ChemicalBook >>Benzoxazole>>Benzoxazole(273-53-0)

Benzoxazole(273-53-0)

Benzoxazole(273-53-0)
Product IdentificationBack to Contents
【Product Name】

Benzoxazole
【Synonyms】

1,3-Benzoxazole
1-Oxa-3-aza-1H-indene
1-Oxa-3-azaindene
【CAS】

273-53-0
【Formula】

C7H5NO
【Molecular Weight】

119.12
【EINECS】

205-988-9
【RTECS】

DM4375000
【RTECS Class】

Drug
【Beilstein/Gmelin】

109467
【Beilstein Reference】

4-27-00-01069
Physical and Chemical PropertiesBack to Contents
【Appearance】

Yellow orange solid.
【Solubility in water】

Slightly soluble
【Melting Point】

28 - 30
【Boiling Point】

182 - 185
【Vapor Pressure】

1.1 (25 C)
【Density】

1.1754 g/cm3 (20 C)
【pKa/pKb】

13.2 (pKb)
【Partition Coefficient】

1.59
【Heat Of Vaporization】

40.2 kJ/mol
【Heat Of Combustion】

-3445 kJ/mol
【Usage】

A starting material for the synthesis of larger, usually bioactive structures.
【Refractive Index】

1.5594 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Refrigerator (approx 4 C).
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
【Skin】

May cause irritation and dermatitis. May cause cyanosis of the extremities.
【Eyes】

May cause eye irritation. May cause chemical conjunctivitis and corneal damage.
【EC Risk Phrase】

R 22
【EC Safety Phrase】

S 23 36/37
【UN (DOT)】

1325
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Flash Point】

58
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable solid. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water.
【Fire Potential】

Flammable/combustible material. May be ignited by friction, heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1325
【Hazard Class】

4.1
【Packing Group】

II; III
Company Name: Zaozhuang Benefit Chemical Co., Ltd.
Tel: 18663238985
Fax: 0531-69958783
WebSite: http://www.benefit-chem.com
Company Name: Shanghai Boyle Chemical Co., Ltd.
Tel: 021-50182298 021-50180596
Fax: +86-21-57758967
WebSite: www.boylechem.com
Company Name: J & K SCIENTIFIC LTD.
Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
WebSite: http://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel: 4006608290; 18621169109
Fax: 86-21-61259102
WebSite: https://www.meryer.com/cn/index/
Company Name: 3B Pharmachem (Wuhan) International Co.,Ltd.
Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
WebSite: https://www.chemicalbook.com/ShowSupplierProductsList13285/0.htm
Company Name: Alfa Aesar
Tel: 400-6106006
Fax: 021-67582001/03/05
WebSite: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.
Tel: 021-67121386
Fax: 021-67121385
WebSite: https://www.tcichemicals.com/CN/zh/
Company Name: BeiJing Hwrk Chemicals Limted
Tel: 0757-86329057 18501085097
Fax: 010-89508210
WebSite: www.hwrkchemical.com