com
Products Intro:Product Name:TriethylaMine, 99.7%, extra pure
CAS:121-44-8
Purity:99.7% Package:1KG Remarks:ACROS 219510500
Company Name: Secco work (Beijing) chemical technology co., LTD  Gold
Tel:010-69755668;
Email:1139670422@qq.com
Products Intro:CAS:121-44-8
Purity:98% Package:25kg 5KG;1KG
Triethylamine Chemical Properties
Melting point -115 °C
Boiling point 90 °C
density 0.728
vapor density 3.5 (vs air)
vapor pressure 51.75 mm Hg ( 20 °C)
refractive index n20/D 1.401(lit.)
FEMA 4246 | TRIETHYLAMINE
Fp 20 °F
storage temp. 2-8°C
solubility water: soluble112g/L at 20°C
pka10.75(at 25℃)
form Liquid
color Clear
PH12.7 (100g/l, H2O, 15℃)(IUCLID)
explosive limit1.2-9.3%(V)
Water Solubility 133 g/L (20 ºC)
Merck 14,9666
BRN 1843166
Stability:Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point. Incompatible with strong oxidizing agents, strong acids, ketones, aldehydes, halogenated hydrocarbons.
CAS DataBase Reference121-44-8(CAS DataBase Reference)
NIST Chemistry ReferenceTriethylamine(121-44-8)
EPA Substance Registry SystemEthanamine, N,N-diethyl-(121-44-8)
Safety Information
Hazard Codes F,C
Risk Statements 11-20/21/22-35
Safety Statements 3-16-26-29-36/37/39-45-61
RIDADR UN 1296 3/PG 2
WGK Germany 1
RTECS YE0175000
34
Hazard Note Highly Flammable/Corrosive
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29211910
Hazardous Substances Data121-44-8(Hazardous Substances Data)
MSDS Information
ProviderLanguage
N,N-diethylethanamine English
SigmaAldrich English
ACROS English
ALFA English
Triethylamine Usage And Synthesis
OutlineTriethylamine (formula: C6H15N), also known as N, N-diethylethanamine, is the most simple tri-substituted uniformly tertiary amine, having typical properties of tertiary amines, including salifying, oxidation, Hing Myers test (Hisberg reaction) for triethylamine does not respond. It is colorless to pale yellow transparent liquid, with a strong smell of ammonia, slightly fuming in the air. Boiling point: 89.5 ℃, relative density (water = 1): 0.70, the relative density (Air = 1): 3.48, slightly soluble in water, soluble in alcohol, ether. Aqueous solution is alkaline, flammable. Vapor and air can form explosive mixtures, the explosion limit is 1.2% to 8.0%. It is toxic, with a strong irritant.
UsesTriethylamine is a clear, colorless liquid with an Ammonia or fish-like odor. It is used in making waterproofing agents, and as a catalyst, corrosion inhibitor and propellant.
It is mainly used as base, catalyst, solvent and raw material in organic synthesis and is generally abbreviated as Et3N, NEt3 or TEA. It can be used to prepare phosgene polycarbonate catalyst, polymerization inhibitor of tetrafluoroethylene, rubber vulcanization accelerator, special solvent in paint remover, enamel anti-hardener, surfactant, antiseptic, wetting agent, bactericides, ion exchange resins, dyes, fragrances, pharmaceuticals, high-energy fuels, and liquid rocket propellants, as a curing and hardening agent for polymers and for the desalination of seawater.
Consumption Quota of in medical industry:
Medicine Consumption Quota(Unit: t/t)
Ampicillin sodium 0.465
Amoxicillin 0.391
Cefazolin sodium 2.442
Cefazolin organism 1.093
Oxygen piperazine penicillin 0.584
Ketoconazole 8.00
Vitamin B6 0.502
Fluorine organism acid 10.00
Praziquantel 0.667
Thiotepa 1.970
Penicillamine 1.290
Berberine hydrochloride 0.030
Verapamil 0.540
Alprazolam 3.950
Adjacent benzene acetic acid 0.010
ProductionIt is produced by ethanol and ammonia in the presence of hydrogen, in containing Cu-Ni-clay catalyst reactor under heating conditions (190 ± 2 ℃ and 165 ± 2 ℃) reaction. The reaction also produces ethylamine and diethylamine, products were condensed and then absorption by ethanol spray to obtain crude triethylamine, through the final separation, dehydration and fractionation, pure triethylamine is obtained.
Reaction
  • It can be used to reduce the alkali in the reaction.

  • Alkylation reaction
  • Oxidation reaction
Health EffectsTriethylamine can affect you when inhaled and by passing through the skin.
  1. Contact can severely irritate and bum the skin and eyes with possible eye damage.
  2. Exposure can irritate the eyes, nose and throat.
  3. Inhaling Triethylamine can irritate the lungs. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical mergency.
  4. Triethylamine may cause a skin allergy.
  5. Triethylamine may affect the liver and kidneys.
  6. Triethylamine is a flammable liquid and a dangerous fire hazard.
CategoryFlammable liquids
Toxicity gradingToxic
Acute toxicityOral-rat LD50: 460 mg/kg; Oral-Mouse LD50: 546 mg/kg
Stimulus dataEyes-rabbit 250 mg severe
Explosive hazardous characteristicsMixed with air can be explosive
Flammability hazard characteristicsIn case of fire, high temperature, oxidant, it is flammable, combustion produces toxic fumes of nitrogen oxides
DefinitionChEBI: A tertiary amine that is ammonia in which each hydrogen atom is substituted by an ethyl group.
Storage CharacteristicsTreasury ventilation low-temperature drying, stored separately from oxidants, acids
Extinguishing agentDry, dry sand, carbon dioxide, foam
Occupational standardsTWA 40 mg/cubic meter
General DescriptionA clear colorless liquid with a strong ammonia to fish-like odor. Flash point 20°F. Vapors irritate the eyes and mucous membranes. Less dense (6.1 lb / gal) than water. Vapors heavier than air. Produces toxic oxides of nitrogen when burned.
Air & Water ReactionsHighly flammable. Soluble in water.
Reactivity ProfileTriethylamine reacts violently with oxidizing agents. Reacts with Al and Zn. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Health HazardVapors irritate nose, throat, and lungs, causing coughing, choking, and difficult breathing. Contact with eyes causes severe burns. Clothing wet with chemical causes skin burns.
Fire HazardFlammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Triethylamine Preparation Products And Raw materials
Raw materialsEtanol-->Ammonia-->Hydrogen-->Diethylamine-->Triethanolamine-->KAOLIN
Preparation Products4-Cyanophenyl isocyanate-->TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD-->ETHYL 2-PHENYL-3-(TRIFLUOROMETHYL)PYRAZOLE-4-CARBOXYLATE-->2-CYANO-4-PYRIDINE CARBOXYLIC ACID-->Camostat-->fluorocarbon sulfactant 6201-->Methyl trans-2-nonenoate-->polyurethane water-based emulsion finishes PU-II series-->6-FLUORO-4-HYDROXY-2-(TRIFLUOROMETHYL)QUINOLINE-->Methyl 2-aminothiophene-3-carboxylate-->DI-2-PYRIDYL THIONOCARBONATE-->2-Thienyl isocyanate-->3-Cyanophenyl isocyanate-->4-(BOC-AMINOMETHYL)PYRIDINE-->5-Chloro-2-(methylthio)pyrimidine-4-carboxylic acid-->METHYL 3-[(2-BROMOACETYL)AMINO]THIOPHENE-2-CARBOXYLATE-->2-Chlorophenyl isocyanate-->3-[(N-(TERT-BUTYLOXYCARBONYL)AMINO)METHYL]PYRIDINE-->2-Methoxyphenyl isocyanate-->(R)-Glycidyl butyrate-->4-Fluorophenyl isocyanate-->Triisopropyl phosphite-->N-Boc-N,N-bis(2-chloroethyl)amine-->5-TERT-BUTOXYCARBONYLAMINO-PYRIDINE-3-CARBOXYLIC ACID-->2-FLUOROPHENYL ISOCYANATE-->4-Methoxyphenyl isocyanate-->Metazachlor-->indomethacin farnesil-->2-amino-5-chloro-diphenyl methanol-->S-2-Benzothiazolyl 2-amino-alpha-(methoxyimino)-4-thiazolethiolacetate-->3-FLUOROPHENYL ISOCYANATE-->3,4-(METHYLENEDIOXY)PHENYL ISOCYANATE-->Ampicillin-->1-(4-NITROBENZENESULFONYL)-1H-1,2,4-TRIAZOLE-->3-Hydroxy-6-methyl-2-pyridinemethanol-->Tetraethylammonium bromide-->Pyridat-->N,N-Diethylhydroxylamine-->Dichlormid-->2-Mercaptobenzothiazolyl-(Z)-(2-aminothiazol-4-yl)-2-(tert-butoxycarbonyl) isopropoxyiminoacetate
Tag:Triethylamine(121-44-8) Related Product Information
Ethylenediamine TRIMETHYLAMINE HYDROCHLORIDE 1-(3,4-DIHYDRO-2-NAPHTHYL)PYRROLIDINE Alizarin Fluorine Blue Thymolphthalein Complexone ETHYLENEDIAMINE-N,N'-DIACETIC-N,N'-DIPROPIONIC ACID Triethanolamine Diethylaminoethanol Perfluorotributylamine Triethylamine Diethyltoluenediamine Perfluorotriethylamine DIETHYLALUMINUM CHLORIDE N,N-Diisopropylethylamine Diethylenetriamine Diethylzinc 2-(2-Aminoethylamino)ethanol N,N-Dimethylethylamine