| Product Identification | Back to Contents | 【Product Name】
Titanium(IV) isopropoxide | 【Synonyms】
Isopropyl orthotitanate
Isopropyl titanate(IV)
Tetraisopropoxide titanium
Tetraisopropoxytitanium
Tetraisopropyl orthotitanate
Tetraisopropyl titanate | 【CAS】
546-68-9 | 【Formula】
C12H28O4Ti | 【Molecular Weight】
284.25 | 【EINECS】
208-909-6 | 【RTECS】
NT8060000 | 【RTECS Class】
Primary Irritant | 【Merck】
12,9614 | 【Beilstein/Gmelin】
3679474 | 【Beilstein Reference】
4-01-00-01469 | 【EC Class】
flammable, harmful, irritant |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Light yellow liquid. | 【Solubility in water】
Decomposition | 【Melting Point】
18 - 20 | 【Boiling Point】
240 | 【Density】
0.9711 g/cm3 (20 C) | 【Heat Of Vaporization】
61.6 kJ/mol | 【Usage】
Heat-resistant surface coatings in paints and plastics. | 【Vapor Density】
9.8 | 【Refractive Index】
1.46 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. | 【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. |
| Handling and Storage | Back to Contents | 【Storage】
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Flammables-area. Keep containers tightly closed. Store protected from moisture. | 【Handling】
Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. |
| Hazards Identification | Back to Contents | 【Inhalation】
May cause respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest. | 【Skin】
May cause irritation and dermatitis. May cause cyanosis of the extremities. | 【Eyes】
May cause eye irritation. May cause chemical conjunctivitis and corneal damage. | 【Ingestion】
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression. | 【Hazards】
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. | 【EC Risk Phrase】
R 10 36 | 【EC Safety Phrase】
S 16 26 36 | 【UN (DOT)】
1993 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Exposure Effects】
Effects may be delayed. | 【Poison Class】
- |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
51 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out. | 【Fire Potential】
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
13 | 【Incompatibilities】
Oxidizing agents, anhydrous hydrazine, moisture. | 【Stability】
Stable under normal temperatures and pressures. Reacts with water to form toxic fumes. | 【Decomposition】
Carbon monoxide, carbon dioxide, titanium/titanium oxides. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. |
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