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Diethyl 1,1-cyclopropanedicarboxylate

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Products Intro: Product Name:Diethyl 1,1-cyclopropanedicarboxylate
CAS:1559-02-0
Purity:99% Package:25KG
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Products Intro: Product Name:Diethyl cyclopropane-1,1-dicarboxylate
CAS:1559-02-0
Purity:NLT 98% Package:1G;1KG;100KG
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CAS:1559-02-0
Purity:99% Package:1KG;5KG ;10KG
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Products Intro: Product Name:TIANFU CHEM -- Diethyl 1,1-cyclopropanedicarboxylate
CAS:1559-02-0
Purity:99% Package:25KG;5KG;1KG
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CAS:1559-02-0
Purity:As coa Package:As request Remarks:1559-02-0

Diethyl 1,1-cyclopropanedicarboxylate manufacturers

Diethyl 1,1-cyclopropanedicarboxylate Basic information
Product Name:Diethyl 1,1-cyclopropanedicarboxylate
Synonyms:RARECHEM AL BO 0836;CYCLOPROPANE-1,1-DICARBOXYLIC ACID DIETHYL ESTER;DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE;DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE, 9 7%;DiethyldifluoroMalonate96%;1,1-Bis(ethoxycarbonyl)cyclopropane;Ethyl 1,1-cyclopropanedicarboxylate;DIETHYL 1,1-CYCLOPROPANE-DICARBONYLATE
CAS:1559-02-0
MF:C9H14O4
MW:186.21
EINECS:216-321-6
Product Categories:Building Blocks;C8 to C9;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Aliphatics;Cyclopropanes;Simple 3-Membered Ring Compounds;Cycloalkanes;C8 to C9;Carbonyl Compounds;Esters;bc0001
Mol File:1559-02-0.mol
Diethyl 1,1-cyclopropanedicarboxylate Structure
Diethyl 1,1-cyclopropanedicarboxylate Chemical Properties
Melting point 134-136 °C(lit.)
Boiling point 94-96 °C/10 mmHg (lit.)
density 1.055 g/mL at 25 °C (lit.)
refractive index n20/D 1.433(lit.)
Fp 188 °F
storage temp. Sealed in dry,Room Temperature
solubility Acetone (Slightly), Chlorform (Slightly), Methanol (Slightly)
form Liquid
color Clear colorless
BRN 2049509
CAS DataBase Reference1559-02-0(CAS DataBase Reference)
NIST Chemistry ReferenceDiethyl 1,1-cyclopropanedicarboxylate(1559-02-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25-23
RIDADR UN 3261 8/PG 2
WGK Germany 3
HazardClass IRRITANT
HS Code 29172090
MSDS Information
ProviderLanguage
Diethyl 1,1-cyclopropanedicarboxylate English
SigmaAldrich English
ACROS English
ALFA English
Diethyl 1,1-cyclopropanedicarboxylate Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesDiethyl 1,1-Cyclopropanedicarboxylate (cas# 1559-02-0) is a compound useful in organic synthesis.
Synthesis Reference(s)Synthesis, p. 690, 1980 DOI: 10.1055/s-1980-29171
General DescriptionDiethyl cyclopropane-1,1-dicarboxylate participates in ring-opening addition reactions with various nucleophilic reagents.
Purification MethodsIf it is free from OH bands in the IR, then fractionally distil the ester and redistil the middle fraction. Otherwise shake it with aqueous NaHCO3, dry it (MgSO4), filter and distil as before or re-esterify it. [As synthon see Danishefsky Acc Chem Res 12 66 1979, Beilstein 9 I 314, 9 II 512, 9 III 3595, 9 IV 2786.]
Tag:Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0) Related Product Information
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