Product Identification | Back to Contents | 【Product Name】
4-Amino-3-bromotoluene | 【Synonyms】
2-Bromo-4-methylbenzenamine 2-Bromo-4-methylphenylamine 2-Bromo-4-toluidine 3-Bromo-4-aminotoluene 4-Amino-3-bromotoluene o-Bromo-p-toluidine | 【CAS】
583-68-6 | 【Formula】
C7H8BrN | 【Molecular Weight】
186.06 | 【EINECS】
209-515-7 | 【RTECS】
XU4300000 | 【RTECS Class】
Mutagen | 【Beilstein/Gmelin】
1931711 | 【Beilstein Reference】
4-12-00-01992 | 【EC Class】
irritant |
Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear brown liquid. | 【Solubility in water】
Insoluble | 【Melting Point】
26 | 【Boiling Point】
240 | 【Vapor Pressure】
0.04 (25 C) | 【Density】
1.498 g/cm3 (20 C) | 【pKa/pKb】
11.03 (pKb) | 【Partition Coefficient】
2.65 | 【Heat Of Vaporization】
47.7 kJ/mol | 【Vapor Density】
6.4 | 【Refractive Index】
1.5999 (20 C) |
First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. |
Handling and Storage | Back to Contents | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | 【Handling】
Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse. |
Hazards Identification | Back to Contents | 【Inhalation】
Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause cardiac abnormalities. Can produce delayed pulmonary edema. | 【Skin】
Causes skin irritation. | 【Eyes】
Causes eye irritation. May cause chemical conjunctivitis. | 【Ingestion】
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause central nervous system depression. May cause cardiac abnormalities. | 【Hazards】
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. | 【EC Risk Phrase】
R 20/21/22 33 | 【EC Safety Phrase】
S 28 36/37 | 【UN (DOT)】
2810 |
Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed. |
Fire Fighting Measures | Back to Contents | 【Flash Point】
102 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out. | 【Fire Potential】
Combustible material: may burn but does not ignite readily. |
Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. |
Stability and Reactivity | Back to Contents | 【Incompatibilities】
Oxidizing agents. | 【Stability】
Stable at room temperature in closed containers under normal storage and handling conditions. | 【Decomposition】
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, nitrogen. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. |
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Company Name: |
J & K SCIENTIFIC LTD. |
Tel: |
010-82848833 400-666-7788 |
Fax: |
86-10-82849933 |
WebSite: |
http://www.jkchemical.com |
Company Name: |
Alfa Aesar |
Tel: |
400-6106006 |
Fax: |
021-67582001/03/05 |
WebSite: |
http://chemicals.thermofisher.cn |
Company Name: |
Energy Chemical |
Tel: |
021-021-58432009 400-005-6266 |
Fax: |
021-58436166 |
WebSite: |
http://www.energy-chemical.com |
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