Diphenyldisulfid
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- CAS-Nr.
- 882-33-7
- Bezeichnung:
- Diphenyldisulfid
- Englisch Name:
- DIPHENYL DISULFIDE
- Synonyma:
- 1,2-diphenyldisulfane;PHENYL DISULFIDE;FEMA 3225;DIPHENYL DISULPHIDE;Diphenyl disulfide ,99%;usafe-1;USAF e-1;AKOS 94361;Phenyl disulfid;Dithiobisbenzene
- CBNumber:
- CB3716625
- Summenformel:
- C12H10S2
- Molgewicht:
- 218.34
- MOL-Datei:
- 882-33-7.mol
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Diphenyldisulfid Eigenschaften
- Schmelzpunkt:
- 58-60 °C (lit.)
- Siedepunkt:
- 191-192 °C (15 mmHg)
- Dichte
- 1.353
- Brechungsindex
- 1,441-1,444
- FEMA
- 3225 | PHENYL DISULFIDE
- Flammpunkt:
- 310°C
- storage temp.
- Sealed in dry,Room Temperature
- Löslichkeit
- xylene: soluble3%, clear, colorless to yellow
- Aggregatzustand
- Crystalline Solid
- Wichte
- 1.353
- Farbe
- White to off-white
- Geruch (Odor)
- at 0.10 % in propylene glycol. sulfurous earthy burnt
- Geruchsart
- sulfurous
- Wasserlöslichkeit
- Insoluble in water.
- JECFA Number
- 578
- BRN
- 639794
- Stabilität:
- Stable. Incompatible with strong oxidizing agents, strong bases.
- InChIKey
- GUUVPOWQJOLRAS-UHFFFAOYSA-N
- LogP
- 4.41
- CAS Datenbank
- 882-33-7(CAS DataBase Reference)
- NIST chemische Informationen
- Disulfide, diphenyl(882-33-7)
- EPA chemische Informationen
- Diphenyl disulfide (882-33-7)
Diphenyldisulfid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
White to light yellow crystal.
Occurrence
Naturally occurring phytoalexin-like substan
Verwenden
Diphenyl disulfide is one of the most popular organic disulfides used in organic synthesis. It is used as a reagent for the α-phenylsulfenylation of carbonyl compounds. It participates in hydrothiolation of alkynes via amine-mediated single electron transfer mechanism. It is the hydrolysis product of dyfonate.
synthetische
By heating and passing a stream of air over an ammoniacal solution of thiophenol.
läuterung methode
Crystallise the disulfide from MeOH. [Alberti et al. J Am Chem Soc 108 3024 1986]. Also crystallise it repeatedly from hot Et2O, then dry it in a vacuum at 30o over P2O5, fuse it under N2 and re-dry it; the whole procedure being repeated, with a final drying under a vacuum for 24hours. Alternatively, recrystallise it from hexane/EtOH solution. [Burkey & Griller J Am Chem Soc 107 246 1985, Beilstein 6 H 323, 6 IV 1560.]
Diphenyldisulfid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Diphenyldisulfid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 335)Lieferanten
882-33-7(Diphenyldisulfid)Verwandte Suche:
Di-p-tolyldisulfid
Bis(4-nitrophenyl)disulfid
6,6'-Dithiodi-2-naphthol
2,2'-Dithiodibenzoesure
N,N'-Dithiodi-o-phenylendibenzamid
2,2'-Dithiobis-benzolamin
Diphenyldisulfid
3,3'-Dithiobis[6-nitrobenzoe]sure
2,4,5-Trichlorphenyldisulfid
S-Phenylbenzolthiosulfonat
Bis(2-nitrophenyl)disulfid
Bis(4-chlorphenyl)disulfid
Bis(3-nitrophenyl)disulfid
2,2'-Dithiobisbenzamid
4,4'-Dithiodianilin
Dimethyl-2,2'-dithiobisbenzoat
- PHENYL DISULPHIDE
- DIPHENYL DISULFIDE
- DIPHENYLDISULPIDE
- BIPHENYL DISULFIDE
- AKOS 94361
- (Phenyldisulfanyl)benzene
- Disulfide,diphenyl
- disulfidediphenyl
- dlphenyldisulfide
- USAF e-1
- Nelfinavir Related CoMpound E
- Phenyl disulfid
- Diphenyl disulfide (diphenyl disulfide)
- usafe-1
- PHENYL DISULFIDE 98+%
- phenyldithiobenzene
- DIPHENTYL DISULFIDE
- 1,1'-Dithiobisbenzene
- 4,4'-Dithiobis(benzene)
- Diphenyl persulfide
- Dithiobisbenzene
- Phenyl disulfide,99%
- Phenyl disulfide, 99% 50GR
- Thiophenol DiMer (IMpurity E)
- 1,1'-Disulphanediyldibenzene, 1,1'-Dithiodibenzene
- 10gdiphenyldisulfide
- DiphenylDisulfide>
- Diphenyl disulfide, 99%, for synthesis
- TIANFUCHEM--882-33-7---DIPHENYL DISULFIDE
- Nelfinavir Related Compound E (Diphenyl disulfide) (1457957)
- PHENYL DISULFIDE
- DIPHENYL DISULPHIDE
- FEMA 3225
- Diphenyl disulfide ,99%
- 1,2-diphenyldisulfane
- Diphenyl Disulphide (98%)
- 882-33-7
- C12H10S2
- C6H52S2
- C6H5SSC6H5
- Building Blocks
- Organic Building Blocks
- Sulfur Compounds
- Sulfides/Disulfides
- Biphenyl & Diphenyl ether
- bc0001
- R00001
