1-Bromooctadecane
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- CAS-Nr.
- 112-89-0
- Englisch Name:
- 1-Bromooctadecane
- Synonyma:
- STEARYL BROMIDE;OCTADECYL BROMIDE;N-OCTADECYL BROMIDE;BroMo octadecane;OCLadecyl BroMide;1-BROMOOCTADECANE;1-bromo-octadecan;1-Bromooctodecane;octadecane,1-bromo-;1-Bromooctadecane,96%
- CBNumber:
- CB3126028
- Summenformel:
- C18H37Br
- Molgewicht:
- 333.39
- MOL-Datei:
- 112-89-0.mol
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1-Bromooctadecane Eigenschaften
- Schmelzpunkt:
- 25-30 °C(lit.)
- Siedepunkt:
- 214-216 °C12 mm Hg(lit.)
- Dichte
- 0.976 g/mL at 25 °C(lit.)
- Brechungsindex
- 1.462-1.464
- Flammpunkt:
- >230 °F
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Low Melting Solid
- Farbe
- Yellow
- Wichte
- 0.980 (20/4℃)
- Wasserlöslichkeit
- insoluble
- BRN
- 774145
- Dielectric constant
- 3.5（30.0℃）
- InChIKey
- WSULSMOGMLRGKU-UHFFFAOYSA-N
- CAS Datenbank
- 112-89-0(CAS DataBase Reference)
- NIST chemische Informationen
- Octadecane, 1-bromo-(112-89-0)
- EPA chemische Informationen
- Octadecane, 1-bromo- (112-89-0)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
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| Alarmwort |
Achtung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H304 |
Kann bei Verschlucken und Eindringen in die Atemwege tödlich sein. |
Aspirationsgefahr |
Kategorie 1 |
Achtung |
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| Sicherheit |
| P301+P310 |
BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
| P331 |
KEIN Erbrechen herbeiführen. |
| P405 |
Unter Verschluss aufbewahren. |
| P501 |
Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
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1-Bromooctadecane Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
colorless or light yellow liquid. soluble in ethanol, ether, ethyl acetate and petroleum ether, insoluble in water. Decomposes when exposed to light. It is used in organic synthesis.
Verwenden
1-Bromooctadecane is used in the preparation of shortened single-walled carbon nanotubes (s-SWCNTs). It is utilized to prepare octadecane in the presence of sodium borohydride as a catalyst. It is involved as a raw material for the preparation of dimethyldistearylammonium bromide, which is a bentonite modifier.
synthetische
1-Bromooctadecane is synthesized by the reaction of stearyl alcohol with hydrogen bromide. The alcohol is heated to 100°C, dry hydrogen bromide is introduced, and the reaction temperature is maintained at 100-120°C until the solution no longer absorbs hydrogen bromide. The bromide is layered, the organic phase is washed with concentrated sulfuric acid, the bromide after the acid solution is separated and mixed with an equal volume of 90% methanol, washed with ammonia to make the bromide alkaline, then washed with 90% methanol, and anhydrous Dry calcium chloride. Finally, vacuum distillation, collecting 209-211 ℃ (1.33kPa) fraction is 1-bromooctadecane, and the yield is 90%.
läuterung methode
Twice recrystallise bromooctadecane from the melt, then distil it under vacuum three times using the middle cut. Alternatively, wash the oil with aqueous Na2SO4, then conc H2SO4 (cool) and again with aqueous Na2SO4 and then fractionally distil it. [Meyer & Ried J Am Chem Soc 55 1574 1933, Hoffmann & Smyth J Am Chem Soc 72 171 1950, IR: LeFévre et al. Aust J Chem 12 743 1959, IR: Brini-Fritz Bull Soc Chim Fr 516 1957, Beilstein 1 IV 555.]
1-Bromooctadecane Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
1-Bromooctadecane Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 418)Lieferanten
112-89-0()Verwandte Suche:
- 1-BROMOOCTADECANE
- 1-BROMOOCTADECANE pure
- Octadecyl bromide, Stearyl bromide
- 1-Bromooctadecane,96%
- 1-Bromooctadecane ,98%
- BroMo octadecane
- 1-BroMooctadecane, 96% 100GR
- OCLadecyl BroMide
- 1-BROMOOCTADECANE FOR SYNTHESIS
- 1-Bromooctadecane Vetec(TM) reagent grade, 97%
- octadecane,1-bromo-
- 1-bromo-octadecan
- 1-Bromooctodecane
- N-OCTADECYL BROMIDE (STEARYL)
- 1-BROMOOCTADECANE 99+%
- 1-Bromooctadecane >
- 1-Bromooctadecane，97%
- 1-Bromooctadecaneydrate
- 1-Bromooctadecane ISO 9001：2015 REACH
- STEARYL BROMIDE
- OCTADECYL BROMIDE
- N-OCTADECYL BROMIDE
- N-Benzylethanolamine 97%
- 112-89-0
- C18H37Br
- CH3CH217Br
- CH3CH210Br
- Building Blocks
- Alkyl
- Monofunctional & 伪,蠅-Bifunctional Alkanes
- Monofunctional Alkanes
- Alkyl Bromides
- Halogenated Hydrocarbons
- Organic Building Blocks
- Alkyl Bromides
- Monofunctional & alpha,omega-Bifunctional Alkanes
- Monofunctional Alkanes
