(9S)-1-Benzyl-9-hydroxycinchonaniumchlorid
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- CAS-Nr.
- 69221-14-3
- Bezeichnung:
- (9S)-1-Benzyl-9-hydroxycinchonaniumchlorid
- Englisch Name:
- N-BENZYLCINCHONINIUM CHLORIDE
- Synonyma:
- BCNC;(1S,2R,4S,5R);N-Benzylcinchonium chloride;chiralphase-transfercatalyst;N-BENZYLCINCHONINUM CHLORIDE);N-BENZYLCINCHONINIUM CHLORIDE;1-Benzylcinchoninium chloride;(+)-N-Benzylcinchone chloride;iNi-BenzylcinchoniniumChloride;(+)-1-Benzylcinchoninium chloride
- CBNumber:
- CB3487095
- Summenformel:
- C26H29ClN2O
- Molgewicht:
- 420.97
- MOL-Datei:
- 69221-14-3.mol
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(9S)-1-Benzyl-9-hydroxycinchonaniumchlorid Eigenschaften
- Schmelzpunkt:
- 256 °C (dec.)(lit.)
- Brechungsindex
- 168.5 ° (C=0.4, MeOH:H2O=1:5)
- storage temp.
- Inert atmosphere,Room Temperature
- Löslichkeit
- slightly sol. in Methanol
- Aggregatzustand
- powder to crystaline
- Farbe
- White to Almost white
- Optische Aktivität
- [α]20/D +169°, c = 0.4 in H2O
- BRN
- 5232950
- CAS Datenbank
- 69221-14-3(CAS DataBase Reference)
(9S)-1-Benzyl-9-hydroxycinchonaniumchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
Solid
Verwenden
Phase-transfer catalyst involved in:
- Enantioselective alkylation of malonic diester with alkyl halides
- Hydrolysis of enol esters
- Asymmetric 6π electrocyclization for synthesis of functionalized indolines
- Asymmetric Michael addition
- Alkylation of monosubstituted indolinones with alkylhalides
- Asymmetric destruction and kinetic resolution of 1-benzylated Reissert compounds
läuterung methode
Recrystallise the chloride from isoPrOH, toluene or small volumes of H2O. It is a good chiral phase transfer catalyst [Julia et al. J Chem Soc, Perkin Trans 1 574 1981, Hughes et al. J Am Chem Soc 106 446 1984, Hughes et al. J Org Chem 52 4745 1987].
(9S)-1-Benzyl-9-hydroxycinchonaniumchlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(9S)-1-Benzyl-9-hydroxycinchonaniumchlorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 93)Lieferanten
69221-14-3((9S)-1-Benzyl-9-hydroxycinchonaniumchlorid)Verwandte Suche:
- N-BENZYLCINCHONINIUM CHLORIDE
- BCNC
- (9S)-1-benzyl-9-hydroxycinchonanium chloride
- chiralphase-transfercatalyst
- N-BENZYLCINCHONINUM CHLORIDE)
- (9S)-9-Hydroxy-1-(phenylmethyl)cinchonanium chloride
- (+)-1-Benzylcinchoninium chloride
- (+)-N-Benzylcinchone chloride
- (9S)-9-Hydroxy-1-(phenylmethyl)cinchonan-1-ium·chloride
- 1-Benzylcinchoninium chloride
- N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]
- N-Benzylcinchonium chloride
- Cinchonanium,9-hydroxy-1-(phenylmethyl)-, chloride, (9S)-
- (1S,2R,4S,5R)-1-Benzyl-2-(hydroxy(quinolin-4-yl)methyl)-5-vinylquinuclidin-1-ium chloride
- 9-Hydroxy-1-(phenylmethyl)cinchonanium chloride
- N-Benzylcinchoninium chloride 98%
- (1S,2R,4S,5R)
- -1-Benzyl-2-(hydroxy(quinolin-4-yl)
- [5-ethenyl-1-(phenylmethyl)-1-azoniabicyclo[2.2.2]octan-2-yl]-(4-quinolinyl)methanol chloride
- (S)-[(1S,2R,4S,5R)-1-benzyl-5-vinyl-quinuclidin-1-ium-2-yl]-(4-quinolyl)methanol
- (9S)-1-Benzyl-9-hydroxycinchonaniumchlorid
- N-Benzylcinchoninium Chloride [Chiral Phase-Transfer Catalyst]>
- iNi-BenzylcinchoniniumChloride
- N-BENZYLCINCHONINIUM CHLORIDE ISO 9001：2015 REACH
- 69221-14-3
- C29H32ClN2O
- C26H29ClN2O
- Quaternary Ammonium Compounds
- Asymmetric Synthesis
- Ammonium Chlorides (Quaternary)
- Quinolines
- Chiral Phase-Transfer Catalysts
- Alkaloids
- Quinolinecarboxylic Acids, etc.
- Quinoline Alkaloids
- Phase Transfer Reaction
- Chiral Catalysts, Ligands, and Reagents
- Quinoline Alkaloids
- Quinolinecarboxylic Acids, etc.
- Quinolines
- Synthetic Organic Chemistry
- chiral
- Alkaloids
- Ammonium Chlorides (Quaternary)
- Asymmetric Synthesis
- Biochemistry
- Chiral Phase-Transfer Catalysts
- Quaternary Ammonium Compounds
