[3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan

Ambroxane Struktur
6790-58-5
CAS-Nr.
6790-58-5
Bezeichnung:
[3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan
Englisch Name:
Ambroxane
Synonyma:
AMBROXAN;Ambrox;AMBROFIX;(-)-ambroxide;(?)-Ambroxide;(-)-AMBROXIDE;FEMA 3471;Amberoxan;Naphtho2,1-bfuran, dodecahydro-3a,6,6,9a-tetramethyl-, (3aR,5aS,9aS,9bR)-;Ambropur
CBNumber:
CB4423607
Summenformel:
C16H28O
Molgewicht:
236.39
MOL-Datei:
6790-58-5.mol

[3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan Eigenschaften

Schmelzpunkt:
74-76 °C (lit.)
alpha 
-30 º (c=1% in toluene)
Siedepunkt:
273.9±8.0 °C(Predicted)
Dichte
0.939
Dampfdruck
0.066Pa at 25℃
FEMA 
3471 | 1,5,5,9-TETRAMETHYL-13-OXATRICYCLO(8.3.0.0(4,9))TRIDECANE
storage temp. 
Sealed in dry,Room Temperature
Aggregatzustand
powder to crystaline
Farbe
White to Almost white
Geruch (Odor)
at 1.00 % in dipropylene glycol. ambergris old paper sweet labdanum dry
Geruchsart
amber
Optische Aktivität
[α]20/D 29°, c = 1 in toluene
Wasserlöslichkeit
1.88mg/L at 20℃
JECFA Number
1240
InChIKey
YPZUZOLGGMJZJO-LQKXBSAESA-N
LogP
5.09 at 25℃
CAS Datenbank
6790-58-5(CAS DataBase Reference)
NIST chemische Informationen
8 «alpha»,12-epoxy-13,14,15,16-tertanorlabdane(6790-58-5)
EPA chemische Informationen
Naphtho[2,1-b]furan, dodecahydro-3a,6,6,9a-tetramethyl-, (3aR,5aS,9aS,9bR)- (6790-58-5)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
WGK Germany  1
HS Code  2932.99.9090
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

[3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Ambroxan is a synthetic spice with the special aroma of natural ambergris, and it is recognized as one of the best substitutes for natural ambergris. It is one of the most critical trace components of natural ambergris tincture. Natural ambergris is a precious animal spice. It is a kind of stone in the stomach of sperm whale. It is vomited or excreted on the sea surface by the whale, and it emits a special fragrance in the air for a long time.

Verwenden

(-)-Ambroxide can be used:
To prepare (+)-sclareolide through C-H oxidation strategy.
As a substrate in C(sp3)-H alkylation/arylation studies of ethers.
As a substrate in the study of ethereal hydrocarbon hydroperoxidation using singlet O2.

synthetische

Ambroxene naturally occurring autoxidation or photooxide of the triterpenoid secreted by sperm whales.
Industrially, High acacia acid was prepared from nerolidol. After acid internal esterification, the racemic Ambroxene was obtained.
Ambroxide is synthesized from sclareol, a component of the essential oil of clary sage. Sclareol is oxidatively degraded to a lactone, which is hydrogenated to the corresponding diol. The resulting compound is dehydrated to form ambroxide.

Definition

ChEBI: Ambroxan is a diterpenoid derived from sclareol that is responsible for the odour of ambergris (a solid, waxy, flammable substance produced in the digestive system of sperm whales). It is an organic heterotricyclic compound and a diterpenoid.

Origin

Ambroxane was first synthesized in the 1950s by the Swiss chemical company Firmenich, and it has since become one of the most widely used aroma compounds in the fragrance industry.

Allgemeine Beschreibung

Ambroxide is a terpenoid, which has vast applications in the perfume industry due to its fixative property and odor. Ambergris, which was originally sourced from sperm whale, has been substituted by synthetic ambroxides.

Nebenwirkungen

The most common side effects associated with Ambroxane use include those which are observed among patients developing allergic reactions. These include pruritus, hives, and swelling in the face, lips, tongue, or throat. It is important to immediately seek medical attention upon the development of dangerous adverse allergic reactions like difficulty in breathing, shortness of breath, convulsions, and mood changes.

[3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


[3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 305)Lieferanten
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ShanDong Look Chemical Co.,Ltd.
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6790-58-5([3aR-(3aα,5aβ,9aα,9bβ)]-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan)Verwandte Suche:


  • Naphtho[2,1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-,[3aR-(3a.alpha.,5a.beta.,9a.al
  • naphtho[2,1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-,[3atheta-(3aalpha,5a
  • n-Epoxide
  • [3aR-(3aalpha,5abeta,9aalpha,9bbeta)]-dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan
  • Ambropur
  • (-)-AMBROXIDE 99+%
  • ()-Ambroxide,1,5,5,9-Tetramethyl-13-oxatricyclo[8.3.0.04,9]tridecane
  • (-)-AMbroxide(AMbroxane)
  • (-)-Ambroxide 99%
  • AMBERLYN SUPER
  • (3aR,5aS,9aS,9bR)-Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan
  • Ambroxane
  • 1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-,[3aR-(3a.alpha.,5a.beta.,9a.alpha.,9b.beta.)]-Naphtho[2
  • 8.alpha.-12-Oxido-13,14,15,16-tetranorlabdane
  • 9aalpha,9bbeta)]-bet
  • DODECAHYDROTETRAMETHYLNAPHTHOFURAN
  • 1,5,5,9-TETRAMETHYL-13-OXATRICYCLO-[8.3.0.04,9]TRIDECANE
  • (-)-Ambroxide >
  • Ambroxane USP/EP/BP
  • Factory Supply Best Ambroxane CAS 6790-58-5
  • (-)-ambroxide
  • (?)-Ambroxide
  • FEMA 3471
  • (-)-AMBROXIDE
  • AMBROXAN
  • AMBROFIX
  • Naphtho2,1-bfuran, dodecahydro-3a,6,6,9a-tetramethyl-, (3aR,5aS,9aS,9bR)-
  • Amberoxan
  • Ambrox
  • Ambroxide Ambroxan
  • magnesium sulphate monohydrate 14168-73-1
  • AMBROFIX FLAKES (code:1486273)
  • 6790-58-5
  • Chiral Building Blocks
  • Asymmetric Synthesis
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  • Heterocyclic Building Blocks
  • Flavors and Fragrances
  • Flavors & Fragrances
  • 6790-58-5
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