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Ethyl 3-methyl-3-phenylglycidate

Ethyl 3-methyl-3-phenylglycidate Suppliers list
Company Name: Changzhou AniKare Pharmatech Co., Ltd.
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Products Intro: Product Name:Strawberry Aldehyde
CAS:77-83-8
Purity:99% Package:1kg??25kg
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Products Intro: Product Name:Ethyl 3-methyl-3-phenylglycidate
CAS:77-83-8
Purity:99% Package:25KG
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Products Intro: Product Name:Strawberry aldehyde
CAS:77-83-8
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Products Intro: Product Name:ethyl 3-methyl-3-phenylglycidate
CAS:77-83-8
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Products Intro: Product Name:77-83-8
CAS:77-83-8
Purity:99% Package:25KG;5KG;1KG

Ethyl 3-methyl-3-phenylglycidate manufacturers

  • Strawberry aldehyde
  • Strawberry aldehyde pictures
  • $1.00 / 1kg
  • 2023-09-07
  • CAS:77-83-8
  • Min. Order: 1kg
  • Purity: 99%
  • Supply Ability: 20tons
Ethyl 3-methyl-3-phenylglycidate Basic information
Product Name:Ethyl 3-methyl-3-phenylglycidate
Synonyms:2,3-Epoxy-3-phenylbutyric acid, ethyl ester;3-methyl-3-phenyl-oxiranecarboxylicacid,ethylester;3-methyl-3-phenyl-oxiranecarboxylicacidethylester;3-methyl-3-phenyl-oxiranecarboxylicaciethylester;alpha,beta-Epoxy-beta-methylhydrocinnamic acid, ethyl ester;alpha,beta-epoxy-beta-methylhydrocinnamicacid,ethylester;alpha,beta-epoxy-beta-methyl-hydrocinnamicaciethylester;EMPG
CAS:77-83-8
MF:C12H14O3
MW:206.24
EINECS:201-061-8
Product Categories:
Mol File:77-83-8.mol
Ethyl 3-methyl-3-phenylglycidate Structure
Ethyl 3-methyl-3-phenylglycidate Chemical Properties
Boiling point 272-275 °C(lit.)
density 1.087 g/mL at 25 °C(lit.)
FEMA 2444 | ETHYL METHYLPHENYLGLYCIDATE
refractive index n20/D 1.505(lit.)
Fp >230 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
Odorat 100.00 %. sweet fruity strawberry floral honey fatty
Odor Typefruity
JECFA Number1577
BRN 12299
LogP2.43
CAS DataBase Reference77-83-8(CAS DataBase Reference)
NIST Chemistry ReferenceGlycidic acid, 3-methyl-3-phenyl, ethyl ester(77-83-8)
EPA Substance Registry SystemEthyl methylphenylglycidate (77-83-8)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 16-26-36/37/39
RIDADR UN 1993 3/PG 3
WGK Germany 2
RTECS MW5250000
TSCA Yes
HS Code 29189090
Hazardous Substances Data77-83-8(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 5470 mg/kg
MSDS Information
ProviderLanguage
3-Methyl-3-phenyl glycidic acid ethyl ester English
SigmaAldrich English
ACROS English
ALFA English
Ethyl 3-methyl-3-phenylglycidate Usage And Synthesis
Chemical PropertiesEthyl methylphenylglycidate on dilution has a strong fruity odor suggestive of strawberry. It has a characteristic, slightly acid taste reminiscent of strawberry.
Chemical Propertiesclear yellow liquid
Chemical PropertiesPerennial, herbaceous plant; grows wild or cultivated in central–southern Europe, North America and Asia. The plant grows 10 to 20 cm (4 to 8 in.) in height and has thick rhizomes; radical leaves with long, small, white flowers blossoming from April to July; and fleshy, ovoidal, red berries covered with numerous achenes. The only part used is the berries. Strawberry has a sweet–sour taste and a characteristic odor.
Chemical PropertiesEthyl 3-Methyl-3-phenylglycidate exists as two optically active pairs of cis- and trans-isomers; each isomer has a characteristic odor . The commercial product is a racemic mixture of all four isomers and has a strong, sweetish, strawberry odor. The cis/trans ratio obtained in the Darzens condensation of acetophenone (R==CH3) and ethyl chloroacetate depends on the base used in the reaction.
OccurrenceHas apparently not been reported to occur in nature.
UsesEthyl 3-Methyl-3-phenylglycidate, also known as “strawberry aldehyde”, is commonly used in the flavor industry for artificial fruit flavors, in particular strawberry.
UsesEthyl 3-methyl-3-phenylglycidate is a synthetic flavoring agent that is a glycidic acid ester. It is a colorless to pale yellow liquid with a strong fruit odor suggestive of strawberries. It is unstable to alkali and moderately stable to weak organic acids. It should be stored in glass, tin, or aluminum containers. It is soluble in fixed oils and in propylene glycol. It is used in flavors for strawberry note and has application in candy, beverages, and ice cream at 6–20 ppm. It is also termed aldehyde c-16.
UsesPerfumery, flavors.
DefinitionChEBI: Phenylmethylglycidic ester is a carboxylic acid and an epoxide.
PreparationBy reaction of acetophenone and the ethyl ester of monochloroacetic acid in the presence of an alkaline condensing agent.
CompositionStrawberry aroma has been the subject of extensive investigation. Several components have been identified, of which only 7% appear to be responsible for the aroma. Strawberry aroma varies widely with the strawberry variety. The most valuable part, aroma, is from wild strawberry.
Aroma threshold valuesDetection: 2 ppm
Taste threshold valuesTaste characteristics at 1 and 5% sucrose: sweet, ripe, strawberry jam and preserve notes.
Taste threshold valuesTaste characteristics at 50 ppm: sweet, berry, strawberry, fruity, tutti-frutti and floral nuances
General DescriptionClear, colorless to yellowish liquid with a strawberry-like odor.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileEsters, such as Ethyl 3-methyl-3-phenylglycidate, react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Fire HazardEthyl 3-methyl-3-phenylglycidate is probably combustible.
Trade nameStrawberry pure (Givaudan)
Safety ProfileMddly toxic by ingestion. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
Ethyl 3-methyl-3-phenylglycidate Preparation Products And Raw materials
Raw materialsXylene-->Sodium ethoxide-->Ethyl chloroacetate-->Acetophenone-->Sodium amide-->Propiophenone
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