ChemicalBook >>Hexyl alcohol>>1-Hexanol(111-27-3)

1-Hexanol(111-27-3)

1-Hexanol(111-27-3)
Product IdentificationBack to Contents
【Product Name】

1-Hexanol
【Synonyms】

Amyl carbinol
Caproyl alcohol
Hexan-1-ol
n-Hexanol
n-Hexyl alcohol
Pentylcarbinol
【CAS】

111-27-3
【Formula】

C6H14O
【Molecular Weight】

102.18
【EINECS】

203-852-3
【RTECS】

MQ4025000
【RTECS Class】

Primary Irritant
【Merck】

13,4715
【Beilstein/Gmelin】

969167
【Beilstein Reference】

4-01-00-01694
【EC Index Number】

603-059-00-6
【EC Class】

Harmful
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid with a fruity odor.
【Solubility in water】

5.9 g/L (20 C)
【Melting Point】

-45
【Boiling Point】

156
【Vapor Pressure】

0.5 (21 C)
【Density】

0.8322 g/cm3
【Partition Coefficient】

2.03
【Heat Of Vaporization】

32.09 kJ/mol
【Heat Of Combustion】

-3980 kJ/mol
【Usage】

Solvent, laboratory reagent.
【Vapor Density】

4.5
【Saturation Concentration】

1200 ppm (0.12%) at 25 C (calculated)
【Odor threshold】

0.01 ppm
【Refractive Index】

1.4162 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards IdentificationBack to Contents
【Inhalation】

Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation.
【Skin】

May cause skin irritation and dermatitis.
【Eyes】

Causes eye irritation with redness and tearing. Splashes have caused temporary corneal damage.
【Ingestion】

Harmful if swallowed. May cause headache, nausea, drowsiness and dizziness. Aspiration into the lungs may occur during swallowing or vomiting, resulting in lung damage.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 22
【EC Safety Phrase】

S 24/25
【UN (DOT)】

2282
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

Prolonged skin contact may result in drying and cracking of the skin.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

62
【Autoignition】

285
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible Liquid. To extinguish fire, use dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
【Upper exp. limit】

8
【Lower exp. limit】

1.2
【Fire Potential】

Moderate fire hazard, when exposed to heat or flame; can react with oxidizing materials.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizers, inorganic acids, and halogens.
【Decomposition】

Carbon dioxide and carbon monoxide may form when heated to decomposition.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2282
【Hazard Class】

3
【Packing Group】

III
【HS Code】

2905 19 00
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