Fluazinam Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R23:Giftig beim Einatmen.
R41:Gefahr ernster Augenschäden.
R43:Sensibilisierung durch Hautkontakt möglich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Beschreibung
Fluazinam, with a LogP of 3.56, has very low
solubility in water (1.7 mgL?1, pH6.8, 25?C) but higher
solubilities in organic solvents (e.g., acetone 470 g/L,
dichloromethane 330 g/L, ethanol 150 g/L, all at 20 ?C).
The active ingredient forms light yellow crystals with an
MP of 115 to 117 ?C and has a vp of 1.5 mPa (25 ?C). The
compound is stable to acid, alkali, and heat (5).
Chemische Eigenschaften
yellow crystal mp 115 ~ 117°C
Verwenden
Fluazinam is a broad spectrum fungicide. Fluazinam is commonly used for control of Sclerotinia blight and other soilborne pathogens of peanut as well for the control of potato blight.
Definition
ChEBI: Fluazinam is a member of the class of aminopyridines that is 2-amino-5-(trifluoromethyl)pyridine in which one of the amino hydrogens is replaced by a 3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl group. A fungicide used to control grey mould, downy mildew and other fungal pathogens. It has a role as an apoptosis inducer, an allergen, a xenobiotic, an environmental contaminant and an antifungal agrochemical. It is a C-nitro compound, a chloropyridine, an aminopyridine, a secondary amino compound, a member of monochlorobenzenes and a member of (trifluoromethyl)benzenes.
Allgemeine Beschreibung
Fluazinam is a 2,6-dinitroaniline protectant fungicide, which belongs to the pyridinamine group. It can mostly find applications in agriculture.
Hazard
Moderately toxic by ingestion and inhalation. A reproductive hazard.
Landwirtschaftliche Anwendung
Fungicide: Used to control Sclerotinia blight on peanuts and
late blight and white mold on potatoes.
Handelsname
FLUAZINAM 50 WP®; FROWNCIDE®;
IKF-1216®; ICIA-192®; OMEGA; PP-192®; SHIRLAN®
Kontakt-Allergie
Fluazinam is a pesticide with a broad spectrum of anti fungal activity. It caused sensitization in employees in
the tulip bulb industry and in farmers. Fluazinam
induced contact dermatitis in a worker in a plant where
it was manufactured.
Sicherheitsprofil
Moderately toxic by
ingestion and inhalation. Experimental
reproductive effects. When heated to
decomposition it emits toxic vapors of NOx,
F-, and Cl-.
Stoffwechselwegen
Fluazinam may typically be applied to crops of potatoes using up to 10
applications each of 150 g ha
-1. Routes of degradation involve ring
hydroxylation in aerobic soils and reduction of the nitro groups in flooded
soils. A large amount of unextractable residue was observed. In potatoes
and rats, important reactions involve the reduction of nitro groups and
the formation of conjugates. In plants, the trifluoromethyl substituents are
hydrolysed to carboxylic acid groups. Most of the information presented
below was taken from an evaluation of the fungicide published by the UK
Pesticide Safety Directorate (PSD, 1994).
Fluazinam Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
