1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R36:Reizt die Augen.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
R23:Giftig beim Einatmen.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Beschreibung
Triadimenol is a metabolite of triadimefon , a broad-spectrum chiral triazole fungicide, that is formed by reduction of a carbonyl group to the corresponding alcohol. It is teratogenic, inducing cranial nerve and ganglia abnormalities in a rat post-implantation whole embryo culture model when used at concentrations ranging from 12.5 to 125 μM.
In vivo, triadimenol induces embryotoxicity in rats and rabbits when administered orally at doses of 100 and 40 mg/kg, respectively. Embryonic exposure to triadimenol (3-3,000 μg/L) induces embryonic mortality as well as decreases fertility and increases the number of female offspring in medaka fish (
O. latipes).
Verwenden
Triadimenol is used for the control of powdery mildews, rusts
and Rhynchosporium in cereals, and also as a seed treatment to control
bunt, smut and other cereal diseases. It is also used on vines, hops, coffee,
tomatoes, vegetables, fruit, tobacco, sugar cane, ornamentals and other
crops, mainly against powdery mildews, rusts and various leaf spot
diseases.
Definition
ChEBI: A member of the class of triazoles that is 3,3-dimethyl-1-(1,2,4-triazol-1-yl)butane-1,2-diol substituted at position O1 by a 4-chlorophenyl group. A fungicide for cereals, beet and brassicas used to control a range of diseases including powdery mildew, ru
ts, bunts and smuts.
Landwirtschaftliche Anwendung
Fungicide: Triadimenol is used to control seed-and soil-borne
diseases and to provide early season control of foliar
diseases. It is applied to seeds of barley, corn, oats, rye,
sorghum and wheat and also to fruits, vegetables and ornamentals. Registered for use in EU countries
. Registered
for use in the U.S.
U.S. Maximum Allowable Residue Levels for Triadimenol
Handelsname
BAYFIDAN®; BAYFRDAN EW®;
BAY KWG 0519®; BAYTAN® SEED TREATMENT;
BAYTAN 30® FUNGICIDE; PROTEGE ALLEGIANCE
BAYTAN®; SPINNAKER®; SUMMIT®;
TRIADIMENOL®; TRIAFOL®; TRIAPHOL®
Stoffwechselwegen
When triadimenol is irradiated by UV light in methanol
solution, two major degradation products are identified
as 1-(4-chlorophenoxy)-3,3-dimethylbutan-2-one and
1-phenoxy-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-
2-ol. When a spray deposit on apple leaves is
exposed outdoors to natural sunlight, the only product
detected is the butanone metabolite. The butanone
metabolite has very low fungicidal activity against
apple powdery mildew, whereas the butanol metabolite
gives some control of infection.
1-(4-Chlorphenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)-butan-2-ol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
