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Ethyl 2-methylbutyrate

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Products Intro: Product Name:Ethyl 2-methylbutyrate
CAS:7452-79-1
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CAS:7452-79-1
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CAS:7452-79-1
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Products Intro: Product Name:Ethyl 2-methylbutyrate
CAS:7452-79-1
Purity:99% Package:5KG;1KG Remarks:C7H14O2
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Products Intro: Product Name:Ethyl 2-Methyl Butyrate
CAS:7452-79-1

Ethyl 2-methylbutyrate manufacturers

  • Ethyl 2-methylbutyrate
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  • $6.00 / 1KG
  • 2024-01-18
  • CAS:7452-79-1
  • Min. Order: 1KG
  • Purity: 99%
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  • Ethyl 2-methylbutyrate
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  • $30.00 / 1KG
  • 2023-09-06
  • CAS:7452-79-1
  • Min. Order: 50KG
  • Purity: 99%
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Ethyl 2-methylbutyrate Basic information
Description References
Product Name:Ethyl 2-methylbutyrate
Synonyms:RARECHEM AL BI 0133;2-METHYLBUTYRIC ACID ETHYL ESTER;ETHYL 2-METHYLBUTYRATE;ETHYL DL-2-METHYLBUTYRATE;DL-2-METHYLBUTYRIC ACID ETHYL ESTER;ETHYL 2-METHYLBUTYRATE 98+% NATURAL &;ETHYL 2-METHYLBUTYRATE 98+% FCC;ethylmethylbutyrate,ethyl2-methylbutanoate
CAS:7452-79-1
MF:C7H14O2
MW:130.18
EINECS:231-225-4
Product Categories:Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Certified Natural ProductsFlavors and Fragrances;Organics;C6 to C7;Carbonyl Compounds;Esters;Alphabetical Listings;E-F;Flavors and Fragrances;Pharmaceutical Intermediates
Mol File:7452-79-1.mol
Ethyl 2-methylbutyrate Structure
Ethyl 2-methylbutyrate Chemical Properties
Melting point -93.23°C (estimate)
Boiling point 133 °C (lit.)
density 0.865 g/mL at 25 °C (lit.)
vapor pressure 11.73hPa at 20℃
FEMA 2443 | ETHYL 2-METHYLBUTYRATE
refractive index n20/D 1.397(lit.)
Fp 79 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless
PH7 (H2O)
Odorat 10.00 % in dipropylene glycol. sharp sweet green apple fruity
Odor Typefruity
Water Solubility 600mg/L at 20℃
JECFA Number206
BRN 1720887
LogP2 at 20℃
CAS DataBase Reference7452-79-1(CAS DataBase Reference)
NIST Chemistry ReferenceButanoic acid, 2-methyl-, ethyl ester(7452-79-1)
EPA Substance Registry SystemEthyl 2-methylbutyrate (7452-79-1)
Safety Information
Risk Statements 10
Safety Statements 16-24/25
RIDADR UN 3272 3/PG 3
WGK Germany 1
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29159080
MSDS Information
ProviderLanguage
2-Methylbutyric acid ethyl ester English
SigmaAldrich English
ACROS English
ALFA English
Ethyl 2-methylbutyrate Usage And Synthesis
DescriptionEthyl 2-methylbutyrate is the ethyl ester form of the 2-methylbutyrate with pleasant sweet aroma. It is a naturally occurring ester which is found in apple, wine, orange, strawberry, cheese, milk, mango, cognac, etc. It is a highly valuable flavoring agent used in flavoring in foods and beverages as well as fragrance in perfume and perfumed products. It is generally prepared through the esterification between alcohol and 2-methylbutyrate.
ReferencesDimick, Paul S., Jonathan C. Hoskin, and Terry E. Acree. "Review of apple flavor—State of the art∗." Critical Reviews in Food Science & Nutrition 18.4 (1983): 387-409.
Konczal, J. B., et al. "Apple juice flavor compound sorption by sealant films."Journal of food science 57.4 (1992): 967-970.
Djojoputro, Hiannie, and Suryadi Ismadji. "Density and viscosity of binary mixtures of ethyl-2-methylbutyrate and ethyl hexanoate with methanol, ethanol, and 1-propanol at (293.15, 303.15, and 313.15) K." Journal of Chemical & Engineering Data 50.4 (2005): 1343-1347.
Chemical Propertiesclear colorless liquid
Chemical PropertiesEthyl 2-methylbutyrate has a powerful, green-fruity, apple-like odor.
Chemical PropertiesEthyl 2-Methylbutyrate is a liquid with a green, fruity odor reminiscent of apples. It is found, for example, in citrus fruits and wild berries and is used in fruit flavor compositions.
OccurrenceReported found in nature; the ethyl l-methylbutyrate has been identified in strawberry juice; because of the presence of the asymmetric carbon, the compound should exhibit optically active forms as well as the racemic form; however, only the d-form and the racemic form are known. Reported found in apple juice, orange and grapefruit juice, bilberry, pineapple, strawberry, cheeses, milk, cognac, rum, whiskey, cider, mango, mountain papaya, spineless monkey orange (Strychnos madagasc.), Chinese quince and German chamomile oil.
UsesEthyl 2-Methylbutyrate-d9 is deuterium labelled ethyl 2-methylbutyrate, which is an ester that has a sweet, apple-like aroma. Ethyl 2-methylbutyrate is naturally found in apples, cherries and orange juice.
DefinitionChEBI: Ethyl 2-methylbutyrate is a fatty acid ethyl ester obtained by the formal condensation of 2-methylbutyric acid with ethanol. It is a constituent of the aroma of wines, strawberries, blueberries, and apples. It has a role as a flavouring agent, a plant metabolite, a human metabolite and a fragrance. It is a volatile organic compound and a fatty acid ethyl ester. It is functionally related to an ethanol and a 2-methylbutyric acid.
PreparationThe racemic form can be prepared catalytically by several methods: from butene and Ni(CO)4 under nitrogen in ethyl alcohol/acetic acid solution, or from ethylene and CO under pressure using HBF4 and HF as catalysts.
Aroma threshold valuesDetection: 0.01 to 0.1 ppb
Taste threshold valuesTaste characteristics at 40 ppm: fruity, green, berry, strawberry, fresh apple, pineapple and raspberry
General DescriptionA colorless oily liquid with a fruity odor. Insoluble in water and less dense than water. Flash point 73°F. Contact may irritate skin, eyes and mucous membranes.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileETHYL-2-METHYL BUTYRATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Flammability and ExplosibilityNon flammable
Safety ProfileCombustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
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