1-Dibenzofuranylboronic Acid

1-Dibenzofuranylboronic Acid Struktur
162607-19-4
CAS-Nr.
162607-19-4
Englisch Name:
1-Dibenzofuranylboronic Acid
Synonyma:
Dibenzo[b,d]furan-1-ylboronic acid;Dibenzofuran-1-boronic acid;1-Dibenzofuranylboronic acid;Dibenzofuran-1-ylboronic acid;B-1-dibenzofuranylBoronic acid;Dibenzo[b,d]furan-1-boronic acid;Boronic acid, B-1-dibenzofuranyl-;1-Dibenzofuranylboronic Acid ISO 9001:2015 REACH;Dibenzofuran-1-boronic Acid (contains varying amounts of Anhydride)
CBNumber:
CB32737143
Summenformel:
C12H9BO3
Molgewicht:
212.01
MOL-Datei:
162607-19-4.mol

1-Dibenzofuranylboronic Acid Eigenschaften

Siedepunkt:
438.5±37.0 °C(Predicted)
Dichte
1.34±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Aggregatzustand
powder to crystal
pka
8.20±0.30(Predicted)
Farbe
White to Almost white
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
HS Code  2932.99.7000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

1-Dibenzofuranylboronic Acid Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

Dibenzo[b,d]furan-1-ylboronic acid can be used as an intermediate in organic synthesis, mainly used in laboratory research and development and chemical production processes.

Synthese

Synthesis_162607-19-4
180 g (728 mmol) of 1-bromodibenzofuran aredissolved in 1500 ml of dry THF and cooled to -78?? C. 305 ml (764 mmol/2.5 M in hexane) of n-butyllithium are added at this temperature over the course of about 5 min., and the mixture is subsequently stirred at -78?? C. for a further 2.5 h. 151 g (1456 mmol) of trimethyl borate are added as rapidly as possible at this temperature, and the reaction mixture is allowed to come slowly to room temperature (about 18 h). The reaction solution is washed with water, and the precipitated solid and the organic phase are dried azeo- tropically with toluene. The crude product is washed by stirring with toluene/methylene chloride at about 40?? C. and filtered off with suction. Yield: 146 g (690 mmol), 95% of theory.

1-Dibenzofuranylboronic Acid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


1-Dibenzofuranylboronic Acid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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  • B-1-dibenzofuranylBoronic acid
  • 1-Dibenzofuranylboronic acid
  • Boronic acid, B-1-dibenzofuranyl-
  • Dibenzofuran-1-boronic Acid (contains varying amounts of Anhydride)
  • 1-Dibenzofuranylboronic Acid ISO 9001:2015 REACH
  • Dibenzo[b,d]furan-1-boronic acid
  • Dibenzo[b,d]furan-1-ylboronic acid
  • Dibenzofuran-1-boronic acid
  • Dibenzofuran-1-ylboronic acid
  • 162607-19-4
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