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ChemicalBook >>Dess-Martin periodinane>>(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one(87413-09-0)

(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one(87413-09-0)

(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one(87413-09-0)
Product IdentificationBack to Contents
【Product Name】

(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
【Synonyms】

1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Triacetoxyperiodinane
【CAS】

87413-09-0
【Formula】

C13H13IO8
【Molecular Weight】

424.15
【Merck】

13,2950
【Beilstein/Gmelin】

4548207
Physical and Chemical PropertiesBack to Contents
【Melting Point】

133
【Usage】

Reagent for the selective oxidation of primary and secondary alcohols.
First Aid MeasuresBack to Contents
【Ingestion】

Seek medical assistance.
【Inhalation】

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
【Skin】

Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush with running water for at least 20 minutes.
【Eyes】

In case of contact with substance, immediately flush with running water for at least 20 minutes.
Hazards IdentificationBack to Contents
【Ingestion】

Ingestion may cause severe injury, burns, or death.
【Inhalation】

Vapors may cause injury, burns, death.
【Skin】

Contact may result in injury, burns and death.
【Eyes】

See Skin.
【Hazards】

May explode from heat or contamination. May react explosively with hydrocarbons (fuels). May ignite combustibles.
【EC Risk Phrase】

R 5 8 36/37/38
【EC Safety Phrase】

S 7/8 26 36/37/39
【UN (DOT)】

1479
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Wear appropriate protective gloves, clothing and goggles.
【Respirators】

Wear positive pressure self-contained breathing apparatus (SCBA).
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Small Fires: Use water. Do not use dry chemicals or foams. carbon dioxide or Halon may provide limited control. Large Fires: Flood fire area with water from a distance.
【Fire Potential】

These substances will accelerate burning when involved in a fire.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Keep away from combustible materials. Avoid contact unless wearing appropriate protective clothing. Stop leak if you can do it without risk. With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.
Transport InformationBack to Contents
【UN Number】

1479
Stability and ReactivityBack to Contents
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
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