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N-(2-Methylphenyl)thiourea(614-78-8)

N-(2-Methylphenyl)thiourea(614-78-8)
Product IdentificationBack to Contents
【Product Name】

N-(2-Methylphenyl)thiourea
【Synonyms】

(2-Methylphenyl)thiourea
N-(o-Tolyl)thiourea
o-Tolylthiourea
【CAS】

614-78-8
【Formula】

C8H10N2S
【Molecular Weight】

166.24
【EINECS】

210-395-3
【RTECS】

YU2975000
【RTECS Class】

Agricultural Chemical and Pesticide
【Beilstein/Gmelin】

2086802
【Beilstein Reference】

4-12-00-01766
Physical and Chemical PropertiesBack to Contents
【Appearance】

Crystalline solid.
【Solubility in water】

Slightly soluble
【Melting Point】

160
【Boiling Point】

295
【pKa/pKb】

13.14 pKa
【Partition Coefficient】

1.96
First Aid MeasuresBack to Contents
【Ingestion】

Do not induce emesis. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.
【Inhalation】

Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.
【Skin】

Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists. Treat dermal irritation or burns with standard topical therapy. Patients developing dermal hypersensitivity reactions may require treatment with systemic or topical corticosteroids or antihistamines.
【Eyes】

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Handling and StorageBack to Contents
【Storage】

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Ingestion】

See inhalation.
【Inhalation】

The material is highly toxic if orally ingested.
【Skin】

Thiourea compounds frequently cause allergic contact dermatitis.
【Eyes】

See inhalation
【Hazards】

When heated to decomposition, it emits very toxic fumes of oxides of nitrogen and sulfur.
【EC Risk Phrase】

R 25
【EC Safety Phrase】

S 22 36/37 45
【UN (DOT)】

2811
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
【Respirators】

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

(Non-Specific -- Poisonous Solid, n.o.s.) Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing.(Non-Specific -- Poisonous Solid, n.o.s.) For small fires use dry chemical, carbon dioxide, water spray, or foam. Use water spray, fog, or foam on larger fires. Move container from fire area if you can do so without risk.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

(Non-Specific -- Poisonous Solid, n.o.s.) Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Do not touch spilled material, stop leak if you can do so without risk. Absorb small spills with sand or other noncombustible material and place into containers for later disposal. For large spills, dike far ahead of spill for later disposal.
Stability and ReactivityBack to Contents
【Incompatibilities】

Incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents Reactions with these materials generate heat and in many cases hydrogen gas.
【Stability】

No data.
Transport InformationBack to Contents
【UN Number】

2811
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