8-bromo-1,4-dioxaspiro[4.5]decane
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- CAS-Nr.
- 68278-51-3
- Englisch Name:
- 8-bromo-1,4-dioxaspiro[4.5]decane
- Synonyma:
- 8-bromo-1,4-dioxaspiro[4.5]decane;1,4-Dioxaspiro[4.5]decane, 8-bromo-
- CBNumber:
- CB71560380
- Summenformel:
- C8H13BrO2
- Molgewicht:
- 221.09
- MOL-Datei:
- 68278-51-3.mol
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8-bromo-1,4-dioxaspiro[4.5]decane Eigenschaften
- Siedepunkt:
- 89-90 °C(Press: 5 Torr)
- Dichte
- 1.46±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- InChI
- InChI=1S/C8H13BrO2/c9-7-1-3-8(4-2-7)10-5-6-11-8/h7H,1-6H2
- InChIKey
- JCWBPQVTECHCIP-UHFFFAOYSA-N
- SMILES
- O1C2(CCC(Br)CC2)OCC1
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
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P264, P270, P301+P312, P330, P501 |
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| Sicherheit |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
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8-bromo-1,4-dioxaspiro[4.5]decane Chemische Eigenschaften,Einsatz,Produktion Methoden
Synthese
A magnetically stirred 1,4-dioxaspiro[4.5]decan-8-ol solution in dry CH2Cl2 was treated with carbon tetrabromide, and the resulting mixture cooled to 0 °C. Triphenylphosphine was added, and the stirring continued at 0 °C under a nitrogen atmosphere for 5 h. After that, H2O and CH2Cl2 were added to the reaction mixture, the organic phase separated, and the aqueous phase extracted with CH2Cl2 (1 x). The combined organic fractions were dried, filtered, and concentrated under reduced pressure. The ensuing residue was subjected to flash chromatography to afford 8-bromo-1,4-dioxaspiro[4.5]decane as a colorless oil.
![8-bromo-1,4-dioxaspiro[4.5]decane](/NewsImg/2023-11-28/6383677793202820448535017.jpg "8-bromo-1,4-dioxaspiro[4.5]decane")
8-bromo-1,4-dioxaspiro[4.5]decane Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
8-bromo-1,4-dioxaspiro[4.5]decane Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 39)Lieferanten
- 8-bromo-1,4-dioxaspiro[4.5]decane
- 1,4-Dioxaspiro[4.5]decane, 8-bromo-
- 68278-51-3
