Kohlenstofftetrafluorid Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
GERUCHLOSES, FARBLOSES, KOMPRIMIERTES GAS.
PHYSIKALISCHE GEFAHREN
Das Gas ist schwerer als Luft. Es kann sich in tiefer gelegenen Bereichen sammeln und den Luftsauerstoff verdrängen.
CHEMISCHE GEFAHREN
Bei Kontakt mit heißen Gegenständen oder Flammen Zersetzung unter Bildung von Fluorwasserstoffsäure.
ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation.
INHALATIONSGEFAHREN
Beim Entweichen aus dem Behälter kann das Gas die Luft verdrängen. Erstickungsgefahr in geschlossenen Räumen.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION: Schnelle Verdampfung kann zu Erfrierungen führen. Möglich sind Auswirkungen auf das Herzkreislaufsystem mit nachfolgenden Herzfunktionsstörungen. Exposition gegenüber hohen Konzentrationen kann zu Bewusstlosigkeit führen. (s.Anm.)
LECKAGE
Belüftung. Wasserstrahl NIEMALS auf die Flüssigkeit richten. Persönliche Schutzausrüstung: Chemikalienschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät.
S-Sätze Betriebsanweisung:
S38:Bei unzureichender Belüftung Atemschutzgerät anlegen.
Beschreibung
Tetrafluoromethane, CF4, also known as carbon tetrafluoride and fluorocarbon 14, is a colorless gas that is slightly soluble in water.
Chemische Eigenschaften
colourless gas
Verwenden
Low tempereture refrigerant; gaseous insulator.
Allgemeine Beschreibung
Tetrafluoromethane is a colorless nonflammable gas. Carbon tetrafluoride is shipped as a liquid under pressure. Carbon tetrafluoride may be narcotic at high concentrations. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Carbon tetrafluoride is used as a refrigerant.
Reaktivität anzeigen
The reaction of aluminum with various halogenated hydrocarbons produces a self-sustaining reaction with sufficient heat to melt aluminum pieces, examples of other halogenated hydrocarbons are fluorotrichloromethane, dichlorodifluoromethane, chlorodifluoromethane, tetrafluoromethane. The vigor of the reaction appears to be dependent on the combined degree of fluorination and the vapor pressure [Chem. Eng. News 39(27):44. 1961].
Hazard
Toxic by inhalation.
Health Hazard
Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.
Brandgefahr
Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.
Sicherheitsprofil
Mddly toxic by
inhalation. Less chronically toxic than
carbon tetrachloride. Violent reaction with
Al. When heated to decomposition it emits
toxic fumes of F-. See also FLUORIDES.
mögliche Exposition
Tetrafluoromethane is used in fire extinguishers and as a low temperature refrigerant.
Versand/Shipping
UN1982 Tetrafluoromethane, compressed or or Refrigerant gas R14, Hazard Class: 2.2; Labels: 2.2Nonflammable gas. Cylinders must be transported in a secure upright position, in a well-ventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.
läuterung methode
Purify CF4 by repeated passage over activated charcoal at solid-CO2 temperatures. Traces of air are removed by evacuating while alternately freezing and melting. Alternatively, liquefy CF4 by cooling in liquid air and then fractionally distil it under vacuum. (The chief impurity originally present is probably CF3Cl). Use brass equipment. It is non-flammable. [Beilstein 1 H 59, 1 I 8, 1 II 11, 1 III 35, 1 IV 26.]
Inkompatibilitäten
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Forms hydrogen fluoride and fluorides on decomposition with hot surfaces above 125F/52C or open flame. Incompatible with powdered metals; including aluminum, zinc, and beryllium.
Waste disposal
Return refillable compressed gas cylinders to supplier. Nonrefillable cylinders should be disposed of in accordance with local, state and federalregulations. Allow remaining gas to vent slowly into atmosphere in an unconfined area or exhaust hood. Refillabletype cylinders should be returned to original supplier with any valve caps and outlet plugs secured and valve protection caps in place.
Kohlenstofftetrafluorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Silica gel
Dichlordifluormethan
Chrom (III) hydroxid
Siliciumcarbid
Nickel tube
Petroleum coke
Calciumfluorid
Tetrachlormethan
Distickstofftetrafluorid
Sulfur, pentafluoro(1,1,2,2,2-pentafluoroethyl)-, (OC-6-21)-
Ethanamine, heptafluoro-
Perfluorethan
Schwefelhexafluorid
Schwefeltetrafluorid
2-Penten-3-amine, 1,1,1,4,4,5,5,5-octafluoro-N,N-dimethyl-2-(trifluoromethyl)-
Methane, oxybis[trifluoro-
Carbonyldifluorid
Downstream Produkte
