132068-98-5
中文名称
氯环戊二烯基[(4R,5R)-2,2-二甲基-Α,Α,Α′,Α′-四苯基-1,3-二氧戊环-4,5-二甲醇酸根]钛
英文名称
(R,R)-DUTHALER-HAFNER REAGENT
CAS
132068-98-5
分子式
C36H35ClO4Ti5*
分子量
614.98
MOL 文件
132068-98-5.mol
132068-98-5 结构式
基本信息
中文别名
(R,R)-DUTHALER-HAFNER 试剂[(4R,5R)-2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]环戊二烯基-氯化钛
(4R,5R)-氯-环戊二烯基-[2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]钛
氯环戊二烯基[(4R,5R)-2,2-二甲基-Α,Α,Α′,Α′-四苯基-1,3-二氧戊环-4,5-二甲醇酸根]钛
英文别名
Duthaler-Hafner Reagent(R,R)-DUTHALER-HAFNER REAGENT
Chloro(h5-cyclopentadienyl)[(4R,trans)-2,2-dimethyl-a,a,a
(R,5)-2,2-dime.-dioxolan-4,5-bis(diphe-nylmethoxy)cp-cl-ti
(4R,5R)-Chloro-cyclopentadienyl-[2,2-dimethyl-1,3-dioxolan-4,5-bis(diphenylmetho
CHLOROCYCLOPENTADIENYL((4R,5R)-DI-ME-TET RA -PHENYL-DIOXOLANE-DIMETHANOLATO)TI,97
[(4R,5R)-2,2-DIMETHYL-1,3-DIOXOLAN-4,5-BIS(DIPHENYLMETHOXY)]CYCLOPENTADIENYL-CHLOROTITANIUM
(4R,5R)-Chloro-cyclopentadienyl-[2,2-dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]titanium
chlorocyclopentadienyl[(4r,5r)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium
Chlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-alpha,alpha,alpha,alpha-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium
物理化学性质
熔点209-213 °C
比旋光度D20 -246° (c = 1 in CHCl3)
储存条件2-8°C
溶解度sol toluene (ca. 370 mg mL-1), THF (ca. 470 mg mL-1), diethyl ether (ca. 150 mg mL-1)
形态powder or crystals
颜色pale yellow
旋光性 (optical activity)[α]20/D -246°, c = 1 in chloroform
Merck13,3505
