Copper benzoate

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Products Intro: Product Name:Copper Benzoate Powder
CAS:533-01-7
Purity:0.98 Package:1KG;5KG;25KG
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Products Intro: Product Name:Copper benzoate
CAS:533-01-7
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Products Intro: Product Name:Copper benzoate
CAS:533-01-7
Purity:99 Package:5KG;1KG,25kg
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Products Intro: Product Name:Cupricbenzoate
CAS:533-01-7
Purity:95+% Package:1g;5g;10g
Copper benzoate Basic information
Product Name:Copper benzoate
Synonyms:copper dibenzoate;benzoicacid,copper(2++)salt;CUPRIC BENZOATE;COPPER BENZOATE;COPPER (II) BENZOATE;BENZOIC ACID COPPER (II) SALT;Dibenzoic acid copper(II) salt;cupric dibenzoate
CAS:533-01-7
MF:C14H10CuO4
MW:305.77
EINECS:208-552-6
Product Categories:
Mol File:533-01-7.mol
Copper benzoate Structure
Copper benzoate Chemical Properties
EPA Substance Registry SystemBenzoic acid, copper(2+) salt (533-01-7)
Safety Information
MSDS Information
Copper benzoate Usage And Synthesis
DescriptionCopper benzoate is the chemical compound with the formula Cu(C6H5CO2)2. This coordination complex is derived from the cupric ion and the conjugate base of benzoic acid. Because copper emits blue in a flame, this salt has found some use as a source of blue light in fireworks.
Chemical PropertiesBlue, crystalline powder; odorless.Slightly soluble in cold water, acids, and alcohol.
Physical propertiesCopper (II) benzoates exists in at least two structural forms , depending on the degree of hydration. As for copper (II) acetate , the benzoate adopts a "Chinese lantern" structure, wherein a pair of copper centers are linked by four bridging carboxylate ligands. Typically one site on each copper center is occupied by water, which can be replaced by other ligands . A hydrated form is also known, wherein each Cu (II) center is bound to four water ligands and benzoate .
UsesCupric benzoate monohydrate (cas# 533-01-7) is used as a catalyst in the preparation of positive resist compositions comprising sulfonium compounds as acid diffusion inhibitors for high resolution and minimal line edge roughness.
PreparationIn laboratory, copper benzoate can be made by combining aqueous solutions of potassium benzoate with copper sulfate. Copper benzoate precipitates as a pale blue solid :
2 C6H5COOK + CuSO4 →Cu(C6H5COO)2 + K2SO4
The primary use of this of this compound is in production of blue flame in fireworks. Copper benzoate made from sodium benzoate for use in fireworks may result in strong yellow dilution of the flame unless the precipitate is carefully washed to remove sodium ion (which emits brightly yello). Emission from potassium does not complicate the emission spectrum.
Purification MethodsRecrystallise it from hot water. Its solubility in EtOH/*C6H6 (90%) at 25o is 0.1%. [Crawford & Stewart J Chem Soc 228, 289 1953, Beilstein 9 H 84, 9 I 60, 9 III 376, 9 IV 280.]
Copper benzoate Preparation Products And Raw materials
Tag:Copper benzoate(533-01-7) Related Product Information
COPPER(II) DIAMMONIUM CHLORIDE DIHYDRATE COPPER(II) 3,5-DIISOPROPYLSALICYLATE HYDRATE salicylic acid, copper salt o-Aminobenzoic acid copper complex Copper benzoate MONO-N-BUTYL PHTHALATE COPPER(II) SALT BENZOIC ACID COPPER(II) SALT HYDRATE bis[4-hydroxysalicylato(2-)-O1,O2]cuprate(2-) COPPER BIS-3,5-DIISOPROPYLSALICYLATE