アクリル酸2-ヒドロキシエチル(818-61-1)

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アクリル酸2-ヒドロキシエチル 製品概要
化学名:アクリル酸2-ヒドロキシエチル
英語化学名:2-Hydroxyethyl acrylate
别名:2-Hydroxyethylester kyseliny akrylove;2-hydroxyethylesterkyselinyakrylove;2-Propenoicacid,2-hydroxyethylester;beta-Hydroxyethyl acrylate;Bisomer 2HEA;bisomer2hea;2-HYDROXYETHYL ACRYLATE, STAB.;2-Hydroxyethyl acrylate, stabilized, 97%
CAS番号:818-61-1
分子式:C5H8O3
分子量:116.12
EINECS:212-454-9
カテゴリ情報:monomer;Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols;818-61-1;T0001
Mol File:818-61-1.mol
アクリル酸2-ヒドロキシエチル
アクリル酸2-ヒドロキシエチル 物理性質
融点 -60 °C
沸点 90-92 °C12 mm Hg(lit.)
比重(密度) 1.106 g/mL at 20 °C
蒸気密度>1 (vs air)
蒸気圧<0.1 mm Hg ( 20 °C)
屈折率 n20/D 1.45(lit.)
闪点 209 °F
貯蔵温度 2-8°C
外見 Oily Liquid
酸解離定数(Pka)13.85±0.10(Predicted)
Yellow to brown
水溶解度 soluble
Sensitive Light Sensitive
BRN 969853
暴露限界値ACGIH: TWA 5 mg/m3
NIOSH: TWA 5 mg/m3
InChIKeyOMIGHNLMNHATMP-UHFFFAOYSA-N
LogP-0.17 at 25℃
CAS データベース818-61-1(CAS DataBase Reference)
NISTの化学物質情報2-Propenoic acid, 2-hydroxyethyl ester(818-61-1)
EPAの化学物質情報2-Hydroxyethyl acrylate (818-61-1)
安全性情報
主な危険性 T,N
Rフレーズ 24-34-43-50-20/22-22
Sフレーズ 26-36/39-45-61-36/37/39
RIDADR UN 2927 6.1/PG 2
WGK Germany 3
RTECS 番号AT1750000
8
TSCA Yes
国連危険物分類 8
容器等級 II
HSコード 29161290
有毒物質データの818-61-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
2-Hydroxyethyl acrylate English
SigmaAldrich English
ACROS English
ALFA English
アクリル酸2-ヒドロキシエチル Usage And Synthesis
外観無色~わずかにうすい黄色, 澄明の液体
定義本品は、次の化学式で表される有機化合物である。
溶解性水に極めて溶けやすく、エタノール及びアセトンに溶ける。
用途有機合成原料。
用途親水性アクリルポリマー用のコモノマー (共重合体は塗料、接着剤、繊維加工剤)
主な用途/役割アクリル樹脂原料、反応性アクリル樹脂系接着剤に使用される。
使用上の注意安定剤(重合禁止剤)としてヒドロキノンモノメチルエーテル約0.03%添加。
説明2-Hydroxyethyl acrylate (HEA) forms homopolymers and copolymers. HEA is used mainly either as a co-monomer in the manufacture of polymers or as a chemical reactant in the manufacture of chemical intermediates. In the manufacture of polymers, HEA can be co-polymerized with acrylic acid, acrylates, methacrylates, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, and the like. Co-reactants with HEA include aromatic and aliphatic isocyanates, anhydrides, and epoxides. The polymers and chemical intermediates made with HEA find applications in automotive top coatings, architectural coatings, photocure resins, and adhesives. Globally about half of the HEA produced is used in the production of acrylic enamels for the automotive industry, where a clear topcoat is applied to a pigmented base coat to increase corrosion protection and durability.
化学的特性Hydroxyethyl acrylate is a clear colorless liquid. miscible with water, soluble in general organic solvents. The commodity generally contains 400ppm of hydroquinone methylether, a polymerization inhibitor. Hydroxyethyl acrylate is a difunctional acrylate monomer with the characteristic high reactivity. Hydroxyethyl acrylate is used in a crylics for coatings, adhesives and UV reacitve oligomers. It can be used for crosslinking with isocyantes or melamines.
使用2-Hydroxyethyl acrylate is an acrylic monomer for use in UV inks, adhesives, lacquers, artificial nails, etc.
使用As a reactive monomer 2-Hydroxyethyl acrylate is used as a crosslinking agent for resins, plastics and rubber modifiers. Further, it is used in the synthesis of amphilic block copolymers by nitroxide mediated living radical polymerization. In addition to this, it is used to prepare tuned poly(hydroxyethyl acrylate) by atom transfer radical polymerization.
定義ChEBI: 2-Hydroxyethyl acrylate is a functional monomer for the manufacture of thermosetting acrylic resins.
一般的な説明A clear colorless liquid. Less dense than water. Vapors heavier than air. Corrosive to tissue. Flash point 120°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Used to make plastics.
空気と水の反応Flammable. Slightly soluble in water.
反応プロフィールA functional monomer of thermosetting acrylic resins.
健康ハザードInhalation causes irritation of nose and throat. Contact with liquid irritates eyes and skin.
火災危険Behavior in Fire: Containers may explode
燃焼性と爆発性Non flammable
職業ばく露2-Hydroxyethyl acrylate is contained in Lowicryl 4KM and K11M resins. It caused contact dermatitis in workers embedding media for electron microscopy. It may also be contained in ultraviolet-curable nail gel used for photobonded sculptured nails.
Tags:818-61-1