9-フルオレニルメタノール(24324-17-2)

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9-フルオレニルメタノール 製品概要
化学名:9-フルオレニルメタノール
英語化学名:9-Fluorenemethanol
别名:TIMTEC-BB SBB008508;AKOS MSC-0133;Fmoc-Oh(9-Fluorenylmethanol);9-Fluorenylmethanol,98+%;9-FLUORENYLMENTHANOL;Fmoc (9-Fluorenemethanol);9-Fluorenemethanol (FMOH);9-FLUOROENYLMETHANOL
CAS番号:24324-17-2
分子式:C14H12O
分子量:196.24
EINECS:246-167-5
カテゴリ情報:Fluorenes;Fluorenes & Fluorenones;Amino alcohols;Alkohols;N-Protecting Reagents;Fluorene Derivatives;Peptide coupling agents;Amino Acid Derivatives;Benzocycles;Fluorenes, Flurenones
Mol File:24324-17-2.mol
9-フルオレニルメタノール
9-フルオレニルメタノール 物理性質
融点 105-107 °C (lit.)
沸点 293.14°C (rough estimate)
比重(密度) 1.0304 (rough estimate)
屈折率 1.5385 (estimate)
貯蔵温度 Sealed in dry,Room Temperature
溶解性Soluble in methanol.
酸解離定数(Pka)13.68±0.10(Predicted)
外見 Crystalline Powder
White to pale yellow
BRN 2330017
CAS データベース24324-17-2(CAS DataBase Reference)
NISTの化学物質情報Fluorene-9-methanol(24324-17-2)
EPAの化学物質情報9H-Fluorene-9-methanol (24324-17-2)
安全性情報
主な危険性 Xi
Rフレーズ 36/37/38
Sフレーズ 22-24/25-36/37/39-27-26
WGK Germany 3
Hazard Note Irritant
TSCA Yes
HSコード 29062900
MSDS Information
ProviderLanguage
Fluorene-9-methanol English
SigmaAldrich English
ACROS English
ALFA English
9-フルオレニルメタノール Usage And Synthesis
外観白色〜赤褐色, 結晶〜結晶性粉末
溶解性エタノール及びアセトンに溶け、水にほとんど溶けない。
用途有機合成原料、ペプチド合成保護試薬。
化学的特性WHITE TO PALE YELLOW CRYSTALLINE POWDER
使用9-Fluorenemethanol, N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates.
使用9-Fluorenylmethanol acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film.
一般的な説明Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.
Tags:24324-17-2