ChemicalBook
Chinese english Germany Japanese Korea

Formothion (ISO) Produkt Beschreibung

FORMOTHION Struktur
2540-82-1
CAS-Nr.
2540-82-1
Bezeichnung:
Formothion (ISO)
Englisch Name:
FORMOTHION
Synonyma:
p1;JC7;J-38;Antio;NUCKS;s6900;Aflix;S 6900;ANTHIO;NUCKS1
CBNumber:
CB0757865
Summenformel:
C6H12NO4PS2
Molgewicht:
257.27
MOL-Datei:
2540-82-1.mol

Formothion (ISO) Eigenschaften

Schmelzpunkt:
25.5℃
Dichte
1.361 g/cm3 (20 ºC)
Dampfdruck
1.13 x 10-4 Pa (20 °C)
Brechungsindex
1.5541 (589.3 nm 20℃)
Flammpunkt:
25 °C
storage temp. 
2-8°C
Aggregatzustand
solid
Wasserlöslichkeit
2600 mg l-1(24 °C)
BRN 
5942199
CAS Datenbank
2540-82-1(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn
R-Sätze: 21/22-36/38-20/21/22-10
S-Sätze: 36/37-36-26
RIDADR  3018
WGK Germany  3
HazardClass  6.1(b)
PackingGroup  III
Toxizität LD50 in rats, rabbits (mg/kg): 350, 410 orally (Liesche)
Bildanzeige (GHS)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H304 Kann bei Verschlucken und Eindringen in die Atemwege tödlich sein. Aspirationsgefahr Kategorie 1 Achtung
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
H373 Kann die Organe schädigen bei längerer oder wiederholter Exposition. Spezifische Zielorgan-Toxizität (wiederholte Exposition) Kategorie 2 Warnung P260, P314, P501
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P260 Dampf/Aerosol/Nebel nicht einatmen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P301+P310 BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P370+P378 Bei Brand: zum Löschen verwenden.

Formothion (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R21/22:Gesundheitsschädlich bei Berührung mit der Haut und beim Verschlucken.
R36/38:Reizt die Augen und die Haut.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R10:Entzündlich.

S-Sätze Betriebsanweisung:

S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

Yellow liquid.Insoluble in water; miscible with common organic solvents.

Chemische Eigenschaften

Formothion is an odorless, yellowish viscous oil or crystalline mass.

Verwenden

Formothion is used to control sucking pests and internally feeding larvae in a variety of crops.

Verwenden

Acaricide, systemic insecticide.

Allgemeine Beschreibung

Viscous yellow oil or a crystalline mass. Used as an insecticide and acaricide on crops and ornamentals. Not presently produced commercially in the U.S.

Air & Water Reaktionen

hydrolyzed by water especially under alkaline conditions. [EPA, 1998].

Reaktivität anzeigen

Organophosphates, such as FORMOTHION, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Cholinesterase inhibitor.

Health Hazard

FORMOTHION is one of the least toxic systemic organophosphates. FORMOTHION is a compound of low to moderate toxicity. It causes the depression of cholinesterase, leading to accumulation of acetylcholine in the nervous system, which is believed to be responsible for the symptoms.

Brandgefahr

When heated to decomposition, FORMOTHION emits very toxic fumes of nitrogen oxides, phosphorus oxides and sulfur oxides. FORMOTHION is an organophosphorus insecticide. Some of these materials may burn but none of them ignite readily. Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases. Avoid alkaline pesticides; hydrolyzed by water especially under alkaline conditions.

Landwirtschaftliche Anwendung

Insecticide, Acaricide: Formothion is a systemic and contact insecticide used to control spider mites, aphids, psyllids, mealy bugs, whiteflies, jassids, leaf miners, ermine moths, and fruit flies. It is used on tree fruits, vines, olives, hops, cereals, sugar cane, rice. Formothion is available as an emulsifiable concentrate and an ultra-low-volume spray. A U.S. EPA restricted Use Pesticide (RUP). Not approved for use in EU countries

Handelsname

AFLIX®; ANTHIO®; ANTIO®; CP 53926®; S 6900®; SAN 244 I®; SAN 6913 I®; SAN 71071®; SPENCER S-6900®; VEL 4284®

Sicherheitsprofil

Poison by ingestion, inhalation, sh contact, and intravenous routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and SOx. See also ESTERS.

mögliche Exposition

Formothion is an insecticide and acar icide for use on crops and ornamentals. Formothion is not currently produced commercially in the U.S.

Stoffwechselwegen

Formothion is broken down in aqueous solution to approximately equal amounts of dimethoate and dimethoate carboxylic acid, the first of which is an activation step and the latter a degradative one. All studies which have investigated the fate of formothion in biological systems have identified these two metabolites but there is evidence that their formation is purely base-catalysed and not enzyme-catalysed. In this respect, the amide group of formothion is much more labile than that of dimethoate since dimethoate carboxylic acid has only been reported in metabolic studies and is not formed by base-catalysed hydrolysis of dimethoate.

Versand/Shipping

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Degradation

Formothion is hydrolysed by water to dimethoate (2) and dimethoate carboxylic acid (3). Dilute solutions in non-polar organic solvents are stable (PM). El-Oshar and Dauterman (1977) investigated the hydrolysis of [O-14C-methyl]formothion in 1.0 M phosphate buffer at pH values between 5.5 and 8.0 at 37 °C. The amounts of unchanged formothion and products were assessed after 30 min. At all pH values the amounts of dimethoate (2) and dimethoate carboxylic acid (3) were approximately equal, indicating that the rate of attack by the hydroxyl ion was equal at both carbonyl groups. The rate of hydrolysis was pH dependent with 16.4% hydrolysis at pH 5.5, 65.2% hydrolysis at pH 7.0 and 96.7% hydrolysis at pH 8.0 after 30 min. The route leading to dimethoate carboxylic acid would yield N-methylformamide (4) as the additional product. A suggested route for the base-catalysed hydrolysis of formothion is shown in Scheme 1.

Inkompatibilitäten

Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the pres ence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

Waste disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Formothion (ISO) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Formothion (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 39)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28236 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
GL Biochem (Shanghai) Ltd 86-21-61263452 (tel), 86-13641803416(mobile)
86-21-61263399 ymbetter@glbiochem.com China 9721 64
BEST-REAGENT 400-1166-196 18981987031
028-84555506 QQ:800101999 cdhxsj@163.com China 9900 57
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 ; 028-86676798 ; 028-86757656
028-86757656 aikeshiji@163.com China 9755 55
Shanghai Meishui Chemical Technology Co., Ltd 021-60549325 18616193163
021-33250306 mail@meishuichem.com China 4537 56
Shanghai JONLN Reagent Co., Ltd. 400-0066-400;021-60496031
021-55660885 shjlsw@163.com China 10052 55
TianJin Alta Scientific Co., Ltd. +86-022-6537-8550
+86-022-2532-9655 contact@altascientific.com China 2775 58
Alta Scientific Co., Ltd. (0086) 22-6537-8550; 185-2256-9193; 185-2256-9194
(0086) 22-2532-9655 contact@altascientific.com China 8312 55

2540-82-1(Formothion (ISO))Verwandte Suche:


  • S-[2-(FORMYLMETHYLAMINO)-2-OXOETHYL] O,O-DIMETHYL DITHIOPHOSPHATE
  • S-[2-(FORMYLMETHYLAMINO)-2-OXOETHYL]-O,O-DIMETHYL-PHOSPHORODITHIONATE
  • O,O-DIMETHYL S-(N-FORMYL-N-METHYL-CARBAMOYLMETHYL)PHOSPHORODITHIOATE
  • Acetamide, N-formyl-2-mercapto-N-methyl-, S-ester with O,O-dimethyl phosphorodithioate
  • acetamide,n-formyl-2-mercapto-n-methyl-,s-esterwitho,o-dimethylphosphoro
  • acetamide,n-formyl-2-mercapto-n-methyl-,s-esterwitho,o-dimethylphosphorodi
  • afliz(sandoz)
  • Anthio 25
  • anthio25
  • Antio
  • CP 53926
  • cp53926
  • des-ester
  • ENT 27,257
  • ent27,257
  • formothion25ec
  • J-38
  • mides-ester
  • N-Formyl-N-methylcarbamoylmethyl O,O-dimethyl phosphorodithioate
  • n-formyl-n-methylcarbamoylmethylo,o-dimethylphosphorodithioate
  • O,O-Dimethyl Dithiophosphorylacetic acid N-methyl-N-formylamide
  • O,O-Dimethyl phosphorodithioate N-formyl-2-mercapto-N-methylacetamide S-ester
  • O,O-Dimethyl S-(N-methyl-N-formylcarbamoylmethyl)phosphorodithioate
  • o,o-dimethyldithiophosphorylaceticacidn-methyl-n-formylamide
  • o,o-dimethylester,s-esterwithn-formyl-2-mercapto-n-phosphorodithioicaci
  • o,o-dimethylphosphorodithioaten-formyl-2-mercapto-n-methylacetamides-ester
  • O,O-Dimethyl-S-(3-methyl-2,4-dioxo-3-azabutyl)dithiofosfaat
  • o,o-dimethyl-s-(3-methyl-2,4-dioxo-3-aza-butyl)-dithiofosfaat
  • O,O-Dimethyl-S-(3-methyl-2,4-dioxo-3-azabutyl)dithiophosphat
  • o,o-dimethyl-s-(3-methyl-2,4-dioxo-3-aza-butyl)-dithiophosphat
  • O,O-Dimethyl-S-(N-methyl-N-formylcarbamoylmethyl)dithiophosphat
  • o,o-dimethyl-s-(n-methyl-n-formyl-carbamoylmethyl)-dithiophosphat
  • o,o-dimethyls-(n-methyl-n-formylcarbamoylmethyl)phosphorodithioate
  • O,O-Dimetil-S-(N-formil-N-metilcarbamoilmetil)ditiofosfato
  • o,o-dimetil-s-(n-formil-n-metil-carbamoil-metil)-ditiofosfato
  • OMS-968
  • p1
  • Phosphorodithioic acid, O,O-dimethyl ester, N-formyl-2-mercapto-N-methylacetamide S-ester
  • Phosphorodithioic acid, O,O-dimethyl ester, S-ester with N-formyl-2-mercapto-N-methylacetamide
  • Phosphorodithioic acid, S-[2-(formylmethylamino)-2-oxoethyl] O,O-dimethyl ester
  • phosphorodithioicacid,o,o-dimethylester,n-formyl-2-mercapto-n-methylaceta
  • phosphorodithioicacid,o,o-dimethylester,n-formyl-2-mercapto-n-methylacetami
  • phosphorodithioicacid,s-(2-(formylmethylamino)-2-oxoethyl)o,o-dimethylest
  • phosphorodithioicacid,s-(2-(formylmethylamino)-2-oxoethyl)o,o-dimethylester
  • S 6900
  • S-(2-(Formylmethylamino)-2-oxoethyl) O,O-dimethylphosphorodithioate
  • s-(2-(formylmethylamino)-2-oxoethyl)o,o-dimethylphosphorodithioate
  • S-(N-Formyl-N-methylcarbamoylmethyl) dimethyl phosphorothiolothionate
  • S-(N-Formyl-N-methylcarbamoylmethyl) O,O-dimethyl phosphorodithioate
  • s-(n-formyl-n-methylcarbamoylmethyl)dimethylphosphorothiolothionate
  • s-(n-formyl-n-methylcarbamoylmethyl)o,o-dimethylphosphorodithioate
  • AFLIX(R)
  • ANTHIO
  • ANTHIO(R)
  • Formothionsolution in xylene PESTANAL, s
  • formothion (bsi,iso,esa,jmaf)
  • formothion solution
  • FORMOTHION STANDARD
Copyright 2019 © ChemicalBook. All rights reserved