| Product Identification | Back to Contents | 【Product Name】
Antioxidant D | 【Synonyms】
(Hydroxyimino)cyclohexane
2H-1-Benzopyran-2-one, 7-amino-4-(trifluoromethyl)-
7-Amino-4-(trifluoromethyl)-2-benzopyrone
7-Amino-4-(trifluoromethyl)chromen-2-one
Antioxidant D
N-Cyclohexylidenehydroxylamine | 【CAS】
100-64-1 | 【CAS】
53518-15-3 | 【Formula】
C10H6F3NO2 | 【Formula】
C6H11NO | 【Molecular Weight】
113.16 | 【Molecular Weight】
229.15 | 【EINECS】
258-599-1 | 【EINECS】
202-874-0 | 【RTECS】
GW1925000 | 【RTECS Class】
Tumorigen; Drug; Mutagen | 【Beilstein/Gmelin】
4456797 | 【Beilstein/Gmelin】
1616769 | 【Beilstein Reference】
4-07-00-00021 | 【EC Class】
harmful |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Prisms, liquid or light tan crystalline solid. | 【Appearance】
Yellow solid. | 【Solubility in water】
15 mg/L | 【Melting Point】
222 | 【Melting Point】
88 - 90 | 【Boiling Point】
343 | 【Boiling Point】
206 | 【Vapor Pressure】
0.03 (25 C) | 【Density】
1.13 g/cm3 (20 C) | 【pKa/pKb】
11.81 (pKa) | 【Partition Coefficient】
1.63 | 【Heat Of Vaporization】
58.08 kJ/mol | 【Heat Of Combustion】
-3778 kJ/mol | 【Usage】
In prepn of caprolactam. Antioxidant. | 【Vapor Density】
3.9 |
| First Aid Measures | Back to Contents | 【Ingestion】
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | 【Inhalation】
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | 【Skin】
May cause skin irritation. | 【Skin】
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
May cause eye irritation. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. |
| Handling and Storage | Back to Contents | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | 【Handling】
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. |
| Hazards Identification | Back to Contents | 【Ingestion】
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. | 【Inhalation】
May cause respiratory tract irritation. | 【Skin】
May cause skin irritation. | 【Eyes】
May cause eye irritation. | 【Ingestion】
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver damage. May cause spleen damage. | 【EC Risk Phrase】
R 22 | 【EC Risk Phrase】
R 36/37/38 | 【EC Safety Phrase】
S 22 36/37 | 【EC Safety Phrase】
S 26 36 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | 【Exposure Effects】
Prolonged exposure may cause anemia and methemoglobinemia, characterized by dizziness, drowsiness, headache, breath shortness, cyanosis, rapid heart rate and chocolate-brown colored blood. | 【Poison Class】
4 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
110 | 【Autoignition】
315 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam. | 【Upper exp. limit】
9.8 | 【Lower exp. limit】
1.3 | 【Fire Potential】
This material is probably combustible. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. | 【Small spills/leaks】
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
3 | 【Incompatibilities】
Oxidizing agents. | 【Stability】
Stable under normal temperatures and pressures. | 【Incompatibilities】
Strong oxidizing agents - strong acids. | 【Decomposition】
Nitrogen oxides, carbon monoxide, carbon dioxide. | 【Decomposition】
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride. |
|
| Company Name: |
J & K SCIENTIFIC LTD. |
| Tel: |
010-82848833 400-666-7788 |
| Fax: |
86-10-82849933 |
| WebSite: |
http://www.jkchemical.com |
| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Fax: |
021-67582001/03/05 |
| WebSite: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical |
| Tel: |
021-021-58432009 400-005-6266 |
| Fax: |
021-58436166 |
| WebSite: |
http://www.energy-chemical.com |
|