869288-09-5
中文名称
MIL-101(CR)
英文名称
MIL-101(Cr)
CAS
869288-09-5
分子式
C24H16Cr3FO16
分子量
735.36
MOL 文件
869288-09-5.mol
更新日期
2026/09/22 13:26:43
869288-09-5 结构式
物理化学性质
密度0.58 g/cm3
储存条件2-8°C, stored under nitrogen
外观Light green to green Solid
InChIInChI=1S/3C8H6O4.3Cr.FH.3H2O.O/c3*9-7(10)5-1-2-6(4-3-5)8(11)12;;;;;;;;/h3*1-4H,(H,9,10)(H,11,12);;;;1H;3*1H2;/q;;;+3;2*+4;;;;;-2/p-9
InChIKeyQQOADXNDUNUNLG-UHFFFAOYSA-E
SMILES[F-][Cr+3]12O=C(C3C=CC(C(=O)[O-])=CC=3)[O-][Cr+3]3(O=C(C4C=CC(C(=O)[O-])=CC=4)[O-][Cr+3](O=C(C4C=CC(C(=O)[O-])=CC=4)[O-]1)(O)[O-2]23)O.O
常见问题列表
结构特性
| 配位金属 | Cr |
| 配体 | 对苯二甲酸（CAS：100-21-0） |
| 孔径 | 窗口:1.2-1.6nm;孔径:2.9-3.4nm |
| 孔容 | 2.0-2.4cm3/g |
| 粒径 | 500-800nm |
| 比表面 | BET比表面2800-3200m2/g |
稳定性
MIL-101(Cr)在空气中非常稳定，可稳定放置数月。热分解温度>300℃；水溶液中稳定，耐强酸弱碱PH1-12应用领域
储气材料和吸附材料参考文献
文献 1
[1] A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area. https://doi.org/10.1126/science.1116275
[2] Comparative Study of Hydrogen Sulfide Adsorption in the MIL-53(Al, Cr, Fe), MIL-47(V), MIL-100(Cr), and MIL-101(Cr) Metal-Organic Frameworks at Room Temperature. https://doi.org/10.1021/ja901587t
[3] Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation. https://doi.org/10.1002/anie.200705998
[4] High Uptakes of CO₂ and CH₄ in Mesoporous Metal-Organic Frameworks MIL-100 and MIL-101. https://doi.org/10.1021/la800227x
[5] High Flux Thin Film Nanocomposite Membranes Based on Metal−Organic Frameworks for Organic Solvent Nanofiltration. https://doi.org/10.1021/ja407665w