| Product Identification | Back to Contents | 【Product Name】
1-Chloro-3-isocyanato-benzene | 【Synonyms】
3-Chloroisocyanatobenzene
Benzene, 1-chloro-3-isocyanato-
Isocyanic acid, m-chlorophenyl ester
m-Chlorophenyl isocyanate | 【CAS】
2909-38-8 | 【Formula】
C7H4ClNO | 【Molecular Weight】
153.57 | 【EINECS】
220-822-5 | 【RTECS】
NQ8560000 | 【RTECS Class】
Other | 【Beilstein/Gmelin】
742445 | 【Beilstein Reference】
4-12-00-01156 |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Colorless liquid with an irritating odor. | 【Solubility in water】
Insoluble | 【Melting Point】
-4.4 | 【Boiling Point】
202 | 【Vapor Pressure】
0.3 (25 C) | 【Density】
1.260 g/cm3 (20 C) | 【Partition Coefficient】
3.3 | 【Heat Of Vaporization】
43.9 kJ/mol | 【Vapor Density】
5.3 | 【Refractive Index】
1.5578 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. |
| Handling and Storage | Back to Contents | 【Storage】
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Hazards Identification | Back to Contents | 【Inhalation】
Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Can produce delayed pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation. | 【Skin】
Causes skin irritation. May cause irritation and dermatitis. May cause cyanosis of the extremities. | 【Eyes】
Causes eye irritation. Lachrymator. May cause chemical conjunctivitis and corneal damage. May cause chemical conjunctivitis. | 【Ingestion】
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. | 【Hazards】
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. | 【EC Risk Phrase】
R 26 36/37/38 42 | 【EC Safety Phrase】
S 23 26 36/37/39 45 | 【UN (DOT)】
2206 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear chemical goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
Effects may be delayed. | 【Poison Class】
2 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
86 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. In case of fire, use carbon dioxide or dry chemical. | 【Fire Potential】
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. |
| Stability and Reactivity | Back to Contents | 【Stability】
Stable under normal temperatures and pressures. Stable at room temperature in closed containers under normal storage and handling conditions. | 【Incompatibilities】
Strong oxidizing agents, alcohols, amines, strong bases, acids, heat. | 【Decomposition】
Hydrogen chloride, hydrogen cyanide, carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide. | 【Combustion Products】
Fire will produce irritating, corrosive and/or toxic gases. |
|
| Company Name: |
J & K SCIENTIFIC LTD. |
| Tel: |
010-82848833 400-666-7788 |
| Fax: |
86-10-82849933 |
| WebSite: |
http://www.jkchemical.com |
| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Fax: |
021-67582001/03/05 |
| WebSite: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical |
| Tel: |
021-021-58432009 400-005-6266 |
| Fax: |
021-58436166 |
| WebSite: |
http://www.energy-chemical.com |
|