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Reinecke salt(13573-16-5)

Reinecke salt(13573-16-5)
Product IdentificationBack to Contents
【Product Name】

Reinecke salt
【Synonyms】

Ammonium reineckate
Ammonium tetraisothiocyanatodiaminechromate(III)
Ammonium tetraisothiocyanatodiamminechromate(III)
Chromate(1-), diamminetetrakis(thiocyanato-kN)-, ammonium, (OC-6-11)-
【CAS】

13573-16-5
【Formula】

C4H10CrN7S4
【Molecular Weight】

336.43
【EINECS】

237-003-3
【Merck】

12,8298
【Beilstein/Gmelin】

NA
Physical and Chemical PropertiesBack to Contents
【Appearance】

Dark red powder.
【Solubility in water】

Slightly soluble
【Melting Point】

270
【Usage】

Precipitant for primary and secondary amines, proline, hydroxyproline, and certain amino acids.
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Refrigerator (approx 4 C). Store protected from moisture. Store in a cool, dry area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled. May cause irritation of the mucous membranes.
【Skin】

May cause skin irritation. May be harmful if absorbed through the skin.
【Eyes】

May cause eye irritation.
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure limit(s)】

NIOSH TWA: 0.5 mg/m3 as Cr.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal temperatures and pressures. Decomposes when heated. May decompose on exposure to moist air or water.
【Incompatibilities】

Strong oxidizing agents, water, acids, heat.
【Decomposition】

Hydrogen cyanide, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
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