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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Struktur
95464-05-4
CAS-Nr.
95464-05-4
Englisch Name:
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyma:
Pd（dppf）2Cl2;Pd(dppf)Cl2.CH2Cl2;PdCl2(dppf)DCM;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2;CHEMDOSE;ex with dichL;adium(II),compL;Pd(dppf)Cl2 DCM
CBNumber:
CB1347621
Summenformel:
C34H28Cl2FeP2Pd.CH2Cl2
Molgewicht:
816.63
MOL-Datei:
95464-05-4.mol
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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Eigenschaften

Schmelzpunkt:
275-280 °C(lit.)
Dichte
1 g/cm3
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Löslichkeit
Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Powder
Farbe
orange-red
Wasserlöslichkeit
Insoluble in water.
Stabilität:
Light Sensitive
CAS Datenbank
95464-05-4(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn
R-Sätze: 20/21/22-36/37/38-40-67-48/20/22
S-Sätze: 23-24/25-26-36/37
WGK Germany  3
TSCA  No
HS Code  28439000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P301+P312 BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R40:Verdacht auf krebserzeugende Wirkung.

S-Sätze Betriebsanweisung:

S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S24/25:Berührung mit den Augen und der Haut vermeiden.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.

Chemische Eigenschaften

orange/red solid

Verwenden

suzuki reaction

Application

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

Synthese

1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Acetonitril 1,1'-Bis(diphenylphosphino)ferrocene Toluol Palladiumchlorid Dichlormethan

Downstream Produkte

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 424)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Wuhan Huahan Dingcheng New Material Technology Co., Ltd
+undefined-027-81388558 +undefined086-1878077615
 huahandingcheng@sina.com China 342 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652
 info@fdachem.com China 7845 58
Frapp's ChemicalNFTZ Co., Ltd. 		+86 (576) 8169-6106
sales@frappschem.com China 885 50
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806
 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886
info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512
 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075
 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714
 fandachem@gmail.com China 9348 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795
ivan@atkchemical.com China 32480 60
AB PharmaTech,LLC 		323-480-4688
United States 989 55

95464-05-4()Verwandte Suche:

Aminoferrocene Ferrocen Palladiumchlorid Cobaltchlorid ETHYNYLFERROCENE Palladium Dichlormethan Acetylferrocen Carboxyferrocen Phenylphosphin Diphenylphosphin Chlormethan
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloMethane coMplex
  • (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladiuM-dichloroMethane (1:1)
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(TM) tablets Loading: 2mumol per tablet
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride dichloromethane adduct
  • 1, 1-Bis(diphenylphosphino)Ferrocene] dichloropalaldium(II) complex with DCM
  • Palladium, [1,1'-bis(diphenylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-, compd. with dichloromethane
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1)
  • Bis(diphenylphosphino)ferrocene palladium dichloride, dichloromethane solvate
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane
  • [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose? tablets
  • 1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE COMPLEX
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), COMPLEX WITH DICHLOROMETHANE (1:1)
  • 1,1'-Bis(diphenylphosphiNA)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHA
  • 1,1'-Bis(diphenylphosphino)fer
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), coMplex with dichloroMethane (1:1), Pd 13%
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium(Ⅱ)chloride dichloromethane complex
  • PALLADIUM, [1,1''-BIS(DIPHENYLPHOSPHINO-.KAPPA.P)FERROCENE]DICHLORO-, (SP-4-2)-, COMPD. WITH DICHLOROMETHANE
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd 13%
  • [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(R) tablets
  • ChemDose(R), [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II )complex with dichloromethane impregnated tablets
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE ADDUCT
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DCM ADDUCT
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DICHLOROMETHANE ADDUCT
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II) DICHLOROMETHANE COMPLEX
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE
  • [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) CHLORIDE, 1:1 COMPLEX WITH DICHLOROMETHANE
  • 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE, COMPLEX WITH DICHLOROMETHANE
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)
  • (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane
  • [1,1'-Bis(diphenylphosphino)ferrocene] dichloropalladiuM(II) coMplex with dichlor
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladiuMdichloride dichloroMethanecoMplex
  • [1,1'-bis (diphenylphosphino) ferrocene] dichloropalladiuM dichloroMethane coMplex
  • [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)
  • Pd(dppf)Cl2 DCM
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1)
  • [1,1Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)H2Cl2
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex.dichloromethane
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) dichloromethane
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex [Pd(dppf)Cl2.CH2Cl2]
  • [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane,Pd(dppf)Cl2 · DCM
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dic
  • 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane com
  • 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)chloride dichloromethane complex ,97%
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride dichloromethane complex
  • Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloroMethane adduct, (DPPF)PdCl2·CH2Cl2
  • Dichloro 1,1'-bis(diphenylphosphino)ferrocene palladium (II) dichloromethane, 99%
  • cyclopenta-2,4-dien-1-yl(diphenyl)phosphane
  • DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)F
  • dichloride dichloromethane complex
  • [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct>
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