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| Bis(tri-tert-butylphosphine)palladium(0) Basic information | Reaction |
| Bis(tri-tert-butylphosphine)palladium(0) Chemical Properties |
Melting point | >300 °C | storage temp. | -20°C | form | Crystals | color | Off-white to orange-brown | Water Solubility | insoluble | Sensitive | Light, Air & Moisture Sensitive | InChIKey | XULQKWNZCKOVSU-UHFFFAOYSA-P | CAS DataBase Reference | 53199-31-8(CAS DataBase Reference) |
Hazard Codes | Xi | Risk Statements | 36/37/38 | Safety Statements | 24/25 | WGK Germany | 3 | TSCA | No | HS Code | 28439000 |
| Bis(tri-tert-butylphosphine)palladium(0) Usage And Synthesis |
Reaction |
- Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.
- A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.
- Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.
- Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.
- Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
- Cross-coupling of silanolates and halides.
- Elimination/isomerization of enol triflates derived from β-ketoesters.
| Chemical Properties | Off white crystalline solid | Uses | Catalyst for Suzuki coupling on a multisubstituted sp 3 -carbon (eq. 1) Catalyst for Stille coupling reaction of aryl chlorides 2 (eq. 2) Catalyst for Negishi coupling reaction 3 (eq. 3) Catalyst for Heck coupling to form tetrasubstituted olefins 4 (eq. 4) Catalyst for Buchwald-Hartwig amination of aryl halide 5 (eq. 5) Catalyst for carbonylation of aryl halides with carbamoylsilanes 6 (eq. 6) t -Bu 3 P) 2 catalyst. | Uses | Bis(tri-tert-butylphosphine)palladium(0) is used in Coupling reactions, Heck couplings. It acts as a palladium catalyst for reductive carbonylation. | General Description | This product has been enhanced for catalytic efficiency. |
| Bis(tri-tert-butylphosphine)palladium(0) Preparation Products And Raw materials |
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