N-(PHENYLTHIO)PHTHALIMIDE
|
|
|
- CAS-Nr.
- 14204-27-4
- Englisch Name:
- N-(PHENYLTHIO)PHTHALIMIDE
- Synonyma:
- N-(PHENYLTHIO)PHTHALIMIDE;N-(Phenylthio)phthalimide>N-(Phenylthio)phthalimide;2-(Phenylthio)isoindoline-1,3-dione;2-(Phenylthio)-1,3-isoindolinedione;2-(Phenylthio)-1H-isoindol-1,3(2H)-dione;2-(Phenylthio)-1H-isoindole-1,3(2H)-dione;1H-Isoindole-1,3(2H)-dione, 2-(phenylthio)-
- CBNumber:
- CB1240906
- Summenformel:
- C14H9NO2S
- Molgewicht:
- 255.29
- MOL-Datei:
- 14204-27-4.mol
|
N-(PHENYLTHIO)PHTHALIMIDE Eigenschaften
- Schmelzpunkt:
- 160-163 °C(lit.)
- Siedepunkt:
- 432.2±28.0 °C(Predicted)
- Dichte
- 1.42±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Löslichkeit
- DMSO: soluble25mg/mL, clear, yellow
- pka
- -3.05±0.20(Predicted)
- Aggregatzustand
- powder to crystal
- Farbe
- White to Light yellow
- CAS Datenbank
- 14204-27-4
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| S-Sätze: |
24/25 |
|
|
| WGK Germany |
3 |
|
|
| HS Code |
29309090 |
|
|
| Bildanzeige (GHS) |
|
| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
|
P264, P270, P301+P312, P330, P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
|
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
|
P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
|
|
|
| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
|
N-(PHENYLTHIO)PHTHALIMIDE Chemische Eigenschaften,Einsatz,Produktion Methoden
synthetische
(a) Preparation of benzenesulfenyl chloride. To a stirred solution of 55 gm (0.5 mole) of benzene thiol in 300 ml of η -pentane at 0°C is added chlorine gas until an assay (GC) of the resulting red-orange solution shows quantitative conversion to the sulfenyl chloride. The reaction usually requires about 39 gm (0.6 mole) of chlorine.
(b) Reaction of benzenesulfenyl chloride with phthalimide. To a stirred solution of 73.5 gm (0.5 mole) of phthalimide in 200 ml of dimethylforma-mide is first added 60 gm (0.6 mole) of triethylamine. Then the sulfenyl chloride solution from (a) is slowly added dropwise. The reaction mixture is stirred for \ hr, poured into 2 liters of cold water, filtered, and dried to afford 121 gm (95%), m.p. 160-161°C (recrystallized from ethanol).
Complex imides such as camphorimide and 9,10-dihydroanthracene-9,10-endo-a,/3-succinimide have been alkylated in methylene dichloride with alkyl halides, using tetrabutylammonium bromide as a phase-transfer catalyst and aqueous potassium hydroxide as a base.
N-(PHENYLTHIO)PHTHALIMIDE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
N-(PHENYLTHIO)PHTHALIMIDE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 58)Lieferanten
14204-27-4()Verwandte Suche:
- N-(Phenylthio)phthalimide
- 2-(Phenylthio)-1,3-isoindolinedione
- 2-(Phenylthio)isoindoline-1,3-dione
- N-(PHENYLTHIO)PHTHALIMIDE
- N-(Phenylthio)phthalimide>
- 1H-Isoindole-1,3(2H)-dione, 2-(phenylthio)-
- 2-(Phenylthio)-1H-isoindole-1,3(2H)-dione
- 2-(Phenylthio)-1H-isoindol-1,3(2H)-dione
- 14204-27-4
- Building Blocks
- Others
- Organic Building Blocks
- Sulfur Compounds
- Sulfur Compounds (for Synthesis)
- N-Substituted Phthalimides
- N-Substituted Maleimides, Succinimides & Phthalimides
- N-Substituted Phthalimides
- Sulfur Compounds (for Synthesis)
- Synthetic Organic Chemistry
- Organic Building Blocks
- Others
- Sulfur Compounds
- Building Blocks
- Chemical Synthesis
- Organic Building Blocks
- Sulfur Compounds
- N-Substituted Maleimides, Succinimides & Phthalimides
