Octan-2-on

2-Octanone Struktur
111-13-7
CAS-Nr.
111-13-7
Bezeichnung:
Octan-2-on
Englisch Name:
2-Octanone
Synonyma:
METHYL HEXYL KETONE;Octan-2-one;METHYL N-HEXYL KETONE;2-Octanon;Methvlhexanone;MHK;octan-2-;FEMA 2802;Zhongxine;Secondone
CBNumber:
CB4852832
Summenformel:
C8H16O
Molgewicht:
128.21
MOL-Datei:
111-13-7.mol

Octan-2-on Eigenschaften

Schmelzpunkt:
-16 °C
Siedepunkt:
173 °C(lit.)
Dichte
0.819 g/mL at 25 °C(lit.)
Dampfdruck
1.8-2.614hPa at 20-25℃
FEMA 
2802 | 2-OCTANONE
Brechungsindex
n20/D 1.416(lit.)
Flammpunkt:
133 °F
storage temp. 
Sealed in dry,2-8°C
Löslichkeit
0.9g/l
Aggregatzustand
Liquid
Farbe
Clear colorless to very slightly yellow
Geruch (Odor)
at 10.00 % in dipropylene glycol. earthy weedy natural woody herbal
Geruchsart
earthy
Wasserlöslichkeit
0.9 g/L
Merck 
14,4711
JECFA Number
288
BRN 
635843
Dielectric constant
7.4(100℃)
Stabilität:
Stable. Incompatible with strong oxidizing agents. Flammable.
LogP
1.95-2.37 at 25℃
CAS Datenbank
111-13-7(CAS DataBase Reference)
NIST chemische Informationen
2-Octanone(111-13-7)
EPA chemische Informationen
2-Octanone (111-13-7)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn
R-Sätze: 21-10
S-Sätze: 36/37-16
RIDADR  UN 1224 3/PG 3
WGK Germany  1
RTECS-Nr. RH1484000
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29141990
Giftige Stoffe Daten 111-13-7(Hazardous Substances Data)
Toxizität Both the acute oral LD50 in rats and the acute dermal LD50 in rabbits exceeded 5 g/kg (Moreno, 1973).
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H312 Gesundheitsschädlich bei Hautkontakt. Akute Toxizität dermal Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P280,P302+P352, P312, P322, P363,P501
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

Octan-2-on Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R21:Gesundheitsschädlich bei Berührung mit der Haut.
R10:Entzündlich.

S-Sätze Betriebsanweisung:

S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S16:Von Zündquellen fernhalten - Nicht rauchen.

Beschreibung

2-Octanone has a floral and bitter, green, fruity (unripe apple) odor with a bitter camphoraceous taste. May be synthesized by the oxidation of methyl hexyl carbinol with K2Cr2O7 and sulfuric acid; also by oxidation of 2-octanol over zinc oxide at 330 - 340°C.

Chemische Eigenschaften

2-Octanone has a floral and bitter, green, fruity (unripe apple) odor and bitter, camphoraceous taste.

Occurrence

Reported found in apple, apricot, banana, cranberry, grape, raisin, papaya, peach, raspberry, strawberry, leek, peas, clove, wheat bread, many cheeses, butter, milk, cooked egg, yogurt, caviar, fatty fish, meats, beer, hop oil beer, cognac, rum, grape wines, cocoa, coffee, tea, roasted filberts and peanuts, pecans, potato chips, oats, soybean, olive, beans, walnut, trassi, mushroom, fig, rice, buckwheat, quince, sweet corn, corn oil, malt, wort, krill, Bourbon vanilla, mountain papaya, shrimp, crab, crayfish, clam, truffle, maté and mastic gum oil.

Verwenden

2-Octanone is used in perfumes, high-boiling solvent, especially for epoxy resin coatings and in leather finishes. It is used in flavoring, odorant. It can act as antiblushing agent for nitrocellulose lacquers.

synthetische

By oxidation of methyl hexyl carbinol with K2Cr2O7 and sulfuric acid; also by oxidation of 2-octanol over zinc oxide at 330 to 340°C.

Vorbereitung Methode

2-Octanone can be produced by oxidation of methyl hexyl carbinol, 2-octanol, or 1-octene or by reductive condensation of acetone with pentanol. Commercial samples can have a purity of 98%.

Definition

ChEBI: A methyl ketone that is octane substituted by an oxo group at position 2.

Allgemeine Beschreibung

2-Octanone is a volatile flavor compound reported to be found in blue cheese, acerola fruit, blue crab and cray fish.

Industrielle Verwendung

Methyl n-hexyl ketone is used as solvent for vinyl compounds and dyes and is suitable for dispersing dyes in light-weight petroleum oils for newsprint inks.

Sicherheitsprofil

Poison by ingestion. Moderately toxic by intraperitoned route. A sktn irritant. Flammable liquid when exposed to heat, flame, or oxidizers. To fight fire, use foam, alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHER and KETONES.

Octan-2-on Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Octan-2-on Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 369)Lieferanten
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