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Palladium chloride

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Products Intro: Product Name:Palladium chloride
CAS:7647-10-1
Purity:99%,99.5% Package:1kg,10kg,25kg
Company Name: Henan Tianfu Chemical Co.,Ltd.
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Products Intro: CAS:7647-10-1
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Shanghai Bojing Chemical Co.,Ltd.
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Products Intro: Product Name:Palladium chloride
CAS:7647-10-1
Purity:52% Package:1kg;25kg;200kg Cardboard barrels Remarks:Red brown powder
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55541817
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Products Intro: Product Name:Palladium Chloride
CAS:7647-10-1
Purity:59.99% Package:100grams;500grams;1kg;5kg;10kg;25kg
Company Name: Richest Group Limited  Gold
Tel:+86 21 5017 5386/3175 7285/86/87/88/89
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Products Intro:Product Name:PalladiuM chloride
CAS:7647-10-1
Purity:99% HPLC Package:500g,1kg,5kg,25kg,100kg
Palladium chloride Chemical Properties
Melting point 678-680 °C(lit.)
density 4 g/mL at 25 °C(lit.)
storage temp. Store below +30°C.
solubility 55.6g/l insoluble
form Powder/Solid
color Yellow
PH2.15 (30g/l, H2O, 20℃)
Water Solubility Insoluble
Merck 14,6990
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference7647-10-1(CAS DataBase Reference)
EPA Substance Registry SystemPalladium chloride (PdCl2)(7647-10-1)
Safety Information
Hazard Codes C,Xi,T+,T,Xn
Risk Statements 34-43-40-28-41-37/38-25-22
Safety Statements 26-36/37/39-45-37/39-28-27-36/37-27/28
RIDADR UN 1789 8/PG 3
WGK Germany 2
RTECS RT3500000
3
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 28439090
Hazardous Substances Data7647-10-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Palladium (II) chloride English
SigmaAldrich English
ACROS English
ALFA English
Palladium chloride Usage And Synthesis
DescriptionPalladium chloride is a commonly used precious metal catalysts, molecular formula is PaCl2, the appearance is brown-red needle-like crystals or powder, easily deliquescence, the relative density is 4.0 (18 ℃), melting point is 500 ℃ (decomposition), soluble in water, ethanol, acetone and hydrogen bromide. Decomposition in ammonia chloride, potassium iodide, ammonia solution, and precipitation of palladium.
[Uses]
(1)used as the analysis reagents, such as determination of trace palladium, mercury, thallium, iodine, etc.
(2) palladium test strips is used to test carbon monoxide.
(3) also used to search for cracks of buried underground gas pipeline cracks, study of agricultural plant resources, preparation of palladium catalyst, electroplating watch parts and photography, and so on.
[Preparation method] by melting palladium dichloride hydrate, make it lost part of chloride to get Palladium chlorine finished products.
the molecular structure of Palladium chloride
Figure 1 the molecular structure of Palladium chloride.
Chemical PropertiesRed-brown powder
UsesPalladium dichloride is a starting material for preparing several palladium compounds. It also is used for detection of carbon monoxide. For such detection, a paper is soaked in very dilute solution of PdCl2 which is decolorized by CO, methane and other reducing substances. It also is used in toning and electroplating solutions and in photography for porcelain pictures.
Usessuzuki reaction
Production MethodsThe palladium powder is added to the reactor containing hydrochloric acid, with stirring, passing the air, an oxidation reaction is performed, generating palladium chloride solution, the solution is purified, filtered, concentrated by evaporation, cooling and crystallization, centrifugal separation, and dried to obtain a palladium chloride finished products.
Pd+2HCl+0.5O2→PdCl2+H2O
ReactionsPalladium dichloride dissolves in HCl forming tetrachloropalladate ion,
PdCl2+2Cl¯→ [PdCl4]2¯
The complex ion catalyzes various types of organic reactions including oxidation of ethylene to acetaldehyde in aqueous solution (the Wacker Process):
PdCl42¯+ C2H4 + H2O → CH3CHO + Pd + 2HCl + 2Cl¯
Palladium dichloride forms polymeric carbonyl complexes when the dry chloride is heated in a stream of carbon monoxide charged with methane vapor. Such complexes include [PdCl2(CO)n] and [PdCl(CO)2]n. The reaction also occurs in aqueous phase resulting in decolorization of the solution.
When H2S is passed through palladium dichloride solution, it yields a brown-black precipitate of palladium monosulfide, PdS.
When heated with sulfur at 450 to 500°C, palladium dichloride forms palladium disulfide, PdS2, a grey-black crystalline compound, insoluble in strong acids but soluble in aqua regia, and which converts to monosulfide, PdS, on heating at 600°C.
When ammonia gas is passed through an aqueous solution of PdCl2, the product is tetrammine palladium(II) chloride, Pd(NH4)2Cl2. The same product also is obtained in dry state by passing ammonia gas over anhydrous PdCl2.
General DescriptionDark brown crystals.
Air & Water ReactionsDeliquescent. Water soluble.
Reactivity ProfilePalladium chloride is a weak oxidizing agent. Palladium chloride is reduced in solution by hydrogen or carbon monoxide to metallic palladium. . Decomposed at high temperatures to metallic palladium and chlorine.
Fire HazardFlash point data for Palladium chloride are not available. Palladium chloride is probably combustible.
Palladium chloride Preparation Products And Raw materials
Raw materialsEtanol-->Dichloromethane-->Toluene-->Palladium-->Acetonitrile-->PALLADIUM ON STRONTIUM CARBONATE, REDUCED
Preparation ProductsPalladium diacetate-->Vinyl acetate-->Tetrakis(triphenylphosphine)palladium-->Acetaldehyde-->Propionaldehyde-->Diphenylacetylene-->1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, -->TERT-BUTYL 5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)ISOINDOLINE-2-CARBOXYLATE-->3-Aminobenzoic acid-->Tris(dibenzylideneacetone)dipalladium-chloroform adduct-->6-Hydroxyindole-->3-Acetyl-1-propanol-->n-Butyl vinyl ether-->3-PYRIDIN-4-YL-BENZOIC ACID-->[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)-->Bis(triphenylphosphine)palladium(II) chloride-->3-aminopropanamide-->6-METHYL-3-(1H)INDAZOLE CARBOXYLIC ACID-->N-(4-THIOPHEN-2-YL-PHENYL)-ACETAMIDE-->3-CYANO-6-METHYL (1H)INDAZOLE-->6-Benzyloxyindole-->Bis(tri-tert-butylphosphine)palladium(0)-->DICHLOROBIS(TRICYCLOHEXYLPHOSPHINE)PALLADIUM(II)-->Bis(dibenzylideneacetone)palladium-->palladium catalyst supported by poly (2, 6-dimethyl-1, 4-phenylene oxide)-->4-(3-THIENYL)BENZALDEHYDE-->Tris(dibenzylideneacetone)dipalladium-->N,N,N',N'-TETRAMETHYL-2-BUTENE-1,4-DIAMINE-->Daltroban-->2-Methyltetrahydrofuran-->2-chloro-3-oxopentyl acetate -->1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex-->Bis(2,4-pentanedionato-O,O')palladium(II)-->[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)-->Dichloro(1,5-cyclooctadiene)palladium(II)-->4-OXOPENTYL ACETATE-->Bis(benzonitrile)palladium chloride-->Quinazoline, 2-methyl- (6CI,7CI,8CI,9CI)-->Bis(acetonitrile)dichloropalladium(II)-->Albuterol sulfate
Tag:Palladium chloride(7647-10-1) Related Product Information
DICHLOROBIS(TRICYCLOHEXYLPHOSPHINE)PALLADIUM(II) Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2,Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane LITHIUM TETRACHLOROPALLADATE(II) HYDRATE DICHLORO[1,2-BIS(DIMETHYLPHOSPHINO)ETHANE]PALLADATE (II) Dipotassium hexachloropalladate Sodium tetrachloropalladate(II) LITHIUM TETRACHLOROPALLADATE(II) AMMONIUM PALLADIUM(II) CHLORIDE Potassium chloropalladite DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II) Ammonium chloride Sodium chloride 4-(DICYANOMETHYLENE)-2-METHYL-6-(JULOLIDIN-4-YL-VINYL)-4H-PYRAN Palladium chloride Etanol Palladium Calcium chloride CHLORIDE STANDARD