| Identification | Back Directory | [Name]
sodium superoxide | [CAS]
12034-12-7 | [Synonyms]
SODIUM SUPEROXIDE
sodium,molecular oxygen
USSXBCNWHSJQOH-UHFFFAOYSA-N
SodiuM superoxide(Na(O2)) (9CI) | [Molecular Formula]
NaO2 | [MOL File]
12034-12-7.mol | [Molecular Weight]
54.99 |
| Safety Data | Back Directory | [RIDADR ]
UN 2547 5.1/ PGI | [HazardClass ]
5.1 | [PackingGroup ]
I | [Safety Profile]
An oxidizer. When heated to decomposition it emits toxic vapors of Na2O. |
| Hazard Information | Back Directory | [General Description]
A solid. Yellowish at room temperatures but may become white when cooled. Prolonged exposure to fire or heat may cause vigorous decomposition and the rupturing of the containers. | [Air & Water Reactions]
Reacts with moisture and carbon dioxide in the air. Reacts vigorously with water to give oxygen and sodium hydroxide. | [Reactivity Profile]
sodium superoxide violently decomposes above 250°C, evolving oxygen [Mellor 2 Supp. 2:639 1961]. An oxidizing agent. Reacts with carbon dioxide to give sodium carbonate and oxygen. Mixtures with combustible materials (most organic compounds) are readily ignited by friction, heat, or contact with moisture. | [Health Hazard]
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire may produce irritating and/or toxic gases. Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard. | [Chemical Properties]
Sodium superoxide, NaO2, is a yellow solid. |
|