ChemicalBook >>Quinaldine>>2-Methylquinoline(91-63-4)

2-Methylquinoline(91-63-4)

2-Methylquinoline(91-63-4)
Product IdentificationBack to Contents
【Product Name】

2-Methylquinoline
【Synonyms】

1-(Tricyclohexylstannyl)-1H-1,2,4-triazole
Khinaldin
Peropal
Quinaldine
Tri(cyclohexyl)-1H-1,2,4-triazol-1-yltin
Tricyclohexyl-(1,2,4-triazol-1-yl)stannane
Tricyclotin
【CAS】

41083-11-8
【CAS】

91-63-4
【Formula】

C10H9N
【Formula】

C20H35N3Sn
【Molecular Weight】

436.27
【Molecular Weight】

143.19
【EINECS】

202-085-1
【EINECS】

255-209-1
【RTECS】

UZ9625000
【RTECS】

WH8637700
【RTECS Class】

Agricultural Chemical and Pesticide; Organometallic
【RTECS Class】

Mutagen; Primary Irritant
【Merck】

12,8228
【Beilstein/Gmelin】

621636
【Beilstein/Gmelin】

110309
【Beilstein Reference】

5-20-07-00375
【Beilstein Reference】

5-26
【EC Class】

harmful
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless crystals.
【Appearance】

Colorless, oily liquid.
【Solubility in water】

Insoluble
【Solubility in water】

0.12 mg/L (20 C)
【Melting Point】

-2
【Melting Point】

209 - 211
【Boiling Point】

247.6
【Boiling Point】

487
【Vapor Pressure】

0.75 (20 C)
【Vapor Pressure】

1.2E-9 (25 C)
【Density】

1.0585 g/cm3 (20 C)
【pKa/pKb】

8.09 (pKb)
【pKa/pKb】

9.0 (pKb)
【Heat Of Vaporization】

66.10 kJ/mol
【Heat Of Combustion】

-5314 kJ/mol
【Usage】

Used to make dyes, pharmaceuticals and other chemicals.
【Usage】

Formerly used as an acaricide. Organotin compound.
【Vapor Density】

4.9
【Refractive Index】

1.6098
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

See Inhalation.
【Ingestion】

Seek medical assistance.
【Inhalation】

TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
【Skin】

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Skin】

Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
【Skin】

Contact with molten substance may cause severe burns to skin and eyes. See Inhalation.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

Immediately flush with running water for at least 20 minutes.
【Eyes】

See Inhalation.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Ingestion】

Causes gastrointestinal tract irritation. May be harmful if swallowed.
【Inhalation】

Causes respiratory tract irritation.
【Skin】

Causes skin irritation. May be harmful if absorbed through the skin.
【Eyes】

Causes eye irritation.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

25 26 37/38 41 50/53
【EC Risk Phrase】

R 21/22 36 40
【EC Safety Phrase】

S 26 36/37/39
【EC Safety Phrase】

26 28 36/37/39 38 45 60 61
【UN (DOT)】

3146
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Personal Protection】

Wear appropriate protective gloves, clothing and goggles.
【Respirators】

Wear positive pressure self-contained breathing apparatus (SCBA).
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Central nervous system toxicity: Headache, nausea, vomiting dizziness, sometimes convulsions and loss of consciousness. Photophobia and mental disturbances. Epigastric pain.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

105
【Flash Point】

249
【Fire Fighting】

Small Fires: Dry chemical, CO2 or water spray. Large Fires: Dry chemical, CO2, alcohol-resistant foam or water spray.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out.
【Upper exp. limit】

6.8
【Lower exp. limit】

.9
【Fire Potential】

This compound is probably combustible.
【Fire Potential】

Combustible material: may burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
【Small spills/leaks】

ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Incompatibilities】

Oxidizing agents
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

When heated to decomposition it emits toxic fumes of NOx.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3146
【Hazard Class】

6.1
【HS Code】

2933 49 90
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