2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin

Bathocuproine Struktur
4733-39-5
CAS-Nr.
4733-39-5
Bezeichnung:
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin
Englisch Name:
Bathocuproine
Synonyma:
2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE;BATHOCUPROIN;BLANC FIXE XR;BATHOCUPROINE;BathocuproineGr;Bathocuproin BCP;EINECS 225-240-5;BATHOCUPROINE AR;2,9-dm-4,7-dpphen;BATHOCUPROINE(RG)
CBNumber:
CB2299411
Summenformel:
C26H20N2
Molgewicht:
360.45
MOL-Datei:
4733-39-5.mol

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Eigenschaften

Schmelzpunkt:
279-283 °C(lit.)
Siedepunkt:
482.47°C (rough estimate)
Dichte
1.2408 (rough estimate)
Brechungsindex
1.7620 (estimate)
storage temp. 
Sealed in dry,Room Temperature
Löslichkeit
Benzene (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heated)
Aggregatzustand
Powder
pka
5.88±0.30(Predicted)
Farbe
Yellow
Wasserlöslichkeit
Soluble in methanol (36mg/100ml), ethanol, 2-propanol, bezene, and acetone. Partly miscible in water.
BRN 
306714
InChIKey
STTGYIUESPWXOW-UHFFFAOYSA-N
CAS Datenbank
4733-39-5(CAS DataBase Reference)
EPA chemische Informationen
1,10-Phenanthroline, 2,9-dimethyl-4,7-diphenyl- (4733-39-5)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn
R-Sätze: 22-36/37/38-20/21/22
S-Sätze: 24/25-36-26-37/39
WGK Germany  3
TSCA  Yes
HS Code  29339990
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H413 Kann für Wasserorganismen schädlich sein, mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 4
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Organic photovoltaic cells (OPVCs) are considered to be promising devices because of their mechanical flexibility, ease of fabrication and potential for low-cost production. For small-molecule OPVCs the most-common material to use between the acceptor, here C60, and the top electrode, Al, is 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline, also known as bathocuproine. Indeed, the insertion of BCP results in an enhanced power-conversion efficiency (PCE). The improved power-conversion efficiency has been attributed to an increased exciton harvesting in the active layer. As BCP is a wide-band-gap material it acts as an exciton-blocking barrier (EBL) that prohibits excitons diffusing towards the Al electrode where they would otherwise be quenched.

R-Sätze Betriebsanweisung:

R22:Gesundheitsschädlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.

S-Sätze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

Yellow powder

Verwenden

It is used as a reagent for the determination of copper. It acts as an exciton blocking barrier which prohibits excitons diffusion process towards the Al electrode otherwise being quenched. It is the most commonly used buffer layer between acceptor and cathode layer.

Allgemeine Beschreibung

TGA/DSC Lot specific scans available upon request

läuterung methode

Purify it by recrystallisation from *benzene. [Smith & Wilkins Anal Chem 25 510 1953, Beilstein 23 III/IV 2160.]

Einzelnachweise

[1] Mao, Lingling et al. “Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells.” Chemistry of Materials 28 (2016): 7781–7792.

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 359)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shanghai UCHEM Inc.
+862156762820 +86-13564624040
sales@myuchem.com China 6645 58
Henan Fengda Chemical Co., Ltd
+8613613820652
info@fdachem.com China 5505 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806
sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 14936 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21700 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715
admin@nexconn.com China 7836 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc.
(+1)-858-699-3322
info@accelachem.com United States 19965 58

4733-39-5(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin)Verwandte Suche:


  • EINECS 225-240-5
  • 2,9-dm-4,7-dpphen
  • 2,9-dimethyl-4,7-diphenyl-phen
  • 2,9-DiMethyl-4,7-diphenyl-1,10-phenantroline
  • 2,9-DiMethyl-4,7-diphenyl-1,10-phenanthroline, 98% 1GR
  • Bathocuproin BCP
  • Bathocuproine p.a.
  • Bathocuproine,2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP
  • Bathocuproine ,99%
  • BATHOCUPROINE(RG)
  • 4,7-DIPHENYL-2,9-DIMETHYL-1,10-PHENANTHROLINE
  • BLANC FIXE XR
  • BATHOCUPROINE
  • 2,9-dimethyl-4,7-diphenyl-10-phenanthroline
  • 2,9-Dimethyl-4,7-diphenyl-1,10
  • 10-Phenanthroline,2,9-dimethyl-4,7-diphenyl-1
  • 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline,98%
  • BATHOCUPROINE (2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE)
  • 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP
  • BATHOCUPROIN extrapure AR
  • Bathocuproin, 98+%
  • Bathocuproine (refined product of D0711)
  • 2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE SUBLIMED HOLE BLOCKING MATERIAL
  • 1,10-Phenanthroline, 2,9-dimethyl-4,7-diphenyl-
  • BATHOCUPROINE REAGENT (ACS)
  • BATHOCUPROINE, REAG.
  • BathocuproineGr
  • BATHOCUPROIN R. G.
  • 2-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE
  • TIMTEC-BB SBB008863
  • Bathocuproine (purified by sublimation)
  • 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolin
  • Bathocuproin SynonyMs 2,9-DiMethyl-4,7-diphenyl-1,10-phenanthroline
  • Bathocuproine subliMed grade, 99.99% trace Metals basis
  • BATHOCUPROINE AR
  • Bathocuproine (BCP) extrapure AR, ACS, 99%
  • Bathocuproine (BCP) extrapure AR, 99%
  • Bathocuproin 4733-39-5
  • Bathocuproine, GR 99%+
  • 2,9-Dimethyl-4,7-diphenyl-1,1-phenanthroline
  • Bathocuproine (BCP)
  • 2,9-dimethy-4,7-diphenyl -1,10-phenathroline
  • Bathocuproine (purified by sublimation)>
  • Bathocuproine >
  • Bathocuproine, sublimed
  • Bathocuproine subliMed grade, trace Metals basis
  • 2,9-DIMETHYL-4,7-D
  • BATHOCUPROINE, LABORATORY REAGENTBATHOCUPROINE, LABORATORY REAGENTBATHOCUPROINE, LABORATORY REAGENTBATHOCUPROINE, LABORATORY REAGENT
  • 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline/Bathocuproine
  • BATHOCUPROIN
  • 2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE
  • 2,9- dimethyl -4,7- biphenyl -1,10- phenanthroline
  • 4733-39-5
  • CH32C6H52C12H4N2
  • C26H20N2
  • Analytical Chromatography Product Catalog
  • Heterocyclic Building Blocks
  • Others
Copyright 2019 © ChemicalBook. All rights reserved