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4-Cyanopyridine(100-48-1)

4-Cyanopyridine(100-48-1)
Product IdentificationBack to Contents
【Product Name】

4-Cyanopyridine
【Synonyms】

4-Cyanopyridine
Isonicotinonitrile
【CAS】

100-48-1
【Formula】

C6H4N2
【Molecular Weight】

104.11
【EINECS】

202-856-2
【Beilstein/Gmelin】

107712
【Beilstein Reference】

5-22-02-00214
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

White to light yellow crystalline solid.
【Solubility in water】

32 g/L
【Melting Point】

78 - 80
【Boiling Point】

195.4
【Vapor Pressure】

0.4 (25 C)
【pKa/pKb】

12.08 (pKb)
【Partition Coefficient】

.41
【Heat Of Vaporization】

43.3 kJ/mol
【Heat Of Combustion】

-3143 kJ/mol
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Ingestion】

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
【Skin】

May cause skin irritation. Harmful if absorbed through the skin.
【Eyes】

May cause severe eye irritation.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 22 36/37/38
【EC Safety Phrase】

S 26 36/37/39
【UN (DOT)】

2811
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Fire Fighting MeasuresBack to Contents
【Flash Point】

83
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

6
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents - strong acids - strong bases.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2811
【Hazard Class】

6.1
【Packing Group】

I; II; III
【HS Code】

2933 39 99
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