t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3 Struktur
1536473-72-9
CAS-Nr.
1536473-72-9
Englisch Name:
t-BuBrettPhos Palladacycle Gen. 3
Synonyma:
P](methane;N)[1,1’-(Amino-κtbuttphos Pd G3;-biphenyl]-2-yl-κC][[3,6-dimethoxy-2’-tris(1-methylethyl)[1,1’t-BuBrettPhos Palladacycle Gen. 3;t-butylBrettPhos Palladacycle Gen. 3;t-BuBrettPhos Palladacycle Gen. 3 ISO 9001:2015 REACH
CBNumber:
CB33052898
Summenformel:
C44H63NO5PPdS-
Molgewicht:
855.433481
MOL-Datei:
1536473-72-9.mol

t-BuBrettPhos Palladacycle Gen. 3 Eigenschaften

Schmelzpunkt:
119-131°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Aggregatzustand
solid
Farbe
brown-green
InChIKey
VKLHIPFGYVFUGT-UHFFFAOYSA-N
CAS Datenbank
1536473-72-9

Sicherheit

WGK Germany  3

t-BuBrettPhos Palladacycle Gen. 3 Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

Allgemeine Beschreibung

tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

t-BuBrettPhos Palladacycle Gen. 3 Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


t-BuBrettPhos Palladacycle Gen. 3 Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 114)Lieferanten
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XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621
sales@runvmat.com China 391 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 15371 58
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075
jack.li@time-chemicals.com China 1807 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32480 60
Accela ChemBio Inc.
(+1)-858-699-3322
info@accelachem.com United States 19965 58
Wuhan Pengo Technology.,Ltd.
+86-27-81330736 +86-13628634921
sunny.w@boronicgroup.com CHINA 171 58
career henan chemical co
+86-0371-86658258 15093356674;
factory@coreychem.com China 29826 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387
1057@dideu.com China 3684 58
Jinan Liheng Biotechnology Co., Ltd.
15865262812
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Richest Group Ltd
18017061086
oled@richest-group.com CHINA 5601 58

  • Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
  • METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3]
  • t-BuBrettPhos Palladacycle Gen. 3
  • Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3]
  • Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.
  • Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II)
  • [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle
  • t-butylBrettPhos Palladacycle Gen. 3
  • Methanesulfonate[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) tBuBrettPhos Pd G3
  • Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium
  • -(Amino-&kappa
  • -biphenyl]-2-yl-&kappa
  • C][[3,6-dimethoxy-2&rsquo
  • -biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-&kappa
  • P](methane
  • N)[1,1&rsquo
  • -tris(1-methylethyl)[1,1&rsquo
  • t-BuBrettPhos Palladacycle Gen. 3 ISO 9001:2015 REACH
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium (tBuBrettPhos Pd G3)
  • Methanesulfonato(2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (tBuBrettPhos Pd G3)
  • t-ButylXPhos Pd G4 / Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
  • tbuttphos Pd G3
  • methanesulfonato 2-di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii)
  • (2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate
  • 1536473-72-9
  • C44H62NO5PPdS
  • C31H49O2PC13H13NO3PdS
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
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