4-Amino-5-hydroxynaphthalin-2,7-disulfonsure

1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid Struktur
90-20-0
CAS-Nr.
90-20-0
Bezeichnung:
4-Amino-5-hydroxynaphthalin-2,7-disulfonsure
Englisch Name:
1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid
Synonyma:
H Acids;c.i.35570;kyselinah;1-Naphthol-8-amino-3,6-disulfonicacid;1-Amino-8-naphthol-3,6-disulphonicacid;8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID;1-AMINO-8-NAPHTHOL-3,6-DISULFONIC ACID;kyselina8-amino-1-naftol-3,6-disulfonova;kyselina1-amino-8-naftol-3,6-disulfonova;1-Amino-8-hydroxy-3,6-disulfonaphthalene
CBNumber:
CB7306275
Summenformel:
C10H9NO7S2
Molgewicht:
319.31
MOL-Datei:
90-20-0.mol

4-Amino-5-hydroxynaphthalin-2,7-disulfonsure Eigenschaften

Schmelzpunkt:
>300 °C(lit.)
Dichte
1.6832 (rough estimate)
Brechungsindex
1.7640 (estimate)
Löslichkeit
DMSO (Slightly, Heated), Methanol (Slightly), Water (Slightly)
Aggregatzustand
Solid
pka
-0.95±0.40(Predicted)
Farbe
Light Beige to Beige
CAS Datenbank
90-20-0(CAS DataBase Reference)
EPA chemische Informationen
2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy- (90-20-0)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 26-36
WGK Germany  3
HS Code  2922210060
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P271 Nur im Freien oder in gut belüfteten Räumen verwenden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

4-Amino-5-hydroxynaphthalin-2,7-disulfonsure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Chemische Eigenschaften

1-Amino-8-hydroxynaphthalene-3,6-disulfonic acid [90-20-0]. (4-amino-5-hydroxynaphthalene-2,7-disulfonic acid), H acid, C10H9NO7S2, Mr 319.3, is usually isolated as its monosodium salt [5460-09-3], a gray powder that is slightly soluble in cold water and readily soluble in hot water; the disodium salt is very soluble in water. With diazo compounds, H acid couples ortho to the amino group under acid conditions and ortho to the hydroxyl group under alkaline conditions. Bisazo derivatives are formed by stepwise acid and alkaline coupling, with the much slower acid coupling being performed first.

läuterung methode

A slightly alkaline solution of Na2CO3 (ca 22g) in water (litmus) is added to a solution of 100g of the dry acid in 750mL of hot distilled water, followed by 5g of activated charcoal and 5g of Celite. The suspension is stirred for 10minutes and filtered by suction. The acid is then precipitated by adding ca 40mL of conc HCl (solution is blue to Congo Red), then filter it by suction through a shark skin filter circular sheet (or hardened filter paper) and wash it with 100mL of distilled water. The purification process is repeated. The acid is dried overnight in an oven at 60o and stored in a dark bottle The diethylamine salt has m 306-307o(dec, from aqueous EtOH). [Post & Moore Anal Chem 31 1872 1959]. [Beilstein 14 H 840, 14 I 758, 14 II 502, 14 III 2292, 14 IV 2824.]

4-Amino-5-hydroxynaphthalin-2,7-disulfonsure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


4-Amino-5-hydroxynaphthalin-2,7-disulfonsure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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90-20-0(4-Amino-5-hydroxynaphthalin-2,7-disulfonsure)Verwandte Suche:


  • 4-amino-5-hydroxy-7-naphthalenedisulfonicacid
  • 7-Naphthalenedisulfonicacid,4-amino-5-hydroxy-2
  • c.i.35570
  • 1-Naphthol-8-amino-3,6-disulfonicacid
  • kyselina1-amino-8-naftol-3,6-disulfonova
  • 1-AMINO-8-NAPHTHOL-3,6-DISULFONIC ACID
  • 4-AMINO-5-HYDROXY-2,7-NAPTHALENEDISULFONIC ACID
  • 4-AMINO-5-HYDROXY-2,7-NAPHTHALENEDISULFONIC ACID
  • 8-AMINO-1-NAPHTHOL-3,6-DISULFONIC ACID
  • 1-Amino-8-naphthol-3,6-disulphonicacid
  • kyselina8-amino-1-naftol-3,6-disulfonova
  • kyselinah
  • 4-amino-5-hydroxynaphthalene-2,7-disulphonic acid
  • 4-amino-5-hydroxy-2,7-naphalene disulfonic acid
  • 1-Amino-8-hydroxy-3,6-disulfonaphthalene
  • 1-Amino-8-hydroxynaphthalene-3,6-disulfonic acid
  • 1-AMINO-8-HYDROXYNAPHTHALENE-3,6-DISULPHONIC ACID
  • 2,7-NAPHTHALENEDISULFONICACID,4-AMINO-5-HYDROXY
  • 8-Amino-1-hydroxy-3,6-naphthalenedisulfonic acid
  • 4-azanyl-5-hydroxy-naphthalene-2,7-disulfonic acid
  • H Acids
  • 4-Amino-5-hydroxy-2,7-naphthalenedisulfonic
  • H ACID (1-AMINO-8-NAPHTHOL -3 6-DISULFONIC ACID)
  • 1-Amino-8-hydroxynaphthalene-3,6-disulphonicaci
  • 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid ISO 9001:2015 REACH
  • TIANFU-CHEM 1-Amino-8-hydroxynaphthalene-3,6-disulphonic acid 90-20-0
  • 90-20-0
  • 1300-51-1
  • C10H9NO7S2
  • Intermediates of Dyes and Pigments
  • OLED materials,pharm chemical,electronic
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