(2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin
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- CAS-Nr.
- 1135-66-6
- Bezeichnung:
- (2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin
- Englisch Name:
- Isolongifolene
- Synonyma:
- 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S,4aR)-(-)-;ISOLONGIFOLENE;Isolongipholene;Iso-longifloene;Einecs 214-494-2;()-Isolongifolene;(-)-Isolongifoline;ISOLONGIFOLENE(SG);(-)-ISOLONGIFOLENE;(-)-isolongifolene
- CBNumber:
- CB2415088
- Summenformel:
- C15H24
- Molgewicht:
- 204.35
- MOL-Datei:
- 1135-66-6.mol
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(2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin Eigenschaften
- Siedepunkt:
- 255-256 °C
- Dichte
- 0.930 g/mL at 20 °C(lit.)
- Dampfdruck
- 5.49Pa at 25℃
- Brechungsindex
- n20/D 1.499
- Flammpunkt:
- 49°C
- storage temp.
- 2-8°C
- Löslichkeit
- DMSO: 10 mg/mL (48.94 mM)
- Geruch (Odor)
- at 100.00 %. woody dusty amber incense
- Geruchsart
- woody
- Optische Aktivität
- [α]20/D 138±2°, c = 1% in ethanol
- Wasserlöslichkeit
- 59.998μg/L at 25℃
- BRN
- 2207559
- LogP
- 5.77 at 25℃
- CAS Datenbank
- 1135-66-6(CAS DataBase Reference)
- NIST chemische Informationen
- 2H-2,4a-methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2s)-(1135-66-6)
- EPA chemische Informationen
- 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S,4aR)- (1135-66-6)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| R-Sätze: |
10 |
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| RIDADR |
UN 2319 3/PG 3 |
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| WGK Germany |
3 |
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| HazardClass |
3.2 |
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| PackingGroup |
III |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H225 |
Flüssigkeit und Dampf leicht entzündbar. |
Entzündbare Flüssigkeiten |
Kategorie 2 |
Achtung |
![GHS hazard pictograms]() src="/GHS02.jpg" width="20" height="20" /> |
P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501 |
| H370 |
Schädigt die Organe. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 1 |
Achtung |
![GHS hazard pictograms]() src="/GHS08.jpg" width="20" height="20" /> |
P260, P264, P270, P307+P311, P321,P405, P501 |
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| Sicherheit |
| P210 |
Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
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(2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R10:Entzündlich.
Verwenden
(-)-Isolongifolene may be used in the preparation of (-)-isolongifolenone, a potent insect repellent.
Allgemeine Beschreibung
(-)-Isolongifolene is a sesquiterpene that can be found in pine cone and Japanese cedar essential oils.
läuterung methode
Reflux it over, and distil it from Na. [Zeiss & Arakawa J Am Chem Soc 76 1653 1954, IR: Reinaecker & Graafe Angew Chem, Int Ed Engl 97 348 1985, UV and NMR: Ranganathan
et al. Tetrahedron 26 621 1970, Beilstein 5 IV 1191.]
(2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 166)Lieferanten
1135-66-6((2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin)Verwandte Suche:
N-Methyl-anilin
2,6-DIMETHYLNAPHTHALENE
[1S-(1α,3aβ,4α,8aβ)]-Decahydro-4,8,8-trimethyl-9-methylen-1,4-methanoazulen
7-Methyl-3-methylenocta-1,6-dien
2-Methylnaphthalin
1,3,4,6,7,8a-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin-8(5H)-on
(2α,4aα,8α)-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin-8(5H)-on
Methylnaphthalin
3-Cyclopentylpropen
Ethylidencyclopentan
Vinylcyclopentan
Methylencyclopentan
(2S)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalin
(1α,2β,4α)-1,2,4-Trimethylcyclopentan
(1α,2α,4β)-1,2,4-Trimethylcyclopentan
[1aR-(1aα,4aα,7α,8aS*)]-Octahydro-4,4,8,8-tetramethyl-4a,7-methano-4aH-naphth[1,8a-b]oxiren
1,1,3,3-Tetramethylcyclopentan
- (-)-Isolongifolene >=98.0% (suM of enantioMers, GC)
- (-)-Isolongifoline
- (2s)-1,3,4,5,6,7-hexahydro-1,1,5,5
- (2s)-1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-2h-2,4a-methanonaphthalene
- 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-
- C15 H24, 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S)-
- ISOLONGIFOLENE(SG)
- (2s)-2h-1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-4a-methanonaphthalen
- 1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalene
- ISOLONGIFOLENE WITH GC
- (2S,4aR)-1,2,3,4,4a,5,6,7-Octahydro-1,1,5,5-tetramethyl-2,4a-methanonaphthalene
- (2S,4aR)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2,4a-methanonaphthalene
- (2S,4aR)-1,3,4,5,6,7-Hexahydro-1,1,5,5-tetramethyl-2H-2α,4aα-methanonaphthalene
- Einecs 214-494-2
- (1R)-2,2,7,7-Tetramethyltricyclo[6.2.1.01.6］
- 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S-cis)-
- 3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-4a-methanonaphthalen(2s)-2h-1
- 4a-Methanonaphthalene,1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-,(2S)-2H-2
- Isolongipholene
- (1R)-2,2,7,7-TETRAMETHYLTRICYCLO[6.2.1.0(1.6)]UNDEC-5-ENE
- (-)-ISOLONGIFOLENE
- ISOLONGIFOLENE
- ISOLONGIFOLENE SOLUTION
- Isolongifolene USP/EP/BP
- ()-Isolongifolene
- (-)-isolongifolene
- 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S,4aR)-(-)-
- Iso-longifloene
- 1135-66-6
- Complex Molecules
- Asymmetric Synthesis
- Chiral Building Blocks
