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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

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Products Intro: Product Name:Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
CAS:12354-85-7
Purity:98% Min. Package:1G;1KG;100KG
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Products Intro: Product Name:Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
CAS:12354-85-7
Purity:99% Package:100g ;1KG ;5KG 25KG Remarks:Catalysts
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CAS:12354-85-7
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CAS:12354-85-7
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Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information
Reaction
Product Name:Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms:Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium;Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE;DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER;BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM];PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&;Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer;Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
CAS:12354-85-7
MF:C20H30Cl4Rh210*
MW:618.08
EINECS:
Product Categories:metallocene;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Rh
Mol File:12354-85-7.mol
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Structure
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties
Melting point >300°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Sparingly), Methanol (Slightly)
form crystal
color red
Water Solubility Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:Hygroscopic
NIST Chemistry ReferenceRhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements 26-36-S36-S26-24/25
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis
Reaction
  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
Reactions of 12354-85-7_1
Reactions of 12354-85-7_2
Chemical Propertiesburgundy solid
UsesDichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.
UsesOxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials
Tag:Bis[(pentamethylcyclopentadienyl)dichloro-rhodium](12354-85-7) Related Product Information
DILINOLEIC ACID Sodium chloride alpha,alpha'-Dichloro-p-xylene 1,2,3,4,5-Pentamethylcyclopentadiene 1,3-Cyclopentadiene Dichloroacetic acid SODIUM CYCLOPENTADIENIDE Tetraphenylcyclopentadienone METHYLCYCLOPENTADIENE DIMER 2-Chloro-5-chloromethylpyridine Choline chloride Dichloromethylphenylsilane Ammonium chloride Rhodium Dichlorodimethylsilane (Pentamethylcyclopentadienyl)iridium(III) chloride dimer (1R,3S,5R)-2-(tert-butoxycarbonyl)-5-methyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid (R)-3-(4'-bromophenyl)-3-hydroxypropanenitrile