ChemicalBook >>1-(2-Hydroxyethyl)piperazine>>1-Piperazineethanol(103-76-4)

1-Piperazineethanol(103-76-4)

1-Piperazineethanol(103-76-4)
Product IdentificationBack to Contents
【Product Name】

1-Piperazineethanol
【Synonyms】

2-Piperazin-1-ylethanol
Benzoxazolium, 3-hexyl-2-[3-(3-hexyl-2(3H)-benzoxazolylidene)-1-propenyl]-, iodide
N-(2-Hydroxyethyl)piperazine
【CAS】

53213-82-4
【CAS】

103-76-4
【Formula】

C29H37IN2O2
【Formula】

C6H14N2O
【Molecular Weight】

130.19
【Molecular Weight】

572.52
【EINECS】

203-142-3
【RTECS】

TL6825000
【RTECS Class】

Primary Irritant
【Beilstein/Gmelin】

NA
【Beilstein/Gmelin】

104361
【Beilstein Reference】

5-23-01-00406
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, light yellow liquid.
【Appearance】

Red powder.
【Solubility in water】

Very soluble
【Melting Point】

215-221
【Melting Point】

-38
【Boiling Point】

246
【Vapor Pressure】

0.005 (25 C)
【Density】

1.0595 g/cm3 (20 C)
【pKa/pKb】

4.73 (pKb)
【Partition Coefficient】

-.45
【Heat Of Vaporization】

56.0 kJ/mol
【Vapor Density】

4.5
【Refractive Index】

1.5058 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

Causes respiratory tract irritation. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
【Skin】

Causes skin irritation.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Store protected from light.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation.
【Skin】

Causes skin irritation.
【Eyes】

Causes eye irritation.
【Ingestion】

Ingestion of large amounts may cause gastrointestinal irritation. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【EC Risk Phrase】

R 38 41
【EC Safety Phrase】

S 26 37/39
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter and cretinoid appearance of the newborn.. Prolonged exposure to iodides may produce iodism in sensitive individuals. Exposure will include: skin rash, running nose and headache.
【Exposure Effects】

The toxicological properties of this substance have not been fully investigated.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

102
【Autoignition】

280
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Upper exp. limit】

8.9
【Lower exp. limit】

1.4
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents, acids, chlorinated solvents, copper, copper alloys.
【Disposal Code】

5
【Decomposition】

Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, oxides of iodine.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Transport InformationBack to Contents
【HS Code】

2933 59 95
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