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Pin-2(3)-en Produkt Beschreibung

alpha-Pinene Struktur
80-56-8
CAS-Nr.
80-56-8
Bezeichnung:
Pin-2(3)-en
Englisch Name:
alpha-Pinene
Synonyma:
c 500;PC500;PINENE;PERMOUNT;AciteneA;2-Pinene;pin-2-ene;Australene;Pina-2-ene;α-pin-2-ene
CBNumber:
CB8209087
Summenformel:
C10H16
Molgewicht:
136.23
MOL-Datei:
80-56-8.mol

Pin-2(3)-en Eigenschaften

Schmelzpunkt:
-55°C
Siedepunkt:
155-156 °C(lit.)
Dichte
0.858 g/mL at 25 °C(lit.)
Brechungsindex
n20/D 1.465(lit.)
FEMA 
2902 | ALPHA-PINENE
Flammpunkt:
90 °F
storage temp. 
2-8°C
Aggregatzustand
Liquid
Farbe
Clear colorless
Odor Threshold
0.018ppm
Wasserlöslichkeit
insoluble
Merck 
13,7527
JECFA Number
1329
Stabilität:
Stable. Flammable. Incompatible with strong oxidizing agents.
CAS Datenbank
80-56-8(CAS DataBase Reference)
NIST chemische Informationen
«alpha»-Pinene(80-56-8)
EPA chemische Informationen
.alpha.-Pinene (80-56-8)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi,N,Xn,F
R-Sätze: 10-36/37/38-43-50-65-51/53-38-36/38-20
S-Sätze: 26-36/37-61-37/39-29-16-36/37/39-7/9-62
RIDADR  UN 2368 3/PG 3
WGK Germany  1
RTECS-Nr. DT7000000
Selbstentzündungstemperatur 491 °F
HazardClass  3.2
PackingGroup  III
HS Code  29021990
Giftige Stoffe Daten 80-56-8(Hazardous Substances Data)
Bildanzeige (GHS)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H304 Kann bei Verschlucken und Eindringen in die Atemwege tödlich sein. Aspirationsgefahr Kategorie 1 Achtung
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H317 Kann allergische Hautreaktionen verursachen. Sensibilisierung der Haut Kategorie 1A Warnung P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 2
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P331 KEIN Erbrechen herbeiführen.
P301+P310 BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P370+P378 Bei Brand: zum Löschen verwenden.

Pin-2(3)-en Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R10:Entzündlich.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R43:Sensibilisierung durch Hautkontakt möglich.
R50:Sehr giftig für Wasserorganismen.
R65:Gesundheitsschädlich: kann beim Verschlucken Lungenschäden verursachen.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S29:Nicht in die Kanalisation gelangen lassen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S7/9:Behälter dicht geschlossen an einem gut gelüfteten Ort aufbewahren.

Beschreibung

Alpha-pinene is the major constituent of turpentine (about 80%). It exists as a levogyre form in European turpentines, and as a dextrogyre form in turpentines found in North America. Sensitization mainly occurs in painters, polishers and varnishers, and in those in the perfume and ceramics industry.

Chemische Eigenschaften

liquid with a turpentine odour

Chemische Eigenschaften

α-Pinene is the most widespread pinene isomer. (+)-α-Pinene, (1R,5R)-2,6,6-trimethylbicyclo[3.3.1]hept-2-ene, occurs, for example, in oil from Pinus palustris Mill., at a concentration up to 65%; oil from Pinus pinaster Soland and American oil from Pinus caribaea contain 70% and 70–80%, respectively, of the laevorotatory isomer, (?)-α-Pinene, (1S,5S)-2,6,6-trimethylbicyclo[3.3.1]hept-2-ene.
α-Pinene undergoes many reactions, of which the following are used in the fragrance industry: upon hydrogenation, α-pinene is converted to pinane, which has become an important starting material in the industrial processes used in the fragrance and flavor industry. α-Pinene can be isomerized to β-pinene with high selectivity for β-pinene formation. Hydration with simultaneous ring opening yields terpineol and cis-terpin hydrate. Pyrolysis of α-pinene yields a mixture of ocimene and alloocimene.
Pure α-pinene is obtained by distillation of turpentine oils. As a fragrance substance, it is used to improve the odor of industrial products.However, it is farmore important as a starting material in industrial syntheses, for example, terpineols, borneol, and camphor.

Chemische Eigenschaften

α-Pinene has a characteristic odor of pine. It is turpentine-like. The oxidized material has a resin-like odor.

Occurrence

The structure would account for the presence of four optically active and two optically inactive isomers; although only d-, l-, and dl-α-pinene are known, however; presence of one or more isomers has been reported in more than 400 essential oils; in the largest amounts it has been reported found in Achillea millefolium (d-), Artemisia tridentata (d-), Italian rosemary (l-), wild thyme (l-), French lavender (l-), coriander (d-, dl-), cumin (d, dl-), labdanum (l-), neroli (l-), lemon, Litsea cubeba (d-) and ylang-ylang (d-). It is also reported in over 200 natural products including apple, apricot, many citrus juices and peel oils, bilberry, cranberry, lingonberry, blackberry, currants, guava, raspberry, strawberry, orange, lime, grapefruit, mandarin, tangerine oils and juices, various spices, mint essential oils, carrot, celery, cooked potato, bell pepper, tomato, anise, cinnamon, cassia leaf, clove, cumin, ginger, Mentha oils, nutmeg, mace, pepper, parsley, thyme, Swiss and cheddar cheese, cream, fatty fish, fried chicken, beef fat, hop oil, rum, bourbon whiskey, tea, roasted filberts, pecans, oats, soybean, plum, mushroom, sweet and wild marjoram, starfruit, mango, tamarind, cardamom, coriander, gin, rice, litchi, calamus, dill, lovage, caraway seed, buckwheat, laurel, fennel, kiwifruit, myrtle leaf and berry, rosemary, buchu oil, Bourbon vanilla, Spanish and clary sage, nectarine, crayfish, clam, cape gooseberry, anise hyssop, angelica root oil, Roman and German chamomile oil, eucalyptus oil, bullock’s heart and mastic gum leaf and fruit oil.

Verwenden

α-Pinene was used as standard in headspace solid-phase microextraction-gas chromatographic analysis of volatile compounds in virgin olive oils 1 . It was used in the synthesis of cesium-doped heteropolyacid having potential application in biodiesel synthesis.

Definition

ChEBI: A pinene that is bicyclo[3.1.1]hept-2-ene substituted by methyl groups at positions 2, 6 and 6 respectively.

Vorbereitung Methode

α-Pinene occurs naturally in a variety of trees and shrubs, including more than 400 essential oils, and air concentrations near pine forests may reach 500–1200 mg/m3. Total U.S. emission of α-pinene from deciduous and coniferous forests amounts to 6.6 million tons annually. An estimated emission rate of α-pinene from natural sources to the atmosphere is 1.84×10 -10 g/cm3/s.

synthetische

From turpentine, by distillation.

Aroma threshold values

Detection: 2.5 to 62 ppb. Aroma characteristics at 1.0%: terpy citrus and spicy, woody pine and turpentinelike with a slight cooling camphoraceous nutmeglike nuance, a fresh herbal lift and a tropical fruit top note.

Taste threshold values

Taste characteristics at 10 ppm: intense, woody, piney and terpy with camphoraceous and turpentine notes. It has herbal, spicy and slightly tropical mango nuances.

Allgemeine Beschreibung

A clear colorless liquid with a turpentine odor. Flash point 91°F. Less dense than water and insoluble in water. Vapors are heavier than air. Used as a solvent.

Air & Water Reaktionen

Highly flammable. Insoluble in water.

Reaktivität anzeigen

alpha-Pinene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen.

Health Hazard

Harmful if swallowed, inhaled or absorbed through skin. High concentrations are extremely destructive to mucous membrane and upper respiratory tract, eyes and skin. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

Brandgefahr

Special Hazards of Combustion Products: Vapor may travel considerable distance to source of ignition and flashback. Container explosion may occur during fire conditions. Forms explosive mixtures in air.

Kontakt-Allergie

Alpha-pinene is the major constituent of turpentine (about 80%). It exists in levogyre form in European turpentine and in dextrogyre form in turpentine found in North-Americans. Sensitization occurs mainly in painters, polishers, and varnishers, and in those in the perfume and in the ceramics industry.

Sicherheitsprofil

A deadly poison by inhalation. Moderately toxic by ingestion. An eye, mucous membrane, and severe human skin irritant. Flammable liquid. A dangerous fire hazard when exposed to heat, flame, or oxidizing materials. To fight fire, use foam, Co2, dry chemical. Explodes on contact with nitrosyl perchlorate.

Pin-2(3)-en Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Pin-2(3)-en Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 225)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com CHINA 8909 55
Anhui Royal Chemical Co., Ltd.
+86-025-86655873
marketing@royal-chem.com CHINA 536 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29954 58
Chengdu GLP biotechnology Co Ltd
13350802083 028-87075086
scglp@glp-china.com CHINA 1824 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5882 58
hdzhl biotechnology co., ltd
86-13032617415
sales@luchibiology.com CHINA 1275 58
NanJing Spring & Autumn Biological Engineering CO., LTD.
0086 13815430202 0086 13815430202
sale02@cqherb.com CHINA 376 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58

80-56-8(Pin-2(3)-en)Verwandte Suche:


  • (±)-pin-2-ene
  • ,6,6-Trimethyl-bicyclo[3.1.1]hept-2-ene
  • 2,6,6-trimethylbicyclo-(3,1,1)-2-heptene
  • 2,6,6-Trimethylbicyclo(3.1.1)-2-hept-2-ene
  • 2,6,6-Trimethylbicyclo(3.1.1)-2-heptene
  • pin-2-ene
  • Terpene hydrocarbon
  • α-pin-2-ene
  • MOUNTING MEDIA
  • POLYMOUNT MOUNTING MEDIA
  • PERMANENT MOUNTING MEDIA
  • PERMOUNT
  • PERMOUNT MOUNTING MEDIA
  • alpha-Pinene, pract., 70%
  • α-pinene,2,6,6-trimethylbicyclo[3.1.1]hept-2-ene;cyclicdexadiene
  • PINANE, (1R)-(+)-cis(SG)
  • PINANE, (1R)-(+)-trans(SG)
  • PINANE, (1S)-(-)-trans(SG)
  • PINANE, (1S)-(-)-cis(SG)
  • 2,6,6-trimethyl-bicyclo(3.1.1)hept-2-en
  • 2,6,6-trimethylbicyclo[3,1,1]-2-heptene (alpha-pinene)
  • 2,6,6-trimethylbicyclo[3,1,1]-heptene (alpha-pinene)
  • 2,6,6-trimethyl-bicyclo[3.1.1]hept-2-en
  • 4,6,6-Trimethylbicyklo(3,1,1)hept-3-en
  • AciteneA
  • c 500
  • femanumber2902
  • PC500
  • alpha-Pinene(ACN)
  • 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene
  • 2-Pinene
  • Pin-2(3)-ene
  • alpha-PINENE, NATURAL
  • a-Pinen (cf. terpene)
  • Alpha-pinene, 97%, stabilized with alpha- tocopherol
  • PINENE
  • (±)-2-Pinene, 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene
  • 2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene alpha-Pinene
  • alpha-Pinene, stabilized with alpha-Tocopherol
  • 2,6,6-Trimethylbicyclo[3.1.1]heptane-2-ene
  • Australene
  • Pina-2-ene
  • alpha-Pinene,70%,pract.
  • 2,6,6-Trimethylbicyclo[3,1,1]-2-hepte
  • alpha-Pinene, stabilized with alpha-Tocopherol, 97% 250GR
  • alpha-Pinene, stabilized with alpha-Tocopherol, 97% 5GR
  • alpha-Pinene solution
  • α-Pinene 80-56-8
  • JACS-80-56-8
  • 2-Pinene,(±)-2-Pinene, 2,6,6-Trimethylbicyclo[3.1.1]Hept-2-Ene, Alpha-Pinene
  • a-Pinene Solution
  • alpha-Pinene,98%
  • 80-56-8
  • 7785-20-4
  • Building Blocks
  • Alkenes
  • Cyclic
  • Organic Building Blocks
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