Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon
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- CAS-Nr.
- 4415-87-6
- Bezeichnung:
- Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon
- Englisch Name:
- Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
- Synonyma:
- 1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIANHYDRIDE;Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride;-tetraone;Maleic anhydride cyclic dimer.;Cyclobutane-1,2,3,4-tetracarboxylic;Cyclobutanetetracarboxylic Dianhydride;1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIAN&;Cyclobutanetetracarboxylic acid dianhydride;1,2,3,4-butanetetracarboxylicdianhydride(CBDA);CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE
- CBNumber:
- CB6718246
- Summenformel:
- C8H4O6
- Molgewicht:
- 196.11
- MOL-Datei:
- 4415-87-6.mol
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Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Eigenschaften
- Schmelzpunkt:
- >300 °C (lit.)
- Siedepunkt:
- 545.3±50.0 °C(Predicted)
- Dichte
- 1.823±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- Löslichkeit
- soluble in Toluene
- Aggregatzustand
- powder to crystal
- Farbe
- White to Light yellow
- BRN
- 1430553
- CAS Datenbank
- 4415-87-6(CAS DataBase Reference)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher |
Xi |
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R-Sätze: |
36/37/38 |
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S-Sätze: |
26-36 |
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RIDADR |
1759 |
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WGK Germany |
3 |
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F |
9-21 |
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HazardClass |
8 |
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PackingGroup |
III |
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HS Code |
29172090 |
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Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
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Sicherheit |
P261 |
Einatmen von Staub vermeiden. |
P264 |
Nach Gebrauch gründlich waschen. |
P264 |
Nach Gebrauch gründlich waschen. |
P271 |
Nur im Freien oder in gut belüfteten Räumen verwenden. |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P302+P352 |
BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
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Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
White to light yellow solid
Verwenden
cyclobutane-1,2,3,4-tetracarboxylic dianhydride and diamine monomer are used for preparation a polyimide (PI), the type of polyimide has excellent electrical characteristics and optical type, with the material prepared the PI film, in addition to having a higher rate cast visible outside, and can withstand high temperatures thirty-four Baidu. Its performance is very good, is the preparation of a liquid crystal display with an ideal material for the film.
synthetische
Preparation of 1,2,3,4- cyclobutanetetracarboxylic acid dianhydride (CBDA)To a 2L quartz glass photoreactor equipped with sixteen UV lamps (300nm) , a stirrer and a cooler were attached and 250ml of ethyl acetate and 100g of maleic anhydride were added thereto followed by stirring for complete mixing. To avoid an excessive temperature increase, an air-cooling type cooler was first run and then UV light was illuminated for a photoreaction for 24h with stirring so as not to have the reactants adhered to the reactor walls. As a result, 71g of white solid was obtained. After the filtration, the white solid was dried for 24h in a vacuum dryer at 60°C Thus-obtained solid was then added to acetic anhydride, dissolved therein and slowly heated to 150°C followed by the reaction for 24h . Hot reaction solution was filtered through a filter paper to remove impurities and kept in a freezer at the temperature of 0°C or less for recrystallization for 24h to obtain a yellow solid. Thus-obtained solid was filtered and washed three times with 1,4-dioxane to remove acetic anhydride, and then dried in a vacuum oven at 60°C for 48h to obtain 64g of 1, 2, 3, 4 -cyclobutane tetracarboxylic acid dianhydride (CBDA) .
Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 252)Lieferanten
4415-87-6(Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraon)Verwandte Suche:
- 3a,3b,6a,6b-Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetrone
- 4,9-Dioxatricyclo[5.3.0.02,6]decane-3,5,8,10-tetrone
- Cyclobutane 1,2,3,4-tetracarboxylic acid 1,2:3,4-dianhydride
- Cyclobutane-1,2,3,4-tetracarboxylic dianhydride ,98%
- Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride (CBDA)
- Cyclobutane-1,2,3,4-tetracarboxylic
- 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)
- Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetrone,tetrahydro-
- Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6(3aH,3bH,6aH,6bH)
- -tetraone
- CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE
- Maleic anhydride cyclic dimer.
- Cyclobutanetetracarboxylic Dianhydride
- 1,2,3,4-cyclobutanetetracarboxylic acid dianhydride
- 1,2,3,4-Cyclobutanetetracarboxylic 1,2:3,4-dianhydride
- Cyclobutanetetracarboxylic acid dianhydride
- 1,2,3,4-Cyclobutanetetracarboxylic acid 1,2:3,4-dianhydride
- 1,2,3,4-Cyclobutanetetracarboxylic acid-1,2:3,4-dianhydride
- 3a,3b,6a,6b-Tetrahydrocyclobuta[1,2-c:3,4-c']difuran 1,3,4,6-tetrone
- tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetraone
- 1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIAN&
- Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone
- 1,2,3,4-Cyclobutanetetracarboxylic1,2:3,4-dianhydride,CBDA
- Cyclobutane-1,2,3,4-tetracarboxylic dianhydride (CBDA)
- 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride >
- 1,2,3,4-Cyclobutanetetracarboxylic Dianhydride (purified by sublimation)>
- CYCLOBUTANE-1,2,3,4-TETRACARBOXYLIC DIANHYDRIDE(CBDA) 4415-87-6
- CBDA 1,2,3,4-Cyclobutanetetracarboxylic1 ,2,3,4-dianhydride
- 1,2,3,4-CYCLOBUTANETETRACARBOXYLIC DIANHYDRIDE
- Cyclobutane-1,2,3,4-tetracarboxylic acid dianhydride
- (CBDA)
Cyclobutane-1,2,3,4-tetracarboxylic dianhydride
- Tetrahydrocyclobuta[1,2-c:3,4-c']difuran-1,3,4,6-tetrone
- 1,2,3,4-butanetetracarboxylicdianhydride(CBDA)
- Cyclobuta[1,2-c:3,4-c']difuran-1,3,4,6(3aH,3bH,6aH,6bH)-tetraone
- 4415-87-6
- C8H4O6
- Organic Building Blocks
- Building Blocks
- Carbonyl Compounds
- Carboxylic Acid Anhydrides
- Fluorenes, etc. (reagent for high-performance polymer research)
- Functional Materials
- Reagent for High-Performance Polymer Research
- Carbonyl Compounds
- Carboxylic Acid Anhydrides
- Organic Building Blocks
- fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, Organic Building Blocks
- fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, pharmaceutical intermediates
- monomer