Magnesiumdi(acetat)

Magnesium acetate  Struktur
142-72-3
CAS-Nr.
142-72-3
Bezeichnung:
Magnesiumdi(acetat)
Englisch Name:
Magnesium acetate
Synonyma:
Nu-Mag;Cromosan;Cromosan*;Mg Acetate;MAGNESIUM ACETATE;MagnesiumAcetateBp;acetatedemagnesium;magnesiumdiacetate;Magnesium diacetate;MagnesiumAcetate>98%
CBNumber:
CB2160485
Summenformel:
C4H6MgO4
Molgewicht:
142.39
MOL-Datei:
142-72-3.mol

Magnesiumdi(acetat) Eigenschaften

Schmelzpunkt:
72-75 °C(lit.)
Dichte
1.5000
Brechungsindex
n20/D 1.358
Löslichkeit
H2O: 1 M at 20 °C, clear, colorless
pka
4.756[at 20 ℃]
Aggregatzustand
Liquid
Farbe
white orthorhombic/monoclinic crystals, crystalline
PH
7.95(1 mM solution);8.23(10 mM solution);8.41(100 mM solution);8.78(1000 mM solution)
Wasserlöslichkeit
Not miscible or difficult to mix with water.
maximale Wellenlänge (λmax)
λ: 260 nm Amax: 0.04
λ: 280 nm Amax: 0.02
Merck 
13,5676
BRN 
3692530
Stabilität:
Stable. Incompatible with strong oxidizing agents. Avoid moisture.
InChIKey
UEGPKNKPLBYCNK-UHFFFAOYSA-L
LogP
-1.38
CAS Datenbank
142-72-3(CAS DataBase Reference)
NIST chemische Informationen
Magnesium acetate(142-72-3)
EPA chemische Informationen
Magnesium acetate (142-72-3)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
S-Sätze: 22-24/25
WGK Germany  3
RTECS-Nr. AI5600000
3
TSCA  Yes
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H312 Gesundheitsschädlich bei Hautkontakt. Akute Toxizität dermal Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P280,P302+P352, P312, P322, P363,P501
H332 Gesundheitsschädlich bei Einatmen. Akute Toxizität inhalativ Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P261, P271, P304+P340, P312
Sicherheit
P261 Einatmen von Staub vermeiden.
P271 Nur im Freien oder in gut belüfteten Räumen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P312 Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P322 Gezielte Maßnahmen
P363 Kontaminierte Kleidung vor erneutem Tragen waschen.
P501 Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Magnesiumdi(acetat) Chemische Eigenschaften,Einsatz,Produktion Methoden

S-Sätze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Beschreibung

Anhydrous Magnesium Acetate has the chemical formula Mg(CH3COO)2 and in its hydrous form, Magnesium Acetate Tetrahydrate, it has the chemical formula Mg(CH3COO)2.4H2O. In this compound the magnesium metal has an oxidation state of 2+.
Anhydrous Magnesium Acetate
Magnesium acetate is the magnesium salt of acetic acid.It is deliquescent and upon heating, it decomposes to form magnesium oxide.Magnesium acetate is commonly used as a source of magnesium or as a chemical reagent.

Chemische Eigenschaften

white deliquescent crystals

Physikalische Eigenschaften

Magnesium acetate appears as white hygroscopic crystals. It smells like acetic acid and is soluble in water. When it is in an aqueous solution its pH can be considered to be neutral.

Charakteristisch

In 1881 Charles Clamond invented the Clamond basket, one of the first effective gas mantles. The reagents used in this invention included magnesium acetate, magnesium hydroxide and water.
Magnesium acetate is commonly used as a source of magnesium or for the acetate ion in chemistry experiments. One example of this is when magnesium acetate and magnesium nitrate were both used to perform molecular dynamics simulations and surface tension measurements. In the experiment the authors found that the acetate had a stronger affinity for the surface compared to the nitrate ion and that the Mg2+ strongly repelled away from the air/liquid interference. They also found that the Mg2+ had a stronger tendency to bind with the acetate ion compared to the nitrate.
One of the more prevalent uses of magnesium acetate is in the mixture called calcium magnesium acetate (CMA). It is a mixture of calcium acetate and magnesium acetate. CMA is thought of as an environmentally friendly alternative deicer to NaCl and CaCl2. CMA also acts as a powerful SO2, NOx, and toxic particulate emission control agent in coal combustion processes to reduce acid rain, and as an effective catalyst for the facilitation of coal combustion.

Verwenden

Dye fixative in textile printing, deodorant, disinfectant, and antiseptic.
Magnesium acetate is used in chemistry and molecular biology as a reagent and a source of magnesium. Magnesium has a variety of biological roles in enzymology, cell membrane and wall structural integrity, muscle cell physiology, and nucleic acid structure.Magnesium is an essential co-factor in many enzymes, including deoxyribonuclease (DNase), the restriction enzymes EcoR I and EcoR V, and Ribonuclease H. Magnesium also stabilizes polymeric nucleic acids such as transfer RNA and ribozymes.
Magnesium acetate has been widely used in the crystallization of proteins. A protocol for the separation of MB and BB isoenzymes of creatine kinase and the LD1 isoenzyme of lactate dehydrogenase that involves elution with magnesium acetate has been published.

Definition

ChEBI: The magnesium salt of acetic acid.

Sicherheit(Safety)

Magnesium Acetate is a relatively safe compound to handle and has been given a health hazard rating of zero. However, it should always be handled with gloves and safety goggles. If it is gets in the eyes, the skin, ingested, or inhaled it will cause irritation in the respective areas: eyes, skin, gastrointestinal system, and lungs.

Lager

Due to the fact that it is very hygroscopic, it must be stored away from water. It is also incompatible with strong oxidizers and should not be mixed with them.

läuterung methode

Crystallise it from anhydrous acetic acid, then dry it under vacuum for 24hours at 100o. [Nencollas J Chem Soc 744 1956, Beilstein 2 IV 113.]

Magnesiumdi(acetat) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Magnesiumdi(acetat) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 273)Lieferanten
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142-72-3(Magnesiumdi(acetat))Verwandte Suche:


  • MAGNESIUM ACETATE
  • MAGNESIUM ACETATE, 4-HYDRATE
  • MAGNESIUM ACETATE, HYDROUS
  • magnesium acetate solution
  • Acetic acid magnesium salt
  • MAGNESIUM ACETATE SOLUTION, FOR MOL. BIO L., 1 M IN H2O
  • MAGNESIUM ACETATE ANHYDROUS, EXTRA PURE 98-102%
  • MagnesiumAcetate>98%
  • MagnesiumAcetateBp
  • MagnesiumAcetateA.R.
  • magnesium diethanoate
  • 99.997% (Metals basis)
  • Magnesium acetate (6CI,7CI)
  • Magnesium acetate (magnesium acetate)
  • Magnesium acetate solution, 1M in water
  • MAGNESIUM ACETATE SOLUTION, FOR MOL.
  • acetatedemagnesium
  • Acetic acid magnesium salt tetrahydrate
  • Cromosan
  • Cromosan*
  • Magnesium diacetate
  • Magnesiumacetate,anhydrous
  • magnesiumdiacetate
  • Mg Acetate
  • Magnesium acetate solution BioUltra, for molecular biology, ~1 M in H2O
  • Nu-Mag
  • Acetic acid (magnesium)
  • 142-72-3
  • C2H6O4Mg4H2O
  • CH3COO2Mg
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  • Puriss p.a. ACS
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  • Analytical Chromatography Product Catalog
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  • Analytical Reagents
  • Antibodies
  • Antibodies to Chemokines
  • Antibodies to Cytokines and Growth Factors
  • Reagents
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  • Inorganic Salts
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  • General Use
  • DNA & RNA Purification
  • Crystallization
  • organic intermediates
  • Snow-Melting Agent
  • AlphabeticalMolecular Biology
  • Biological Buffers
  • BioUltra Buffers
  • BioUltraBiological Buffers
  • Buffer SolutionsProtein Structural Analysis
  • DNA&RNA Purification
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