Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon

Cyclobutane-1,2,3,4-tetracarboxylic dianhydride Struktur
4415-87-6
CAS-Nr.
4415-87-6
Bezeichnung:
Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon
Englisch Name:
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
Synonyma:
1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIANHYDRIDE;Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride;-tetraone;Maleic anhydride cyclic dimer.;Cyclobutane-1,2,3,4-tetracarboxylic;Cyclobutanetetracarboxylic Dianhydride;1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIAN&;Cyclobutanetetracarboxylic acid dianhydride;1,2,3,4-butanetetracarboxylicdianhydride(CBDA);CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE
CBNumber:
CB6718246
Summenformel:
C8H4O6
Molgewicht:
196.11
MOL-Datei:
4415-87-6.mol

Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Eigenschaften

Schmelzpunkt:
>300 °C (lit.)
Siedepunkt:
545.3±50.0 °C(Predicted)
Dichte
1.823±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Löslichkeit
soluble in Toluene
Aggregatzustand
powder to crystal
Farbe
White to Light yellow
BRN 
1430553
CAS Datenbank
4415-87-6(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36
RIDADR  1759
WGK Germany  3
9-21
HazardClass  8
PackingGroup  III
HS Code  29172090
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P271 Nur im Freien oder in gut belüfteten Räumen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Chemische Eigenschaften

White to light yellow solid

Verwenden

cyclobutane-1,2,3,4-tetracarboxylic dianhydride and diamine monomer are used for preparation a polyimide (PI), the type of polyimide has excellent electrical characteristics and optical type, with the material prepared the PI film, in addition to having a higher rate cast visible outside, and can withstand high temperatures thirty-four Baidu. Its performance is very good, is the preparation of a liquid crystal display with an ideal material for the film.

synthetische

Preparation of 1,2,3,4- cyclobutanetetracarboxylic acid dianhydride (CBDA)To a 2L quartz glass photoreactor equipped with sixteen UV lamps (300nm) , a stirrer and a cooler were attached and 250ml of ethyl acetate and 100g of maleic anhydride were added thereto followed by stirring for complete mixing. To avoid an excessive temperature increase, an air-cooling type cooler was first run and then UV light was illuminated for a photoreaction for 24h with stirring so as not to have the reactants adhered to the reactor walls. As a result, 71g of white solid was obtained. After the filtration, the white solid was dried for 24h in a vacuum dryer at 60°C Thus-obtained solid was then added to acetic anhydride, dissolved therein and slowly heated to 150°C followed by the reaction for 24h . Hot reaction solution was filtered through a filter paper to remove impurities and kept in a freezer at the temperature of 0°C or less for recrystallization for 24h to obtain a yellow solid. Thus-obtained solid was filtered and washed three times with 1,4-dioxane to remove acetic anhydride, and then dried in a vacuum oven at 60°C for 48h to obtain 64g of 1, 2, 3, 4 -cyclobutane tetracarboxylic acid dianhydride (CBDA) .

4415-87-6.png

Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 252)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shanghai Daeyeon Chemicals Co., Ltd
021-64478606 +8615900664856
daeyeon001@vip.163.com China 2062 58
Heynova (Shanghai) New Material Technology CO., Ltd
+86-17821320848
zoe@heynovachem.com China 431 58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
+8618222493702
sales8@chinatechem.com China 61 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578
sales@hbmojin.com China 12456 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652
info@fdachem.com China 7845 58
Ouhuang Engineering Materials (Hubei) Co., Ltd
+8617702722807
admin@hbouhuang.com China 2259 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075
jack.li@time-chemicals.com China 1807 55
career henan chemical co
+86-0371-86658258
sales@coreychem.com China 29914 58

4415-87-6(Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon)Verwandte Suche:


  • 3a,3b,6a,6b-Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetrone
  • 4,9-Dioxatricyclo[5.3.0.02,6]decane-3,5,8,10-tetrone
  • Cyclobutane 1,2,3,4-tetracarboxylic acid 1,2:3,4-dianhydride
  • Cyclobutane-1,2,3,4-tetracarboxylic dianhydride ,98%
  • Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride (CBDA)
  • Cyclobutane-1,2,3,4-tetracarboxylic
  • 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)
  • Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetrone,tetrahydro-
  • Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6(3aH,3bH,6aH,6bH)
  • -tetraone
  • CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE
  • Maleic anhydride cyclic dimer.
  • Cyclobutanetetracarboxylic Dianhydride
  • 1,2,3,4-cyclobutanetetracarboxylic acid dianhydride
  • 1,2,3,4-Cyclobutanetetracarboxylic 1,2:3,4-dianhydride
  • Cyclobutanetetracarboxylic acid dianhydride
  • 1,2,3,4-Cyclobutanetetracarboxylic acid 1,2:3,4-dianhydride
  • 1,2,3,4-Cyclobutanetetracarboxylic acid-1,2:3,4-dianhydride
  • 3a,3b,6a,6b-Tetrahydrocyclobuta[1,2-c:3,4-c']difuran 1,3,4,6-tetrone
  • tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraone
  • 1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIAN&
  • Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone
  • 1,2,3,4-Cyclobutanetetracarboxylic1,2:3,4-dianhydride,CBDA
  • Cyclobutane-1,2,3,4-tetracarboxylic dianhydride (CBDA)
  • 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride >
  • 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)>
  • CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE(CBDA) 4415-87-6
  • CBDA 1,2,3,4-Cyclobutanetetracarboxylic1 ,2,3,4-dianhydride
  • 1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIANHYDRIDE
  • Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride
  • (CBDA) Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
  • Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetrone
  • 1,2,3,4-butanetetracarboxylicdianhydride(CBDA)
  • Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone
  • 4415-87-6
  • C8H4O6
  • Organic Building Blocks
  • Building Blocks
  • Carbonyl Compounds
  • Carboxylic Acid Anhydrides
  • Fluorenes, etc. (reagent for high-performance polymer research)
  • Functional Materials
  • Reagent for High-Performance Polymer Research
  • Carbonyl Compounds
  • Carboxylic Acid Anhydrides
  • Organic Building Blocks
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, Organic Building Blocks
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, pharmaceutical intermediates
  • monomer
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